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    • 1. 发明授权
    • Shape memory polyurethane or polyurethane-urea polymers
    • 形状记忆聚氨酯或聚氨酯 - 脲聚合物
    • US06858680B2
    • 2005-02-22
    • US10054742
    • 2002-01-22
    • Pathiraja A. GunatillakeSimon J. McCarthyGordon F. MeijsRaju Adhikari
    • Pathiraja A. GunatillakeSimon J. McCarthyGordon F. MeijsRaju Adhikari
    • A61L27/00A61L27/18A61L27/26A61L27/50A61L29/04A61L29/06A61L29/14A61L31/00A61L31/04A61L31/06A61L31/14C08G18/38C08G18/48C08G18/61C08G18/66C08J5/00C08L75/00C08L75/04C08L101/00C08G77/38
    • C08G18/6674A61L27/18A61L27/26A61L27/50A61L29/049A61L29/06A61L29/14A61L31/041A61L31/06A61L31/14A61L2400/16C08G18/3893C08G18/4858C08G18/61C08G2280/00C08L75/04Y10S525/937C08L75/02C08L83/04
    • A shape memory polyurethane or polyurethane-urea polymer including a reaction product of: (A) (a) silicon-based macrodiol, silicon-based macrodiamine and/or polyether of the formula (I): A—[(CH2)m—O]n—(CH2)m—A′, wherein A and A are endcapping groups; m is an integer of 6 or more; and n is an integer of 1 or greater; (b) a diisocyanate; and (c) a chain extender; or (B) (b) a diisocyanate: and (c) a chain extender, said polymer having a glass transition temperature which enables the polymer to be formed into a first shape at a temperature higher than the glass transition temperature and maintained in said first shape when the polymer is cooled to a temperature lower than the glass transition temperature, said polymer then being capable of resuming its original shape on heating to a temperature higher than the glass transition temperature. The present invention also relates to a shape memory composition which includes a blend of two or more of the shape memory polyurethane or polyurethane-urea polymers defined above or at least one shape memory polyurethane or polyurethane-urea polymer defined above in combination with another material. The present invention further relates to processes for preparing materials having improved mechanical properties, clarity, processability, biostability and/or degradation resistance and devices or articles containing the shape memory polyurethane or polyurethane-urea polymer and/or composition defined above.
    • 一种形状记忆聚氨酯或聚氨酯 - 脲聚合物,其包括以下反应产物:(A)(a)硅基大分子二醇,硅基大二胺和/或式(I)的聚醚:A - [(CH 2)m O] n - (CH 2)m -A',其中A和A'是封端基团; m为6以上的整数, n为1以上的整数, (b)二异氰酸酯; 和(c)扩链剂; 或(B)(b)二异氰酸酯和(c)扩链剂,所述聚合物具有玻璃化转变温度,使聚合物能够在高于玻璃化转变温度的温度下形成第一形状,并保持在所述第一 当聚合物冷却至低于玻璃化转变温度的温度时,所述聚合物在加热至高于玻璃化转变温度的温度时能够恢复其原始形状。 本发明还涉及一种形状记忆组合物,其包括两种或更多种上述定义的形状记忆聚氨酯或聚氨酯 - 脲聚合物或至少一种形状记忆聚氨酯或聚氨酯 - 脲聚合物与另一种材料组合的共混物。 本发明还涉及制备具有改进的机械性能,透明度,可加工性,生物稳定性和/或耐降解性的材料的方法以及含有上述定形形状记忆聚氨酯或聚氨酯 - 脲聚合物和/或组合物的装置或制品。
    • 3. 发明授权
    • Polyurethane or polyurethane-urea elastomeric compositions
    • 聚氨酯或聚氨酯 - 脲弹性体组合物
    • US5393858A
    • 1995-02-28
    • US962799
    • 1993-02-23
    • Gordon F. MeijsEzio RizzardoArthur BrandwoodPathiraja GunatillakeKlaus H. Schindhelm
    • Gordon F. MeijsEzio RizzardoArthur BrandwoodPathiraja GunatillakeKlaus H. Schindhelm
    • A61L27/00A61L17/04A61L27/18A61L29/00A61L29/06A61L31/00C08G18/10C08G18/48C08G18/65C08G18/66C08G18/76C08G18/30
    • C08G18/765A61L17/04A61L27/18A61L29/06C08G18/10C08G18/4858
    • A polyurethane or polyurethane-urea elastomeric composition, characterized in that the composition is a reaction product of:(A) a soft segment macrodiol which is either:(i) a homopolymer represented by formula I,HO--[(CH.sub.2).sub.n O].sub.m --H Iwherein n represents an integer greater than 5 and less than 13, m is a number such that the number average molecular weight of the compound of formula I falls in the range from 218 to 5000 and optionally at least one hydrogen atom represented in formula I is substituted by a C.sub.1 to C.sub.3 alkyl group or a halogen atom;(ii) a copolymer containing at least 25% by mass of repeating units --(CH.sub.2).sub.n O-- wherein n is as defined in formula I above; or(iii) mixture of macrodiols comprising greater than 10% of a macrodiol as defined in formula I above;(B ) an aliphatic or aromatic diisocyanate known in the art of polyurethane manufacture; and(C) optionally a chain extender.A biomaterial and a medical device which are composed wholly or partly of the polyurethane or polyurethane-urea elastomeric composition are also described.
    • PCT No.PCT / AU91 / 00270 Sec。 371日期:1993年2月23日 102(e)1993年2月23日PCT PCT 1991年6月26日PCT公布。 出版物WO92 / 日本1992年1月9日。一种聚氨酯或聚氨酯 - 脲弹性体组合物,其特征在于所述组合物是以下物质的反应产物:(A)软段大分子二醇,其为:(i)由式I表示的均聚物,HO- [(CH 2)n O] m-HI其中n表示大于5且小于13的整数,m是使式I化合物的数均分子量在218至5000的范围内的数, 式I中表示的至少一个氢原子被C1至C3烷基或卤素原子取代; (ii)含有至少25质量%的重复单元 - (CH 2)n O-的共聚物,其中n如上述式I中所定义; 或(iii)包含大于10%上述式I定义的大分子二醇的大分子二醇的混合物; (B)聚氨酯制造领域已知的脂族或芳族二异氰酸酯; 和(C)任选的扩链剂。 还描述了全部或部分由聚氨酯或聚氨酯 - 脲弹性体组合物组成的生物材料和医疗装置。