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1. 发明申请

US20070105719A1 Use of prolines for improving growth and/or yield 有权
标题翻译：使用脯氨酸来改善生长和/或产量
公开(公告)号：US20070105719A1
公开(公告)日：2007-05-10
申请号：US11269417
申请日：2005-11-07
申请人： Pat Unkefer , Rodolfo Martinez , Thomas Knight
发明人： Pat Unkefer , Rodolfo Martinez , Thomas Knight
IPC分类号： A01N43/36
CPC分类号： A01N43/36 , A01N37/38
摘要： The present invention describes a composition including a mixture of L- and D-pyroglutamate stereoisomers in a ratio of L to D of from about 80:20 to about 97:3, and, a carrier medium for application of the L- and D-pyroglutamate stereoisomers to a target plant. The composition can also be used as a germination medium and may be incorporated into a seed coat for assisting in germination. The present invention further describes a method of increasing the agronomic performance of a target plant by treating a target plant with a composition including a mixture of L- and D-pyroglutamate stereoisomers in a ratio of L to D of from about 80:20 to about 97:3 and a carrier medium for said L- and D-pyroglutamate stereoisomers.
摘要翻译：本发明描述了一种组合物，其包含L至D的比例为约80:20至约97:3的L-和D-焦谷氨酸盐立体异构体的混合物，以及用于施用L-和D- 焦谷氨酸立体异构体。组合物也可以用作发芽培养基，并且可以并入种皮中以辅助发芽。本发明进一步描述了通过用包含L-和D-焦谷氨酸钠立体异构体的混合物的组合物处理靶植物，其比例为约80:20至约 97：3和用于所述L-和D-焦谷氨酸立体异构体的载体介质。

2. 发明申请

US20070004929A1 Synthesis of labeled compounds 审中-公开
标题翻译：标记化合物的合成
公开(公告)号：US20070004929A1
公开(公告)日：2007-01-04
申请号：US11172126
申请日：2005-06-29
申请人： Rodolfo Martinez , Jurgen Schmidt , Marc Alvarez , Louis Silks
发明人： Rodolfo Martinez , Jurgen Schmidt , Marc Alvarez , Louis Silks
IPC分类号： C07F7/22 , C07C391/02 , C07F7/00
CPC分类号： C07C391/02 , C07B2200/05 , C07C321/28 , C07F7/081 , C07F7/2208
摘要： The present invention is directed to labeled compounds of the formula Ar-Z1-Q-Z2 where Ar is an aryl group is selected from the group consisting of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure wherein R1, R2, R3, R4 and R5 are each independently selected from the group consisting of hydrogen, a C1-C4 lower alkyl, a halogen, a phenyl, an alkoxy group and an amino group from the group consisting of NH2, NHR and NRR′ where R and R′ are each a C1-C4 lower alkyl, Q is selected from the group consisting of 13CH2, 13CDH and 13CD2, and Z1 is selected from the group consisting of —S—, —S(═O)—, —S(═O)2—, —Se—, —Se(═O)—, and —Se(═O)2—, Z2 is selected from the group consisting of —Si(R6R7R8), —O(R9), —Se—Ar, —Se(═O)—Ar, —Se(═O)2—Ar, —S—Ar, —S(═O)—Ar, and —S(═O)2—Ar wherein R6, R7 and R8 are each independently selected from the group consisting of a C1-C4 lower alkyl, R9 is a C1-C4 lower alkyl or an R10—Ar group where R10 is a C1-C4 alkylene group.
摘要翻译：本发明涉及标记的式Ar-Z 1 -QZ 2的化合物，其中Ar是芳基，其选自1-萘基，取代的 1-萘基，2-萘基，取代的2-萘基和具有以下结构的苯基：其中R 1，R 2，R 3， R 4和R 5各自独立地选自氢，C 1 -C 4 - 低级烷基，卤素，苯基，烷氧基和氨基，由NH 2，NHR和NRR'组成，其中R和R'各自为C 1〜 C 1 -C 4低级烷基，Q选自 CH 2，CH 2，CH 3，和Z 1〜Z 2选自-S - ， - S（-O） - ， - S （-O）2 - ， - S - ， - S（-O） - 和-Se（-O）2 - ，Z 2 - SUB>选自-Si（R 6 R 7）/ SU （R 9），-O（R 9），-Se-Ar，-Se（-O）-Ar，-Se（-O） 2 -Ar，-S-Ar，-S（-O）-Ar和-S（-O）2 -Ar，其中R 6， R 7和R 8各自独立地选自C 1 -C 4 - 低级烷基 R 9是C 1 -C 4低级烷基或R 10 -Ar基团，其中R 1， SUB> 10 是C 1 -C 4亚烷基。

3. 发明申请

US20060178534A1 Synthesis of [1-13C]pyruvic acid], [2-13C]pyruvic acid], [3-13C]pyruvic acid] and combinations thereof 失效
公开(公告)号：US20060178534A1
公开(公告)日：2006-08-10
申请号：US11052589
申请日：2005-02-07
申请人： Rodolfo Martinez , Clifford Unkefer , Marc Alvarez
发明人： Rodolfo Martinez , Clifford Unkefer , Marc Alvarez
IPC分类号： C07C321/02 , C07C237/40
CPC分类号： C07C69/716 , C07B59/001 , C07B2200/05 , C07C59/347 , C07C235/80 , C07C317/24 , C07C317/46 , Y10T436/200833
摘要： The present invention is directed to labeled compounds, of the formulae wherein C* is each independently selected from the group consisting of 13C and 12C with the proviso that at least one C* is 13C, each hydrogen of the methylene group can independently be either hydrogen or deuterium, the methyl group includes either zero or three deuterium atoms, Q is from the group of sulfide, sulfinyl, and sulfone, Z is an aryl group from the group of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure wherein R1, R2, R3, R4 and R5 are each independently from the group of hydrogen, a C1-C4 lower alkyl, a halogen, and an amino group from the group of NH2, NHR and NRR′ where R and R′ are each independently from the group of a C1-C4 lower alkyl, a phenyl, and an alkoxy group, and the methyl group can include either zero or three deuterium atoms. The present invention is also directed to labeled compounds of the formula where X is from the group of —NR6R7 and —OR8 where R6 and R7 are each independently selected from the group of C1-C4 lower alkyl, alkoxy and aryl and R8 is from the group of C1-C4 lower alkyl, alkoxy and aryl, T is from the group of —CH3, —CD3, —CH2—S—R9, —CH2—S(O)—R9, and —CH2—(O)S(O)—R9, J is from the group of —CH(OH)—CH2—S—R9, —CH(OH)—CH2—S(O)—R9, and —CH(OH)—CH2—(O)S(O)—R9 where R9 is an aryl group from the group of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure wherein R1, R2, R3, R4 and R5 are each independently from the group of hydrogen, a C1-C4 lower alkyl, a halogen, and an amino group from the group of NH2, NHR and NRR′ where R and R′ are each independently from the group of a C1-C4 lower alkyl, a phenyl, and an alkoxy group, and C* are each independently selected from the group consisting of 13C and 12C with the proviso that at least one C* is 13C.

4. 发明申请

US20070191635A1 Synthesis of [13C] and [2H] substituted methacrylic acid, [13c] and [2H] substituted methyl methacrylate and/ or related compounds 失效
公开(公告)号：US20070191635A1
公开(公告)日：2007-08-16
申请号：US11591828
申请日：2006-11-02
申请人： Marc Alvarez , Rodolfo Martinez , Clifford Unkefer
发明人： Marc Alvarez , Rodolfo Martinez , Clifford Unkefer
IPC分类号： C07C53/124
CPC分类号： C07C51/377 , C07B2200/05 , C07C67/317 , C07C317/44 , C07C323/52 , C07C57/04 , C07C69/54
摘要： The present invention is directed to labeled compounds of the formulae wherein Q is selected from the group consisting of —S—, —S(═O)—, and —S(═O)2—, Z is selected from the group consisting of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure wherein R1, R2, R3, R4 and R5 are each independently selected from the group consisting of hydrogen, a C1-C4 lower alkyl, a halogen, and an amino group selected from the group consisting of NH2, NHR and NRR′ where R and R′ are each independently selected from the group consisting of a C1-C4 lower alkyl, an aryl, and an alkoxy group, and X is selected from the group consisting of hydrogen, a C1-C4 lower alkyl group, and a fully-deuterated C1-C4 lower alkyl group. The present invention is also directed to a process of preparing labeled compounds, e.g., process of preparing [13C]methacrylic acid by reacting a (CH3CH2O—13C(O)—13CH2)—aryl sulfone precursor with 13CHI to form a (CH3CH2O—13C(O)—13C(13CH3)2)—aryl sulfone intermediate, and, reacting the (CH3CH2O—13C(O)—13C(13CH3)2)—aryl sulfone intermediate with sodium hydroxide, followed by acid to form [13C]methacrylic acid. The present invention is further directed to a process of preparing [2H8]methyl methacrylate by reacting a (HOOC—C(C2H3)2—aryl sulfinyl intermediate with CD3I to form a (2H3COOC—C(C2H3)2)—aryl sulfinyl intermediate, and heating the (2H3COOC—C(C2H3)2)—aryl sulfinyl intermediate at temperatures and for time sufficient to form [2H8]methyl methacrylate.

5. 发明授权

US5893806A Batting instruction method and apparatus 失效
标题翻译：击打指令方法和装置
公开(公告)号：US5893806A
公开(公告)日：1999-04-13
申请号：US901906
申请日：1997-07-29
申请人： Rodolfo Martinez
发明人： Rodolfo Martinez
IPC分类号： A63B69/00 , A63B69/36 , A63B69/40
CPC分类号： A63B69/0075 , A63B2208/12 , A63B69/0002 , A63B69/3617
摘要： A baseball instructional device and method for use teaches a hitter how to properly hit a ball depending on the location at which the ball is thrown by the pitcher. The device is capable of positioning a baseball, softball, or other ball, at proper hitting positions relative to the hitter, thus teaching the hitter when and where to swing to make proper contact with the ball. In addition to positioning the ball relative to the hitter, the device is provided with visual indicators to assist in teaching the hitter the proper location for striking the ball with the bat.
摘要翻译：一种棒球教学装置和使用方法根据投球员投掷球的位置教导击球员如何正确地击球。该装置能够将棒球，垒球或其他球定位在相对于打击者的适当击球位置处，从而教导击球者何时何地摆动以与球正确接触。除了相对于打击者定位球之外，该装置还设置有视觉指示器，以帮助教练打击者用蝙蝠击球的适当位置。

6. 发明申请

US20070106085A1 Synthesis of [13C] and [2H] susbstituted methacrylic acid, [13C] and [2H] substituted methyl methacrylate and/or related compounds 失效
公开(公告)号：US20070106085A1
公开(公告)日：2007-05-10
申请号：US11268227
申请日：2005-11-04
申请人： Marc Alvarez , Rodolfo Martinez , Clifford Unkefer
发明人： Marc Alvarez , Rodolfo Martinez , Clifford Unkefer
IPC分类号： C07C69/52
CPC分类号： C07C51/377 , C07B2200/05 , C07C67/317 , C07C317/44 , C07C323/52 , C07C57/04 , C07C69/54
摘要： The present invention is directed to labeled compounds of the formulae wherein Q is selected from the group consisting of —S—, —S(═O)—, and —S(═O)2—, Z is selected from the group consisting of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure wherein R1, R2, R3, R4 and R5 are each independently selected from the group consisting of hydrogen, a C1-C4 lower alkyl, a halogen, and an amino group selected from the group consisting of NH2, NHR and NRR′ where R and R′ are each independently selected from the group consisting of a C1-C4 lower alkyl, an aryl, and an alkoxy group, and X is selected from the group consisting of hydrogen, a C1-C4 lower alkyl group, and a fully-deuterated C1-C4 lower alkyl group. The present invention is also directed to a process of preparing labeled compounds, e.g., process of preparing [13C]methacrylic acid by reacting a (CH3CH2O—13C(O)—13CH2)— aryl sulfone precursor with 13CHI to form a (CH3CH2O—13C(O)—13C(13CH3)2)— aryl sulfone intermediate, and, reacting the (CH3CH2O—13C(O)—13C(13CH3)2)— aryl sulfone intermediate with sodium hydroxide, followed by acid to form [13C]methacrylic acid. The present invention is further directed to a process of preparing [2H8]methyl methacrylate by reacting a (HOOC—C(C2H3)2— aryl sulfinyl intermediate with CD3I to form a (2H3COOC—C(C2H3)2)— aryl sulfinyl intermediate, and heating the(2H3COOC—C(C2H3)2)— aryl sulfinyl intermediate at temperatures and for time sufficient to form [2H8]methyl methacrylate.

7. 发明申请

US20050027146A1 Synthesis of isotopically labeled R- or S-[13C, 2H] glycerols 有权
标题翻译：同位素标记的R-或S- [13C，2H]甘油的合成
公开(公告)号：US20050027146A1
公开(公告)日：2005-02-03
申请号：US10629982
申请日：2003-07-30
申请人： Rodolfo Martinez , Clifford Unkefer , Marc Alvarez
发明人： Rodolfo Martinez , Clifford Unkefer , Marc Alvarez
IPC分类号： C07C31/22 , C07C35/22 , C07C35/24
CPC分类号： C07C31/225 , C07B2200/05 , C07B2200/07
摘要： The present invention is directed to asymmetric chiral labeled glycerols including at least one chiral atom, from one to two 13C atoms and from zero to four deuterium atoms bonded directly to a carbon atom, e.g., (2S)[1,2-13C2]glycerol and (2R)[1,2-13C2]glycerol, and to the use of such chiral glycerols in the preparation of labeled amino acids.
摘要翻译：本发明涉及不对称手性标记的甘油，包括至少一个手性原子，一个至两个13个碳原子和从零到四个直接与碳原子键合的氘原子，例如（2S）[1,2- C2]甘油和（2R）[1,2-13C2]甘油，以及这些手性甘油在制备标记的氨基酸中的用途。

8. 发明授权

US5662536A Batting practice apparatus 失效
标题翻译：击球练习器
公开(公告)号：US5662536A
公开(公告)日：1997-09-02
申请号：US322061
申请日：1994-10-12
申请人： Rodolfo Martinez
发明人： Rodolfo Martinez
IPC分类号： A63B69/00 , A63B69/36 , A63B69/40
CPC分类号： A63B69/0075 , A63B2208/12 , A63B69/0002 , A63B69/3617
摘要： A baseball instructional device for use teaches a hitter how to properly hit a ball depending on the location at which the ball is thrown by the pitcher. The device is capable of positioning a baseball, softball, or other ball, at proper hitting positions relative to the hitter, thus teaching the hitter when and where to swing to make proper contact with the ball. In addition to positioning the ball relative to the hitter, the device is provided with visual indicators to assist in teaching the hitter the proper location for striking the ball with the bat.
摘要翻译：用于使用的棒球教学装置教导打击者如何根据投球员投掷球的位置正确地击球。该装置能够将棒球，垒球或其他球定位在相对于打击者的适当击球位置处，从而教导击球者何时何地摆动以与球正确接触。除了相对于打击者定位球之外，该装置还设置有视觉指示器，以帮助教练打击者用蝙蝠击球的适当位置。

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