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1. 发明授权

US08722803B2 Polyolefinic compositions 有权
标题翻译：聚烯烃组合物
公开(公告)号：US08722803B2
公开(公告)日：2014-05-13
申请号：US13386389
申请日：2010-07-20
申请人： Paola Massari , Marco Ciarafoni , Gisella Biondini , Roberto Pantaleoni
发明人： Paola Massari , Marco Ciarafoni , Gisella Biondini , Roberto Pantaleoni
IPC分类号： C08F8/00 , C08L23/00 , C08L23/04 , C08L23/10
CPC分类号： C08L23/12 , C08F297/083 , C08L23/06 , C08L23/16 , C08L2205/03 , C08L2666/02
摘要： A polymer composition comprising (per cent by weight): a) 70-84% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar %; b) 8-15% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 25 to 50 wt % and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 8-15% of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 55 to 90 g/10 min, and the amount of hexane extractables lower than 3.5 wt %.
摘要翻译：包含（重量％）的聚合物组合物：a）通过13C-MNR在25℃下不溶于二甲苯的级分测量的具有全同立构五单元组（Mwmm）的结晶丙烯聚合物的70-84％，更高大于97.5摩尔％ b）8-15％的乙烯和丙烯的弹性体共聚物，所述共聚物具有一定量的源自乙烯的重复单元，范围为25至50重量％，并且在环境温度下部分可溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c）8-15％的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为55至90g / 10min，并且己烷可提取物的量低于3.5wt％。

2. 发明授权

US09309394B2 Polyolefin masterbatch and composition suitable for injection molding 有权
标题翻译：聚烯烃母粒和组合物适合注塑成型
公开(公告)号：US09309394B2
公开(公告)日：2016-04-12
申请号：US13202738
申请日：2010-03-19
申请人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni , Sander Willems
发明人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni , Sander Willems
IPC分类号： C08L23/00 , C08L23/10 , C08L23/12 , C08L23/14
CPC分类号： C08L23/12 , C08L23/10 , C08L23/14 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/06 , C08L2207/04 , C08L2310/00 , C08L2666/06
摘要： A masterbatch composition comprising:70-90% wt of a component (A) being a propylene homopolymer or copolymer of propylene with ethylene or C4-C10 alpha olefins, having a MFRA according to ISO 1133 (230° C./2.16 Kg) ranging from 15 to 70 g/10 min; and10-30% wt of a component B) being a propylene-ethylene copolymer comprising 25-45% wt of ethylene derived units and having a value of the intrinsic viscosity [η] of the fraction soluble in xylene at room temperature ranging from 5 to 9 dl/g, said masterbatch composition having a total MFR higher than 4 g/10 min, and a value of the flexural modulus measured according to ISO method 178 ranging from 950 to 2000 MPa.
摘要翻译：一种母料组合物，其包含：70-90重量％的组分（A）为丙烯均聚物或丙烯与乙烯或C 4 -C 10α-烯烃的共聚物，其具有根据ISO 1133（230℃/ 2.16Kg）的MFRA范围 15〜70g / 10min; 和10-30重量％的组分B）是包含25-45重量％的乙烯衍生单元并且在室温下可溶于二甲苯的级分的特性粘度[η]的值的丙烯 - 乙烯共聚物，其范围为 5至9dl / g，所述母料组合物的总MFR高于4g / 10min，根据ISO方法178测量的弯曲模量值为950至2000MPa。

3. 发明授权

US08575272B2 Polyolefinic compositions 有权
标题翻译：聚烯烃组合物
公开(公告)号：US08575272B2
公开(公告)日：2013-11-05
申请号：US13386381
申请日：2010-07-20
申请人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni
发明人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni
IPC分类号： C08L23/12 , C08F297/08 , C08J5/18
CPC分类号： C08J5/18 , C08F297/083 , C08J2323/12 , C08L23/06 , C08L23/12 , C08L23/16 , C08L2205/03 , C08L2666/02
摘要： A polymer composition comprising (percent by weight):a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 5 to 10;b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt %.
摘要翻译：包含（重量％）的聚合物组合物：a）57％-74％的具有全同立构五单元组的结晶丙烯聚合物（mmmm），通过13C-MNR测量在25℃下不溶于二甲苯的级分，高于97.5摩尔％，多分散指数为5〜10; b）8至15％的乙烯和丙烯的弹性体共聚物，所述共聚物具有一定量的衍生自乙烯的重复单元，范围为30至50％，并且在环境温度下部分溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c）18-28％的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为35至60g / 10min，并且己烷可提取物的量低于4.0wt％。

4. 发明申请

US20120172533A1 POLYOLEFINIC COMPOSITIONS 有权
标题翻译：聚合物组合物
公开(公告)号：US20120172533A1
公开(公告)日：2012-07-05
申请号：US13386381
申请日：2010-07-20
申请人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni
发明人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni
IPC分类号： C08L23/16
CPC分类号： C08J5/18 , C08F297/083 , C08J2323/12 , C08L23/06 , C08L23/12 , C08L23/16 , C08L2205/03 , C08L2666/02
摘要： A polymer composition comprising (per cent by weight):a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 5 to 10;b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; andc) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g;said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt %.
摘要翻译：包含（重量％）的聚合物组合物：a）57％-74％的具有全同立构五单元组的结晶丙烯聚合物（mmmm），通过13C-MNR测量在25℃下不溶于二甲苯的级分。，高于97.5摩尔％，多分散指数为5〜10; b）8至15％的乙烯和丙烯的弹性体共聚物，所述共聚物具有一定量的衍生自乙烯的重复单元，范围为30至50％，并且在环境温度下部分溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c）18-28％的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为35至60g / 10min，并且己烷可提取物的量低于4.0wt％。

5. 发明申请

US20120165472A1 POLYOLEFINIC COMPOSITIONS 有权
标题翻译：聚合物组合物
公开(公告)号：US20120165472A1
公开(公告)日：2012-06-28
申请号：US13386389
申请日：2010-07-20
申请人： Paola Massari , Marco Ciarafoni , Gisella Biondini , Roberto Pantaleoni
发明人： Paola Massari , Marco Ciarafoni , Gisella Biondini , Roberto Pantaleoni
IPC分类号： C08L23/16
CPC分类号： C08L23/12 , C08F297/083 , C08L23/06 , C08L23/16 , C08L2205/03 , C08L2666/02
摘要： A polymer composition comprising (per cent by weight): a) 70-84% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar %; b) 8-15% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 25 to 50 wt % and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 8-15% of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 55 to 90 g/10 min, and the amount of hexane extractables lower than 3.5 wt %.
摘要翻译：包含（重量％）的聚合物组合物：a）通过13C-MNR在25℃下不溶于二甲苯的级分测量的具有全同立构五单元组（Mwmm）的结晶丙烯聚合物的70-84％，更高大于97.5摩尔％ b）8-15％的乙烯和丙烯的弹性体共聚物，该共聚物具有一定量的衍生自乙烯的重复单元，范围为25至50重量％，并且在环境温度下部分可溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c）8-15％的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为55至90g / 10min，并且己烷可提取物的量低于3.5wt％。

6. 发明申请

US20120035327A1 Polyolefin Masterbatch and Composition Suitable for Injection Molding 有权
标题翻译：聚烯烃母粒和组合物适用于注射成型
公开(公告)号：US20120035327A1
公开(公告)日：2012-02-09
申请号：US13202738
申请日：2010-03-19
申请人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni , Sander Willems
发明人： Marco Ciarafoni , Paola Massari , Gisella Biondini , Roberto Pantaleoni , Sander Willems
IPC分类号： C08L23/16 , C08L23/24 , C08L23/20
CPC分类号： C08L23/12 , C08L23/10 , C08L23/14 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/06 , C08L2207/04 , C08L2310/00 , C08L2666/06
摘要： A masterbatch composition comprising:70-90% wt of a component (A) being a propylene homopolymer or copolymer of propylene with ethylene or C4-C10 alpha olefins, having a MFRA according to ISO 1133 (230° C./2.16 Kg) ranging from 15 to 70 g/10 min; and 10-30% wt of a component B) being a propylene-ethylene copolymer comprising 25-45% wt of ethylene derived units and having a value of the intrinsic viscosity [η] of the fraction soluble in xylene at room temperature ranging from 5 to 9 dl/g, said masterbatch composition having a total MFR higher than 4 g/10 min, and a value of the flexural modulus measured according to ISO method 178 ranging from 950 to 2000 MPa.
摘要翻译：一种母料组合物，其包含：70-90重量％的组分（A）为丙烯均聚物或丙烯与乙烯或C 4 -C 10α-烯烃的共聚物，其具有根据ISO 1133（230℃/ 2.16Kg）的MFRA范围 15〜70g / 10min; 和10-30重量％的组分B）是包含25-45重量％的乙烯衍生单元并且在室温下可溶于二甲苯的级分的特性粘度[η]的值的丙烯 - 乙烯共聚物，其范围为 5至9dl / g，所述母料组合物的总MFR高于4g / 10min，根据ISO方法178测量的弯曲模量值为950至2000MPa。

7. 发明申请

US20130344267A1 POLYOLEFIN-BASED CONTAINERS 有权
标题翻译：基于聚烯烃的容器
公开(公告)号：US20130344267A1
公开(公告)日：2013-12-26
申请号：US14004114
申请日：2012-03-08
申请人： Thomas A. Frederick , Claudio Cavalieri , Jeanine A. Smith , Gilles Jobin , Timothy C. Brasel , Roberto Pantaleoni , Marco Ciarafoni , Paola Massari
发明人： Thomas A. Frederick , Claudio Cavalieri , Jeanine A. Smith , Gilles Jobin , Timothy C. Brasel , Roberto Pantaleoni , Marco Ciarafoni , Paola Massari
IPC分类号： B65D1/02
CPC分类号： B65D1/0207 , B29C45/0001 , C08L23/12 , C08L23/14 , Y10T428/1352
摘要： A container comprising a polyolefin composition comprising: A) from 59 wt % to 84 wt %, of a propylene homopolymer having isotactic pentads (mmmm) measured with by 13C-NMR higher than 96%, B) from 16 wt % to 41 wt %, of a copolymer of propylene and ethylene with from 30 wt % to 44 wt %, of ethylene derived units; the sum A) +B) being 100; the composition having an MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) comprised from 72 to 100 g/10 min.
摘要翻译：一种包含聚烯烃组合物的容器，其包含：A）59重量％至84重量％的具有通过13 C-NMR测量的全同立构五单元组（mmmm）的丙烯均聚物高于96％，B）为16重量％至41重量％的丙烯和乙烯与30重量％至44重量％的乙烯衍生单元的共聚物; 总和A）+ B）为100; 该组合物具有72至100g / 10分钟的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）。

8. 发明授权

US09045247B2 Polyolefin-based containers 有权
标题翻译：聚烯烃基容器
公开(公告)号：US09045247B2
公开(公告)日：2015-06-02
申请号：US14004114
申请日：2012-03-08
申请人： Thomas A. Frederick , Claudio Cavalieri , Jeanine A. Smith , Gilles Jobin , Timothy C. Brasel , Roberto Pantaleoni , Marco Ciarafoni , Paola Massari
发明人： Thomas A. Frederick , Claudio Cavalieri , Jeanine A. Smith , Gilles Jobin , Timothy C. Brasel , Roberto Pantaleoni , Marco Ciarafoni , Paola Massari
IPC分类号： B65D1/02 , C08L23/12 , B29C45/00 , C08L23/14
CPC分类号： B65D1/0207 , B29C45/0001 , C08L23/12 , C08L23/14 , Y10T428/1352
摘要： A container comprising a polyolefin composition comprising: A) from 59 wt. % to 84 wt. %, based upon the total weight of the polyolefin composition, of a propylene homopolymer having isotactic pentads (mmmm) measured with 13C-NMR higher than 96%, B) from 16 wt. % to 41 wt. %, based upon the total weight of the polyolefin composition, of a copolymer of propylene and ethylene, wherein the copolymer of propylene and ethylene comprises from 30 wt. % to 44 wt. %, of ethylene derived units based upon total weight of the copolymer of propylene and ethylene; the sum A)+B) being 100 wt. %; the polyolefin composition having an MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) between 72 and 100 g/10 min.
摘要翻译：一种包含聚烯烃组合物的容器，其包含：A）59重量％％至84重量％％，基于聚烯烃组合物的总重量，具有13C-NMR测量的具有全同立构五单元组（mmmm）的丙烯均聚物高于96％，B）为16重量％％至41重量％％，基于聚烯烃组合物的总重量，丙烯和乙烯的共聚物，其中丙烯和乙烯的共聚物包含30wt。％至44重量％基于丙烯和乙烯的共聚物的总重量的乙烯衍生单元的％; 总和A）+ B）为100重量％％; 该聚烯烃组合物在72-100g / 10min之间具有MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）。

9. 发明申请

US20130316213A1 POLYOLEFIN COMPOSITION 审中-公开
标题翻译：聚烯烃组合物
公开(公告)号：US20130316213A1
公开(公告)日：2013-11-28
申请号：US13980268
申请日：2012-01-17
申请人： Marco Ciarafoni , Mara Destro , Paola Massari , Roberto Pantaleoni
发明人： Marco Ciarafoni , Mara Destro , Paola Massari , Roberto Pantaleoni
IPC分类号： C08L23/12 , H01M2/10
CPC分类号： C08L23/12 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L2207/02 , C08L2314/02 , H01M2/1022 , H01M2/1072 , C08L2666/02
摘要： A polyolefin composition comprising: a) from 66 wt % to 76 wt % of a propylene polymer having the fraction insoluble in xylene at 25° C., higher than 97 wt %, a polydispersity index lower than 4.5, and a melt flow rate (MFR) comprised between 6.0 g/10 min and 10.0 g/10 min, b) from 12 wt % to 20 wt % of a copolymer of ethylene and propylene, the copolymer having ethylene ranging from 40 wt % to 53 wt %, the polymer fraction soluble in xylene at 25° C. having an intrinsic viscosity value ranging from 2 to 4 dl/g; c) from 12% to 20%% of ethylene homopolymer; the sum of the amount of a)+b)+c) being 100; said composition having a value of melt flow rate (MFR) ranging from 3.6 to 8.0 g/10 min.
摘要翻译：一种聚烯烃组合物，其包含：a）66重量％至76重量％的在25℃下不溶于二甲苯的级分的丙烯聚合物，高于97重量％，多分散指数低于4.5的熔体流动速率（ MFR）为6.0g / 10min至10.0g / 10min，b）12wt％至20wt％的乙烯和丙烯的共聚物，共聚物的乙烯为40wt％至53wt％，聚合物 25℃下可溶于二甲苯的级分，其特性粘度值为2至4dl / g; c）12％-20％的乙烯均聚物; a）+ b）+ c）的总和为100; 所述组合物的熔体流动速率（MFR）为3.6-8.0g / 10min。

10. 发明授权

US08569418B2 Polyolefin compositions 有权
标题翻译：聚烯烃组合物
公开(公告)号：US08569418B2
公开(公告)日：2013-10-29
申请号：US13378952
申请日：2010-06-23
申请人： Monica Galvan , Marco Ciarafoni , Roberto Pantaleoni , Angelo Ferraro
发明人： Monica Galvan , Marco Ciarafoni , Roberto Pantaleoni , Angelo Ferraro
IPC分类号： C08L23/04 , C08L23/10 , C08F8/00
CPC分类号： C08J5/18 , C08J2323/10 , C08L23/0807 , C08L23/0815 , C08L23/10 , C08L2666/06
摘要： Polyolefin compositions particularly suitable for cast film, exhibiting heat sealability, retortability, low haze and stiffness, comprising: 1) 75-85% of a propylene homopolymer or copolymer of propylene with ethylene and/or one or more C4-C10 α-olefin(s), the homopolymer or copolymer having melting temperature equal to or higher than 150° C., 2) 15-25% of a copolymer of ethylene with one or more C4-C10 α-olefin(s) containing from 20 to 30% of said C4-C10 α-olefin(s); said composition having MFR (at 230° C., 2.16 kg) of from 5-10 g/10 min, the total content of ethylene of from 10 to 20%, the total content of C4-C10 α-olefin(s) of from 2 to 8%, the ratio XStot/XSm of the total fraction soluble in Xylene at room temperature to the fraction soluble in Xylene at room temperature of the matrix component (1) of from 5 to 15, and the value of the intrinsic viscosity of the total fraction soluble in Xylene at room temperature (XSIVtot) of 1.5 dl/g or less.
摘要翻译：特别适用于流延膜的聚烯烃组合物，具有热封性，蒸煮性，低雾度和刚度，包括：1）75-85％的丙烯均聚物或丙烯与乙烯和/或一种或多种C 4 -C 10α-烯烃的共聚物 s），熔融温度等于或高于150℃的均聚物或共聚物，2）乙烯与一种或多种含有20-30％（重量）的C 4 -C 10α-烯烃的共聚物的15-25％的所述C 4 -C 10α-烯烃; 所述组合物的MFR（在230℃，2.16kg）为5-10g / 10min，乙烯的总含量为10至20％，C 4 -C 10α-烯烃的总含量为 2〜8％，室温下可溶于二甲苯的总馏分的比例XStot / XSm与基体成分（1）的室温下可溶于二甲苯的馏分的比例为5〜15，特性粘度在室温下可溶于二甲苯的总馏分（XSIVtot）为1.5dl / g以下。

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