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    • 4. 发明专利
    • Resist material and patter-forming method using the same
    • 使用它的耐材料和图案形成方法
    • JP2010145480A
    • 2010-07-01
    • JP2008319623
    • 2008-12-16
    • Panasonic Corpパナソニック株式会社
    • ENDO MASATAKASASAKO MASARU
    • G03F7/039C07C39/12H01L21/027
    • G03F7/0392G03F7/0045
    • PROBLEM TO BE SOLVED: To prevent occurrence of defective patterns in resist patterns using a molecular resist material.
      SOLUTION: First, on a substrate, a resist film 102 is formed from a resist material which contains a cyclic oligomer of at least trimer which contains no acid-unstable group and is alkali-soluble, a molecular compound containing an acid-unstable group and a photoacid generator, and does not contain a polymer. Then, the resist film 102 thus formed is selectively irradiated with exposure light consisting of extreme ultraviolet rays to perform pattern exposure. Then, the resist film 102 which is subjected to pattern exposure is heated, and then the heated resist film 102 is developed to form a resist pattern 102a from the resist film 102.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了防止使用分子抗蚀剂材料发生抗蚀剂图案中的缺陷图案。 解决方案:首先,在基板上,由含有至少三聚体的不含酸不稳定基团且为碱溶性的三聚体的环状低聚物的抗蚀剂材料形成抗蚀剂膜102, 不稳定组和光致酸发生剂,不含聚合物。 然后,由如此形成的抗蚀剂膜102选择性地用由极紫外线组成的曝光灯照射以进行图案曝光。 然后,对受到图案曝光的抗蚀剂膜102进行加热,然后将加热的抗蚀剂膜102显影,从抗蚀膜102形成抗蚀剂图案102a。版权所有(C)2010,JPO&INPIT
    • 5. 发明专利
    • Resist material and pattern forming method using the same
    • 使用该材料的抗蚀材料和图案形成方法
    • JP2010085921A
    • 2010-04-15
    • JP2008257626
    • 2008-10-02
    • Panasonic Corpパナソニック株式会社
    • ENDO MASATAKASASAKO MASARU
    • G03F7/004G03F7/039G03F7/38H01L21/027
    • G03F7/2041G03F7/0046G03F7/0392G03F7/11
    • PROBLEM TO BE SOLVED: To prevent pattern defects by improving the resolution of a resist material to be used for lithography when no barrier film is prepared on a resist film.
      SOLUTION: The resist film 102 is formed on a substrate 101, the film being formed from a resist material containing a perfluoroethyl acrylate that is a monomer containing a halogen atom (fluorine) and stable against an acid, a polyperfluoroethyl acrylate that is a polymer containing fluorine and stable against an acid, a polymer containing an acid-labile group, and a photo-acid generator. The resist film 102 is subjected to pattern exposure by selectively irradiating the resist film 102 with exposure light while a liquid 103 is disposed on the resist film 101. Subsequently, the resist film 102 subjected to the pattern exposure is developed to form a resist pattern 102b from the resist film 102.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了在抗蚀剂膜上没有制备阻挡膜时,通过提高用于光刻的抗蚀剂材料的分辨率来防止图案缺陷。 抗蚀剂膜102形成在基板101上,该膜由抗蚀剂材料形成,该抗蚀剂材料包含作为含有卤素原子(氟)并且对酸稳定的单体的丙烯酸全氟乙酯,丙烯酸聚全氟乙酯是 含氟并且对酸稳定的聚合物,含有酸不稳定基团的聚合物和光酸发生剂。 通过在抗蚀剂膜101上设置液体103的同时用曝光光选择性地照射抗蚀剂膜102来对抗蚀剂膜102进行图案曝光。接着,对经过图案曝光的抗蚀剂膜102进行显影以形成抗蚀剂图案102b 来自抗蚀剂膜102.版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Pattern forming method
    • 图案形成方法
    • JP2009283565A
    • 2009-12-03
    • JP2008132173
    • 2008-05-20
    • Panasonic Corpパナソニック株式会社
    • ENDO MASATAKASASAKO MASARU
    • H01L21/027G03F7/11G03F7/20G03F7/38
    • G03F7/2041
    • PROBLEM TO BE SOLVED: To prevent failure of a resist pattern in using a barrier film containing nano-particles consisting of an inorganic oxide for liquid immersion lithography.
      SOLUTION: A resist film 102 is formed on a substrate 101, and then the resist film 102 is selectively irradiated with an exposure light while a liquid 104 containing nano-particles (HfO
      2 ) made of an inorganic oxide and an alycyclic compound (1,3-adamandinol) having an alkali-soluble group is disposed on the formed resist film 102, thereby executing pattern exposure. Subsequently, the resist film 102 subjected to pattern exposure is developed to form a resist pattern 102a from the resist film 102.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了防止使用含有由用于液浸光刻的无机氧化物组成的纳米颗粒的阻挡膜的抗蚀剂图案的失效。 解决方案:在基板101上形成抗蚀剂膜102,然后用曝光灯选择性地照射抗蚀剂膜102,同时将含有纳米颗粒(HfO 2 )的液体104 在形成的抗蚀剂膜102上设置具有碱溶性基团的无机氧化物和亚环状化合物(1,3-亚胺丁醇),从而进行图案曝光。 随后,经受图案曝光的抗蚀剂膜102被显影以从抗蚀剂膜102形成抗蚀剂图案102a。版权所有(C)2010,JPO&INPIT
    • 9. 发明专利
    • Chemically amplified resist material and pattern formation method using the same
    • 使用相同的化学放大电阻材料和图案形成方法
    • JP2011017902A
    • 2011-01-27
    • JP2009162525
    • 2009-07-09
    • Panasonic Corpパナソニック株式会社
    • ENDO MASATAKASASAKO MASARU
    • G03F7/039C08F297/00G03F7/004H01L21/027
    • C09D153/00G03F7/0045G03F7/0392
    • PROBLEM TO BE SOLVED: To provide a pattern formation method that reduces roughness produced on a resist pattern to make the pattern have a good shape.SOLUTION: At first, a resist film 102 is formed from a chemically amplified resist material onto a substrate 101. The resist film 102 is irradiated with an exposure light comprising extreme ultraviolet light in a selective manner to achieve pattern exposure. The resist film 102 that has been subjected to pattern exposure is heated, and the heated resist film 102 is developed to form a resist pattern 102a from the resist film 102. The chemically amplified resist material comprises a block polymer comprising a first monomer unit and a second monomer unit, wherein the first monomer unit has an onium salt having an anionic moiety and a cationic moiety and contains a group covalently bound to a sulfonate group that is the anionic moiety, and wherein the second monomer unit contains an acid leaving group.
    • 要解决的问题:提供减少抗蚀剂图案上产生的粗糙度以使图案具有良好形状的图案形成方法。解决方案:首先,将抗蚀剂膜102由化学放大的抗蚀剂材料形成在基板101上。 以选择性的方式对包含极紫外光的曝光光照射抗蚀剂膜102以实现图案曝光。 对已经进行图案曝光的抗蚀剂膜102进行加热,并且将加热的抗蚀剂膜102显影,从抗蚀剂膜102形成抗蚀剂图案102a。化学放大抗蚀剂材料包含嵌段聚合物,该嵌段聚合物包括第一单体单元和 第二单体单元,其中所述第一单体单元具有具有阴离子部分和阳离子部分的鎓盐,并且含有共价结合到作为所述阴离子部分的磺酸盐基团的基团,并且其中所述第二单体单元含有酸离去基团。