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1. 发明申请

WO02080870A3 HAIR COLOURING COMPOSITIONS AND THEIR USE 审中-公开
标题翻译：头发染色组合物及其使用
公开(公告)号：WO02080870A3
公开(公告)日：2003-05-08
申请号：PCT/US0210625
申请日：2002-04-04
申请人： PROCTER & GAMBLE , DUNBAR JAMES CHARLES , PRATT DOMINIC , JAMES DELYTH ANGHARAD
发明人： DUNBAR JAMES CHARLES , PRATT DOMINIC , JAMES DELYTH ANGHARAD
IPC分类号： A61K8/00 , A61K8/35 , A61K8/41 , A61K8/42 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/35
摘要： The invention provides a hair colouring composition comprising one or more developers selected from amino aromatic systems capable of being oxidised and thereafter undergoing at least two electrophilic attack reactions, and one or more couplers selected from (a) 1,3-diketones of the formula (I): in which X and Y are non-leaving substituents and Z is an active leaving group, such that in the presence of an oxidising agent the or each developer reacts with the or each coupler substantially only at the position having the active leaving group Z and (b) compounds of the formula (II): in which R1, R2 and R3 are, independently, cycloalkyl, alkenyl, cycloalkenyl, aryl, alkaryl, aralkyl, -R'NHCOR, -CONHR, -R'CONHR, -R'OH, -R'SO2R, -R'SO2NHR, -R'OR or -COR, in any of which R is H, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, alkaryl or aralkyl and R' is alkylene, alkenylene, cycloalkylene, cycloalkenylene, arylene, alkarylene or aralkyrene, or substituted versions of any of these.
摘要翻译：本发明提供一种头发着色组合物，其包含一种或多种显影剂，所述显影剂选自能够被氧化的氨基芳族体系，然后经历至少两次亲电子攻击反应，以及一种或多种选自（a）1,3-二酮 I）：其中X和Y是非离去取代基，Z是活性离去基团，使得在存在氧化剂的情况下，每个显影剂基本上仅在具有活性离去基团的位置处与该或每个成色剂反应 Z和（b）式（II）的化合物：其中R1，R2和R3独立地是环烷基，烯基，环烯基，芳基，烷芳基，芳烷基，-R'NHCOR，-CONHR，-R'CONHR， - R'OH，-R'SO2R，-R'SO2NHR，-R'OR或-COR，其中R是H，烷基，环烷基，烯基，环烯基，芳基，烷芳基或芳烷基，R'是亚烷基，亚烯基，亚环烷基，亚环烯基，亚芳基，亚烷芳基或芳烯基，或这些的取代形式。

2. 发明公开

EP0951270A4 HAIR COLORING COMPOSITIONS 失效
标题翻译： HAARFÄRBEMITTEL
公开(公告)号：EP0951270A4
公开(公告)日：2001-08-29
申请号：EP97953152
申请日：1997-12-09
申请人： PROCTER & GAMBLE
发明人： DIAS LOUIS CARLOS , DUNBAR JAMES CHARLES , PRATT DOMINIC
IPC分类号： A61K8/00 , A61K20060101 , A61K8/22 , A61K8/33 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/368 , A61K8/38 , A61K8/41 , A61K8/44 , A61K8/49 , A61Q5/10 , C09B20060101 , D06P20060101 , A61K7/13
CPC分类号： A61K8/22 , A61K8/411 , A61K8/415 , A61K8/4926 , A61Q5/10
摘要： A hair coloring composition comprising: (a) an inorganic peroxygen oxidising agent; and (b) an oxidative hair coloring agent; wherin the pH of each of components (a) and (b) is in the range of from about pH 1 to about pH 4.5 and wherein the pH of the composition is in the range of from about pH 1 to about pH 4.5. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.
摘要翻译：一种染发组合物，其包含：（a）无机过氧氧化剂; 和（b）氧化染发剂; 其中组分（a）和（b）中的每一个的pH在约pH 1至约pH 4.5的范围内，并且其中组合物的pH在约pH 1至约pH 4.5的范围内。该产品可以提供优异的染发性和使用中的功效，包括极佳的初始颜色和良好的耐洗牢度，同时降低低pH下的头发损伤。

3. 发明公开

EP1006990A4 HAIR COLOURING COMPOSITIONS AND THEIR USE 失效
标题翻译： HAARFÄRBEMITTELUND IHRE VERWENDUNG
公开(公告)号：EP1006990A4
公开(公告)日：2000-12-13
申请号：EP98923676
申请日：1998-05-22
申请人： PROCTER & GAMBLE
发明人： PRATT DOMINIC
IPC分类号： A61K8/00 , A61K8/22 , A61K8/23 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , A61Q7/00 , A61K7/13
CPC分类号： A61K8/35 , A61K8/494 , A61Q5/10
摘要： Hair colouring compositions which are of reduced harshness to skinand hair are provided which comprise: (i) one or more developers selected from aminoaromatic systems capable of being oxidised and thereafter undergoing a single electrophilic attack, and (ii) one or more couplers selected from (A) phenols and naphthols having an active leaving group in the para position relative to the hydroxy group, (B) 1,3-diketone derivatives having an active leaving group, or (C) pyrazolone derivatives having an active leaving group, such that in the presence of an oxidizing agent the or each developer reacts with the or each coupler substantially only at the position having the active leaving group, and (iii) an inorganic peroxygen agent in an amount of from about 0.0001 to about 0.05 moles per 100 g of composition. Alternative compositions may contain higher levels of oxidizing agent provided that they have a pH below 6.
摘要翻译：提供了提供改善的抗褪色性的新型染发组合物。它们包括（i）一种或多种选自氨基芳族体系能够被氧化并随后经历单次亲电攻击的显影剂，和（ii）一种或多种选自（A）酚和酚醛的成色剂，其具有在对位中具有活性离去基团（B）含有Z为活性离去基团的基团（I）的1,3-二酮，（C）含有Z为活性离去基团的基团（II）的化合物，并且X是活性离去基团或非离去取代基，使得在存在氧化剂的情况下，该显影剂或每个显影剂基本上仅在具有活性离去基团Z的位置处与该或每个成色剂反应，并且如果X是活性离去基团X，当通过本文所述的毛发开色剂方法施用于毛发并通过本文所述的洗涤方案洗涤20次时，给出如下所述测量的“E渐变值”：（a）当该组合物适用于d 提供金色或浅棕色阴影“E淡化不超过2.5，（b）当组合物适合传递红色阴影时，”E褪色不超过5.0，（c）当组合物适合传送黑色或深棕色阴影“E褪色不超过2.5。

4. 发明公开

EP0957894A4 HAIR COLORING COMPOSITIONS 失效
标题翻译： HAARFÄRBEMITTEL
公开(公告)号：EP0957894A4
公开(公告)日：2001-08-29
申请号：EP97952373
申请日：1997-12-09
申请人： PROCTER & GAMBLE
发明人： DIAS LOUIS CARLOS , DUNBAR JAMES CHARLES , PRATT DOMINIC
IPC分类号： A61K8/00 , A61K20060101 , A61K8/22 , A61K8/33 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/368 , A61K8/38 , A61K8/44 , A61Q5/10 , C09B20060101 , D06P20060101 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/22 , A61K2800/88
摘要： A storage stable, re-usable hair coloring composition comprising: (a) an oxidising agent; and (b) an oxidative hair coloring agent; wherein the pH of each of (a) and (b) is in the range of from about 1 to about 6 and wherein the combined mixture of (a) and (b) has a pH in the range of from about 1 to about 5 and wherein both (a) and (b) are capable of being stored at low pH, either separately, or, once mixed, for at least 1 month at room temperature and wherein the resultant color delivered to the hair (Delta E) is up to about 75 %, preferably up to about 85 %, more preferably up to about 90 % and most preferably up to about 95 % of the total color delivered to the hair (Delta E) from a mixture of (a) and (b) on mixing. The products are storage stable and re-usable and can provide excellent hair coloring and in-use efficacy benefits in combination with improved color retention potential after storage at room temperature.
摘要翻译：储存稳定的，可重复使用的染发组合物，其包含：（a）氧化剂; 和（b）氧化染发剂; 其中（a）和（b）各自的pH在约1至约6的范围内，并且其中（a）和（b）的混合的混合物的pH在约1至约5的范围内并且其中（a）和（b）能够在低pH下分开存储或者一旦混合，在室温下存储至少1个月，并且其中递送至头发的最终颜色（ΔE）达到（a）和（b）的混合物递送至头发的总颜色（ΔE）的约75％至约75％，优选至多约85％，更优选至多约90％，最优选至多约95％在混合。这些产品具有储存稳定性和可重复使用的特点，可以提供优异的染发性和使用中的功效，并且在室温下储存后具有更好的保色性。

5. 发明公开

EP0952811A4 HAIR COLORING COMPOSITIONS 失效
标题翻译：染发组合物
公开(公告)号：EP0952811A4
公开(公告)日：2001-08-29
申请号：EP97954556
申请日：1997-12-09
申请人： PROCTER & GAMBLE
发明人： DIAS LOUIS CARLOS , DUNBAR JAMES CHARLES , PRATT DOMINIC , STRAND CATHERINE MARGARET , SANGER ALISON JANE
IPC分类号： A61K8/00 , A61K20060101 , A61K8/22 , A61K8/33 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/368 , A61K8/38 , A61K8/41 , A61K8/42 , A61K8/44 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/38 , A61K2800/88 , A61Q5/10
摘要： A hair coloring composition comprising: (a) a preformed organic peroxyacid oxidising agent; and (b) an oxidative hair coloring agent; wherein the pH of each of components (a) and (b) is in the range of from about pH 1 to less than about pH 7 and wherein the pH of the composition is in the range of from about pH 1 to less than about pH 7. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.

6. 发明公开

EP1006989A4 HAIR COLOURING METHODS 失效
标题翻译： VERFAHREN ZUMFÄRBENVON HAAREN
公开(公告)号：EP1006989A4
公开(公告)日：2000-12-13
申请号：EP98923675
申请日：1998-05-22
申请人： PROCTER & GAMBLE
发明人： PRATT DOMINIC
IPC分类号： A61K8/00 , A61K8/22 , A61K8/23 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , A61Q7/00 , A61K7/13
CPC分类号： A61K8/35 , A61K8/494 , A61Q5/10
摘要： A method of colouring hair, particularly suitable for demi-permanent colouration, comprising providing: (i) one or more developers selected from aminoaromatic systems capable of being oxidized and thereafter undergoing a single nucleophilic attack, and (ii) one or more couplers selected from (A) phenols and naphthols having an active leaving group in the para position relative to the hydroxyl group, (B) 1,3-diketone derivatives having an active leaving group, and (C) pyrazolone derivatives having an active leaving group, and (iii) oxidizing agent, applying components (i), (ii) and (iii) to the hair to be coloured, and allowing the components (i), (ii), and (iii) to remain on the hair for not more than 15 minutes, and rinsing. Also provided is a hair colouring kit comprising the defined components and instructions.
摘要翻译：一种着色头发的方法，特别适用于半永久性着色，包括提供：（i）一种或多种选自能够被氧化并随后进行单亲核攻击的氨基芳族体系的显影剂，和（ii）一种或多种选自（A）相对于羟基在对位具有活性离去基团的酚和萘酚，（B）具有活性离去基团的1,3-二酮衍生物，和（C）具有活性离去基团的吡唑啉酮衍生物，以及（ iii）氧化剂，将组分（i），（ii）和（iii）施用到待染色的头发上，并允许组分（i），（ii）和（iii）留在头发上不超过 15分钟，然后冲洗。还提供了包含定义的组分和说明书的染发剂盒。

7. 发明公开

EP0966249A4 HAIR COLORING COMPOSITIONS 失效
标题翻译： HAARFÄRBEMITTEL
公开(公告)号：EP0966249A4
公开(公告)日：2001-12-19
申请号：EP97952374
申请日：1997-12-09
申请人： PROCTER & GAMBLE
发明人： DIAS LOUIS CARLOS , DUNBAR JAMES CHARLES , PRATT DOMINIC
IPC分类号： A61K8/00 , A61K20060101 , A61K8/22 , A61K8/33 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/368 , A61K8/38 , A61K8/41 , A61K8/44 , A61K8/49 , A61Q5/10 , C09B20060101 , D06P20060101 , D06P3/08 , A61K7/13
CPC分类号： A61K8/22 , A61K8/411 , A61K8/415 , A61K8/4926 , A61Q5/10
摘要： A hair coloring composition comprising: (a) from about 0.0003 moles (per 100 g of composition) to less than about 0.09 moles (per 100 g of composition) of an inorganic peroxygen oxidising agent; and (b) an oxidative hair coloring agent; wherein the pH of each of (a) and (b) is in the range of from about 1 to about 6 and wherein the combined mixture of (a) and (b) has a pH in the range of from about 1 to about 6. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.
摘要翻译：一种染发组合物，其包含：（a）约0.0003摩尔（每100g组合物）至小于约0.09摩尔（每100g组合物）无机过氧氧化剂; 和（b）氧化染发剂; （a）和（b）各自的pH在约1至约6的范围内，并且其中（a）和（b）的混合的混合物的pH在约1至约6的范围内。这些产品能够提供优异的染发和使用中的功效，包括极佳的初始颜色和良好的耐洗牢度，同时在低pH值下减少头发损伤。

8. 发明公开

EP0946133A4 HAIR COLORING COMPOSITIONS 失效
标题翻译：染发剂
公开(公告)号：EP0946133A4
公开(公告)日：2001-08-29
申请号：EP97954058
申请日：1997-12-09
申请人： PROCTER & GAMBLE
发明人： DIAS LOUIS CARLOS , DUNBAR JAMES CHARLES , PRATT DOMINIC
IPC分类号： A61K8/00 , A61K20060101 , A61K8/22 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/368 , A61K8/38 , A61K8/41 , A61K8/44 , A61Q5/10 , C09B20060101 , D06P20060101 , D06P3/08 , A61K7/13
CPC分类号： A61K8/22 , A61K8/347 , A61K8/411 , A61K8/415 , A61Q5/10
摘要： A hair coloring composition present in a single package suitable for direct application to the hair wherein the hair coloring mixture comprises: a) an oxidising agent; and b) an oxidative hair coloring agent; and wherein the combined mixture of a) and b) has a pH in the range of from about 1 to about 5 and wherein the resultant color delivered to the hair (Delta E), after at least about 1 month of storage at room temperature, is up to about 75 %, preferably up to about 85 %, more preferably up to about 90 % and most preferably up to about 95 % of the total color delivered to the hair (Delta E) from a mixture of a) and b) on application. The products are storage stable, re-usable and can provide both excellent hair coloring and in-use efficacy benefits as well as improved color development potential after storage at room temperature.

9. 发明公开

EP1003466A4 HAIR COLOURING COMPOSITIONS AND THEIR USE 失效
标题翻译： HAARFÄRBEMITELUND IHRE ANWENDUNG
公开(公告)号：EP1003466A4
公开(公告)日：2001-01-03
申请号：EP98923679
申请日：1998-05-22
申请人： PROCTER & GAMBLE
发明人： PRATT DOMINIC , DIAS LOUIS CARLOS , DUNBAR JAMES CHARLES , GENAIN GILLES YVES MARIE FERNA
IPC分类号： A61K8/00 , A61K8/22 , A61K8/23 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , A61Q7/00 , A61K7/13
CPC分类号： A61K8/35 , A61K8/494 , A61Q5/10
摘要： Novel hair colouring compositions are provided which give improved fade resistance. They comprise (i) one or more developers selected from amino aromatic systems capable of being oxidised and thereafter undergoing a single electrophilic attack, and (ii) one or more couplers selected from (A) phenols and naphthols having an active leaving group in the para position relative to the OH group, (B) 1,3-diketones containing the group (I) in which Z is an active leaving group, and (C) compounds containing the group (II) in which Z is an active leaving group, and X is an active leaving group or a non-leaving substituent, such that in the presence of an oxidising agent the or each developer reacts with the or each coupler substantially only at the position having the active leaving group Z and, if X is an active leaving group, X, which when applied to hair by the hair switch colouring method described herein and washed 20 times by the washing protocol described herein, gives a value of DELTA E fade, measured as described herein, as follows: (a) when the composition is suitable for delivering a blonde or light brown shade DELTA E fade is not more than 2.5, (b) when the composition is suitable for delivering a red shade, DELTA E fade is not more than 5.0, (c) when the composition is suitable for delivering a black or dark brown shade DELTA E fade is not more than 2.5.
摘要翻译：提供了提供改善的抗褪色性的新型染发组合物。它们包括（i）一种或多种选自氨基芳族体系能够被氧化并随后经历单次亲电攻击的显影剂，和（ii）一种或多种选自（A）酚和酚醛的成色剂，其具有在对位中具有活性离去基团（B）含有Z为活性离去基团的基团（I）的1,3-二酮，（C）含有Z为活性离去基团的基团（II）的化合物，并且X是活性离去基团或非离去取代基，使得在存在氧化剂的情况下，该显影剂或每个显影剂基本上仅在具有活性离去基团Z的位置处与该或每个成色剂反应，并且如果X是活性离去基团X，当通过本文所述的毛发开色剂方法施用于毛发并通过本文所述的洗涤方案洗涤20次时，给出如下所述测量的“E渐变值”：（a）当该组合物适用于d 提供金色或浅棕色阴影“E淡化不超过2.5，（b）当组合物适合传递红色阴影时，”E褪色不超过5.0，（c）当组合物适合传送黑色或深棕色阴影“E褪色不超过2.5。

10. 发明专利

AU744937B2 Hair colouring compositions and their use 未知
公开(公告)号：AU744937B2
公开(公告)日：2002-03-07
申请号：AU7692198
申请日：1998-05-22
申请人： PROCTER & GAMBLE
发明人： PRATT DOMINIC
IPC分类号： A61K8/00 , A61K8/22 , A61K8/23 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , A61Q7/00 , A61K7/13
摘要： Novel hair coloring compositions are provided which give improved fade resistance. They comprise (i) one or more developers selected from amino aromatic systems capable of being oxidized and thereafter undergoing a single electrophilic attack, and (ii) one or more couplers selected from (A) phenols and naphthols having an active leaving group in the para position relative to the OH group, (B) 1,3-diketones containing the group (I) in which Z is an active leaving group, and (C) compounds containing the group (II) in which Z is an active leaving group, and X is an active leaving group or a non-leaving substituent, such that in the presence of an oxidizing agent the or each developer reacts with the or each coupler substantially only at the position having the active leaving group Z and, if X is an active leaving group, X, which when applied to hair by the hair switch coloring method described herein and washed 20 times by the washing protocol described herein, gives a value of "E fade, measured as described herein, as follows: (a) when the composition is suitable for delivering a blonde or light brown shade "E fade is not more than 2.5, (b) when the composition is suitable for delivering a red shade, "E fade is not more than 5.0, (c) when the composition is suitable for delivering a black or dark brown shade "E fade is not more than 2.5.

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