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    • 4. 发明申请
    • SULFUR-CONTAINING OLIGOMERS AND HIGH INDEX POLYURETHANES PREPARED THEREFROM
    • 含硫的低聚物和高指数聚氨酯
    • WO2007078550A3
    • 2008-02-07
    • PCT/US2006046639
    • 2006-12-06
    • PPG IND OHIO INC
    • BOJKOVA NINA VHEROLD ROBERT DMCDONALD WILLIAM HGRAHAM MARVIN JSMITH ROBERT A
    • C08G75/00C08G18/00G02B1/00
    • C08G18/758C08G18/10C08G18/1816C08G18/3876C08G18/52
    • The present invention provides polythiol oligomer formed by the reaction of at least two or more different dienes and at least one or more dithiol wherein stoichiometric ratio of the sum of the number of equivalents of all polythiols to the sum of the number of equivalents of all dienes used to form said polythiol oligomer is greater than 1.0 : 1.0; and wherein said two or more different dienes comprise (a) at least one non-cyclic diene and at least one cyclic diene; or (b) at least one aromatic ring-containing diene and at least one non-aromatic cyclic diene; or (c) at least one non-aromatic monocyclic diene and at least one non-aromatic polycyclic diene; Sulfur-containing polyurethane of the present invention can be prepared by combining polyisocyanate, polyisothiocyanate, or mixture thereof; the polythiol oligomer described above; and active hydrogen-containing material.
    • 本发明提供通过至少两种或更多种不同的二烯和至少一种或多种二硫醇的反应形成的多硫醇低聚物,其中所有多硫醇的当量数之和与所有二烯的当量数之和的化学计量比 用于形成所述多硫醇低聚物大于1.0:1.0; 并且其中所述两种或更多种不同的二烯包含(a)至少一种非环状二烯和至少一种环状二烯; 或(b)至少一种含芳族环的二烯和至少一种非芳族环状二烯; 或(c)至少一种非芳族单环二烯和至少一种非芳族多环二烯; 本发明的含硫聚氨酯可以通过多异氰酸酯,多异硫氰酸酯或其混合物的组合来制备; 上述多硫醇低聚物; 和含活性氢的材料。