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    • 2. 发明申请
    • METHOD OF MANUFACTURING NICKEL ZINC BATTERIES
    • 制造镍锌电池的方法
    • WO2005020353A2
    • 2005-03-03
    • PCT/US2004/026859
    • 2004-08-17
    • POWERGENIX SYSTEMSPHILLIPS, JeffreyZHAO, Jason
    • PHILLIPS, JeffreyZHAO, Jason
    • H01M4/00
    • H01M2/1686H01M4/244H01M4/661H01M10/30H01M10/44Y10T29/49108Y10T29/4911
    • Methods of manufacturing a rechargeable power cell are described. Methods include providing a slurry or paste of negative electrode materials having low toxicity and including dispersants to prevent the agglomeration of particles that may adversely affect the performance of power cells. The methods utilize semi-permeable sheets to separate the electrodes and minimize formation of dendrites; and further provide electrode specific electrolyte to achieve efficient electrochemistry and to further discourage dendritic growth in the cell. The negative electrode materials may be comprised of zinc and zinc compounds. Zinc and zinc compounds are notably less toxic than the cadmium used in NiCad batteries. The described methods may utilize some production techniques employed in existing NiCad production lines. Thus, the methods described will find particular use in an already well-defined and mature manufacturing base.
    • 描述制造可再充电电池的方法。 方法包括提供具有低毒性且包括分散剂的负电极材料的浆料或糊剂以防止可能不利地影响电池性能的颗粒附聚。 该方法利用半渗透性片材来分离电极并使树突的形成最小化; 并进一步提供电极特异性电解质以实现有效的电化学并进一步阻止细胞中的树枝状生长。 负极材料可以由锌和锌化合物组成。 锌和锌化合物的毒性比镍镉电池中使用的镉小得多。 所描述的方法可以利用现有NiCad生产线中采用的一些生产技术。 因此,所描述的方法将在一个已经明确界定和成熟的制造基地中找到特别的用途。
    • 5. 发明公开
    • METHODS FOR PRODUCTION OF ZINC OXIDE ELECTRODES FOR ALKALINE BATTERIES
    • VERFAHREN ZUR HERSTELLUNG VON ZINKOXIDELEKTRODENFÜRALKALIBATTERIEN
    • EP1371103A2
    • 2003-12-17
    • EP02708074.6
    • 2002-03-15
    • Phillips, Jeffrey
    • PHILLIPS, Jeffrey
    • H01M2/00
    • H01M4/244H01M4/04H01M4/26H01M4/364H01M4/62H01M4/622H01M10/24Y10T29/49115
    • A zinc electrode for use in alkaline batteries comprises a mixture of 0.425 to 1.55 volume parts of zinc oxide with a volume part of a metallic oxide chosen from the group consisting of: calcium oxide, barium oxide, and mixtures thereof, together with hydroxy-ethyl cellulose, an oxide dispersant chosen from the group consisting of: soap derivatives, anionic polyelectrolytes, anionic surfactants, and mixtures thereof, and a binder. The electrode is prepared by mixing zinc oxide with the chosen metallic oxide in an aqueous medium such as water or potassium hydroxide, stirring overnight, filtering and drying the mixture, optionally adding a further small amount of zinc oxide, optionally adding other metallic oxides, and adding hydroxy-ethyl cellulose, an oxide dispersant, and a binder. The aqueous paste os slurry thus formed is placed on a conductive substrate, drawn through a sizing gap, cut and dried, to form low cost pasted zinc oxide electrodes.
    • 用于碱性电池的锌电极包括0.425至1.55体积份的氧化锌与体积部分金属氧化物的混合物,其选自:氧化钙,氧化钡及其混合物,以及羟基乙基 纤维素,选自以下的氧化物分散剂:皂衍生物,阴离子聚电解质,阴离子表面活性剂及其混合物,以及粘合剂。 电极是通过将氧化锌与所选择的金属氧化物在水性介质如水或氢氧化钾中混合制备的,搅拌过夜,过滤并干燥混合物,任选地加入少量氧化锌,任选地加入其它金属氧化物,和 加入羟乙基纤维素,氧化物分散剂和粘合剂。 将如此形成的含水浆料浆料放置在导电基材上,通过筛分间隙拉伸,切割干燥,形成低成本的糊状氧化锌电极。
    • 8. 发明申请
    • DUAL CHEMISTRY HYBRID BATTERY SYSTEMS
    • 双化学混合电池系统
    • WO2003088375A2
    • 2003-10-23
    • PCT/CA2003/000509
    • 2003-04-04
    • POWERGENIX SYSTEMS, INC.PHILLIPS, Jeffrey
    • PHILLIPS, Jeffrey
    • H01M
    • H02J7/34
    • A hybrid battery system (10, 12) comprises a high power, low impedance battery (20) in parallel with a high energy battery (22), which have substantially equal, fully charged, at rest, terminal voltages. The ampere hour capacity of the high energy battery to a predetermined cutoff voltage is at least twenty times the ampere hour capacity of the high power battery to the same cutoff voltage. The electrical couples of the high power battery and the high energy battery are different one from the other; and may be chosen from the group of pairs of electrical couples consisting of lead acid and nickel zinc, lead acid and lithium ion, lead acid and lithium polymer, nickel zinc and lithium polymer, nickel metal hydride and lithium polymer, and carbon nickel oxide and nickel zinc. If the hybrid battery system is carbon nickel oxide and nickel zinc, then the carbon nickel oxide battery may comprise carbon impregnated into a nickel foam substrate, and the nickel electrode may be a compressed pasted nickel oxide electrode with a thickness in the range of 0.007 to 0.012 inches.
    • 混合电池系统(10,12)包括与高能量电池(22)并联的大功率低阻抗电池(20),其在静止时具有基本相等的完全充电的端电压。 高能电池到预定截止电压的安培小时容量至少是高功率电池的相当截止电压的安培小时容量的二十倍。 大功率电池和高能电池的电耦合是不同的; 并且可以选自由铅酸和镍锌,铅酸和锂离子,铅酸和锂聚合物,镍锌和锂聚合物,镍金属氢化物和锂聚合物,碳氧化镍和碳氧化镍组成的电对对组 镍锌。 如果混合电池系统是碳氧化镍和镍锌,则碳氧化镍电池可以包括浸渍在镍泡沫衬底中的碳,并且镍电极可以是压缩的粘贴的氧化镍电极,其厚度在0.007至 0.012英寸