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    • 8. 发明申请
    • REMOVAL OF FREE FATTY ACIDS FROM GLYCERIDE OILS
    • 从甘油油中去除免费的脂肪酸
    • WO2015079262A1
    • 2015-06-04
    • PCT/GB2014/053553
    • 2014-11-28
    • THE QUEEN'S UNIVERSITY OF BELFASTATKINS, MartinCOLEMAN, FergalGOODRICH, Peter
    • ATKINS, MartinCOLEMAN, FergalGOODRICH, Peter
    • C11B3/02C11B3/06
    • C11B3/06A23D9/007A23L5/27A23V2002/00C11B3/02C11C3/003
    • The present invention relates to deacidification of glyceride oils. The present invention provides a process for removing free fatty acids from glyceride oil, preferably palm oil, containing free fatty acids, said process comprising the steps of: (i) contacting the glyceride oil containing free fatty acids with the basic ionic liquid; wherein the basic ionic liquid has a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a cation selected from: [N(R a )(R b )(R c )(R d )] + , wherein: R a , R b , R c and R d are each independently selected from hydrogen, a C 1 to C 8 , straight chain or branched alkyl group or a C 3 to C 6 cycloalkyl group, wherein said alkyl or cycloalkyl groups are unsubstituted or may be substituted by one to three groups selected from: C 1 to C 4 alkoxy, C 2 to C 8 alkoxyalkoxy, C 3 to C 6 cycloalkyl, -OH, -SH, - CO 2 (C 1 to C 6 )alkyl, -OC(O)(C 1 to C 6 )alkyl, or any two of R a , R b , R c and R d combine to form an alkylene chain -(CH 2 ) q - wherein q is from 3 to 6; and (ii) obtaining a treated glyceride oil having a reduced content of free fatty acid compared to the glyceride oil feed of step (i).
    • 本发明涉及甘油酯油的脱酸。 本发明提供了一种从含有游离脂肪酸的甘油酯油,优选棕榈油中除去游离脂肪酸的方法,所述方法包括以下步骤:(i)使含有游离脂肪酸的甘油酯油与碱性离子液体接触; 其中所述碱性离子液体具有选自氢氧化物,醇盐,烷基碳酸盐,碳酸氢盐,丝氨酸盐,脯氨酸盐,组氨酸盐,苏氨酸盐,缬氨酸盐,天冬酰胺酸盐,牛磺酸盐和赖氨酸盐的碱性阴离子; 和选自:[N(Ra)(Rb)(Rc)(Rd)] +的阳离子,其中:Ra,Rb,Rc和Rd各自独立地选自氢,C1至C8,直链或支链烷基 或C 3至C 6环烷基,其中所述烷基或环烷基是未取代的或可被一至三个选自以下的基团取代:C 1至C 4烷氧基,C 2至C 8烷氧基烷氧基,C 3至C 6环烷基,-OH,-SH, CO 2(C 1至C 6)烷基,-OC(O)(C 1至C 6)烷基或R a,R b,R c和R d中的任何两个结合形成亚烷基链 - (CH 2)q-,其中q为3至6 ; 和(ii)与步骤(i)的甘油酯油进料相比,获得游离脂肪酸含量降低的经处理的甘油酯油。