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1. 发明授权

US3919292A Production of chlorinated cotelomers 失效
标题翻译：生产氯化钴矿
公开(公告)号：US3919292A
公开(公告)日：1975-11-11
申请号：US33987473
申请日：1973-03-09
申请人： PECHINEY SAINT GOBAIN
发明人： VOFSI DAVID , ASSCHER MEIR
IPC分类号： C08F2/38 , C07C69/54
CPC分类号： C08F2/38
摘要： The production of chlorinated cotelomers in which a homogeneous solution of mixtures of vinyl chloride and vinylidine chloride or a binary or tertiary mixture of vinyl chloride and/or vinylidene chloride with a non-chlorinated vinyl monomer are polymerized in the presence of chloroform or carbon tetrachloride with a catalyst in the form of a ferrous or ferric compound.
摘要翻译：制备氯化共聚物，其中氯乙烯和氯化亚乙烯基氯化物的混合物的均匀溶液或氯乙烯和/或偏二氯乙烯的二元或三元混合物与非氯化乙烯基单体的混合物在氯仿或四氯化碳存在下聚合，亚铁或铁化合物形式的催化剂。

2. 发明专利

GB1242177A PRODUCTION OF CHLORINATED CO-TELOMERS 未知
公开(公告)号：GB1242177A
公开(公告)日：1971-08-11
申请号：GB1674169
申请日：1969-03-31
申请人： PECHINEY SAINT GOBAIN
发明人： VOFSI DAVID , ASSCHER MEIR
IPC分类号： C08F214/06
摘要： 1,242,177. Telomers. PRODUITS CHIMIQUES PECHINEY-SAINT-GOBAIN. 31 March, 1969 [1 April, 1968], No. 16741/69. Heading C3P. [Also in Division C2] Telomers of vinyl chloride and vinylidene chloride or one or both of these with a non- chlorinated ethylenically-unsaturated monomer are prepared by reaction with carbon tetrachloride or chloroform in the presence of a bivalent or trivalent iron salt, or of a co-ordination complex of iron. Non-chlorinated monomers specified are acrylic and methacrylic acids, their salts and alkyl esters, acrylonitrile, acrylamide, fumaric and maleic acids and their salts and alkyl esters, maleic anhydride, styrene, butadiene and isoprene. Trivalent iron salts are preferably used in the presence of a reducing agent capable of converting them to divalent . iron compounds during the reaction, e.g. benzoin, acetaldehyde, isobutyraldehyde, benzaldehyde, stannous chloride, acetoin, ammonia or ammonium sulphite. Solubility of iron salts in the reaction mixture may be increased by addition of an alkyl-substituted ammonium chloride or bromide or lithium chloride or bromide. Co-solvents may be used. The products are used as softeners, plasticizers and flame-retardants for synthetic resins.

3. 发明专利

DE1916489A1 未知
公开(公告)号：DE1916489A1
公开(公告)日：1969-11-13
申请号：DE1916489
申请日：1969-03-31
申请人： PECHINEY SAINT GOBAIN
发明人： VOFSI DAVID , ASSCHER MEIR
IPC分类号： C08F214/06 , C08F1/62
摘要： The production of chlorinated cotelomers in which a homogeneous solution of mixtures of vinyl chloride and vinylidene chloride or a binary or tertiary mixture of vinyl chloride and/or vinylidene chloride with a non-chlorinated vinyl monomer are polymerized in the presence of chloroform or carbon tetrachloride with a catalyst in the form of a ferrous or ferric compound.

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