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    • 2. 发明申请
    • Method and apparatus for determining a concentration of a component in a mixture
    • 用于测定混合物中组分浓度的方法和装置
    • US20060088943A1
    • 2006-04-27
    • US11265731
    • 2005-11-02
    • Otto ProhaskaAvinash Dalmia
    • Otto ProhaskaAvinash Dalmia
    • G01N33/00
    • G01N1/2226G01N35/1097G01N2001/2229Y10T436/20Y10T436/25875
    • The invention relates to a method and apparatus for determining a concentration of a component in an unknown mixture. The method includes the steps of preparing a reactant having a specified pH level and a specified temperature and combining the unknown mixture with the reactant. The method further includes varying the pH level and temperature of the combination of the reactant and the unknown mixture to facilitate converting at least one selected component. Upon varying the pH level and temperature, the method will release volatiles from the selected component(s). Based on these released volatiles, which indicate the concentration of the selected component(s), the method detects the indication. The apparatus for determining a concentration of a component in an unknown mixture includes a container having a specified volume, a reactant chamber, and a sample chamber. The receptacle contains a reactant, placed within the reactant chamber, having a predetermined pH level and a predetermined volume. The receptacle also has a headspace sampling interface in contact with the container for permitting connection to a headspace sampling device and a sample introduction interface for permitting connection to a sample injector to introduce a sample into the sample chamber.
    • 本发明涉及一种用于确定未知混合物中组分浓度的方法和装置。 该方法包括制备具有特定pH值和特定温度的反应物并将未知混合物与反应物组合的步骤。 该方法还包括改变反应物和未知混合物的组合的pH水平和温度,以便于转化至少一种选择的组分。 在改变pH水平和温度时,该方法将从所选择的组分中释放挥发物。 基于这些释放的挥发物,其表示所选组分的浓度,该方法检测指示。 用于确定未知混合物中的组分浓度的装置包括具有特定体积的容器,反应物室和样品室。 容器包含放置在反应物室内的具有预定pH水平和预定体积的反应物。 容器还具有与容器接触的顶空采样接口,用于允许连接到顶空采样装置和样品引入界面,用于允许连接到样品注射器以将样品引入样品室。
    • 4. 发明申请
    • Electrochemical sensor compensated for relative humidity
    • 电化学传感器补偿相对湿度
    • US20050269203A1
    • 2005-12-08
    • US11198812
    • 2005-08-05
    • Avinash DalmiaOtto Prohaska
    • Avinash DalmiaOtto Prohaska
    • G01N27/407G01N27/49G01N27/26
    • G01N27/4045
    • The invention relates to an electrochemical gas sensor having both a reference sensor and an active sensor, whereby each reference and active sensor includes a substrate, a counter electrode deposited on a surface of the substrate, a sensing electrode also deposited on the surface, and a solid electrolytic material in electrical contact with both electrodes for carrying a flow of ions between them, which measures a concentration of a gas and compensates for relative humidity differences between sample gas and surrounding atmosphere. The sensor also includes a layer of solid electrolytic material on the sensing electrode of the reference sensor and a film of solid electrolytic material on the sensing electrode of the active sensor, whereby the layer is thicker than the film. The invention may further include a reference electrode in both the reference and active sensors for improving sensor accuracy and/or repeatability.
    • 本发明涉及一种具有参考传感器和有源传感器两者的电化学气体传感器,其中每个参考和主动传感器包括基底,沉积在基底表面上的对电极,还沉积在表面上的感测电极,以及 固体电解质材料与两个电极电接触,用于在它们之间携带离子流,其测量气体的浓度并补偿样品气体和周围大气之间的相对湿度差异。 该传感器还包括在参考传感器的感测电极上的固体电解质层和活性传感器的感测电极上的固体电解质膜,由此该层比该膜厚。 本发明还可以包括用于提高传感器精度和/或可重复性的参考电极和有源传感器中的参考电极。