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1. 发明授权

US06781017B2 Method for the production of acrolein or acrylic acid or the mixture thereof from propane 有权
标题翻译：从丙烷生产丙烯醛或丙烯酸或其混合物的方法
公开(公告)号：US06781017B2
公开(公告)日：2004-08-24
申请号：US10297602
申请日：2002-12-13
申请人： Otto Machhammer , Goetz-Peter Schindler , Andreas Tenten , Klaus Harth , Peter Zehner , Klaus Joachim Müller-Engel , Frank Rosowski , Frieder Borgmeier
发明人： Otto Machhammer , Goetz-Peter Schindler , Andreas Tenten , Klaus Harth , Peter Zehner , Klaus Joachim Müller-Engel , Frank Rosowski , Frieder Borgmeier
IPC分类号： C07C4500
CPC分类号： C07C51/215 , C07C5/333 , C07C45/33 , C07C45/35 , C07C51/252 , C07C11/06 , C07C47/22 , C07C57/04
摘要： In a process for the preparation of acrolein or acrylic acid or a mixture thereof from propane, the propane is subjected, in a first reaction stage, to a partial dehydrogenation under heterogeneous catalysis to give propene, of the components contained in the product gas mixture formed in the first reaction stage other than propene and propane at least a portion of the molecular hydrogen present is then separated off from said mixture and the product gas mixture is then used for the preparation of acrolein and/or acrylic acid by gas-phase catalytic propylene oxidation, molecular nitrogen being present for diluting the reaction gas mixture during the propylene oxidation.
摘要翻译：在从丙烷制备丙烯醛或丙烯酸或其混合物的方法中，丙烷在第一反应阶段中在非均相催化下进行部分脱氢以形成产物气体混合物中所含组分的丙烯在除丙烯和丙烷之外的第一反应阶段中，存在的分子氢的至少一部分然后从所述混合物中分离出来，然后将产物气体混合物用于通过气相催化丙烯制备丙烯醛和/或丙烯酸存在氧化，分子氮，用于在丙烯氧化期间稀释反应气体混合物。

2. 发明授权

US07087802B2 Method for the dehydrogenation of hydrocarbons 有权
标题翻译：碳氢化合物脱氢方法
公开(公告)号：US07087802B2
公开(公告)日：2006-08-08
申请号：US10380552
申请日：2001-09-14
申请人： Goetz-Peter Schindler , Otto Machhammer , Klaus Harth , Klaus Joachim Müller-Engel , Peter Zehner
发明人： Goetz-Peter Schindler , Otto Machhammer , Klaus Harth , Klaus Joachim Müller-Engel , Peter Zehner
IPC分类号： C07C5/327
CPC分类号： C07C5/325 , B01J23/58 , B01J23/626 , B01J23/63 , B01J23/96 , B01J38/14 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/42 , C07C2523/44 , Y02P20/128 , Y02P20/584
摘要： In a process for the heterogeneously catalyzed dehydrogenation in one or more reaction zones of one or more dehydrogenatable C2-C30-hydrocarbons in a reaction gas mixture comprising them, with at least part of the heat of dehydrogenation required being generated directly in the reaction gas mixture in at least one reaction zone by combustion of hydrogen, the hydrocarbon or hydrocarbons and/or carbon in the presence of an oxygen-containing gas, the reaction gas mixture comprising the dehydrogenatable hydrocarbon or hydrocarbons is brought into contact with a Lewis-acid dehydrogenation catalyst which has essentially no Brönsted acidity.
摘要翻译：在包含它们的反应气体混合物中的一种或多种可脱氢C 2 -C 30 - 烃的一个或多个反应区中的非均相催化脱氢的方法中，需要的至少一部分脱氢热量通过在含氧气体存在下通过氢气，烃或烃和/或碳的燃烧直接在至少一个反应区中的反应气体混合物中产生，反应气体混合物包含使可脱氢的烃或烃与基本上没有布朗斯台德酸性的路易斯酸脱氢催化剂接触。

3. 发明授权

US07173143B2 Integrated method for synthesis propylene oxide 有权
标题翻译：合成环氧丙烷的综合方法
公开(公告)号：US07173143B2
公开(公告)日：2007-02-06
申请号：US10526045
申请日：2003-08-29
申请人： Michael Bender , Peter Zehner , Otto Machhammer , Ulrich Mueller , Klaus Harth , Goetz-Peter Schindler , Henrik Junicke
发明人： Michael Bender , Peter Zehner , Otto Machhammer , Ulrich Mueller , Klaus Harth , Goetz-Peter Schindler , Henrik Junicke
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/125 , Y02P20/582
摘要： The present invention relates to an integrated process for the synthesis of propylene oxide, which comprises at least the following steps: (i) dehydrogenation of propane to give a substream T(0) comprising at least propane, propene and hydrogen; (ii) fractionation of the substream T(0) to give at least one gaseous hydrogen-rich substream T(2) and a substream T(1) comprising at least propene and propane; (iii) synthesis of hydrogen peroxide using the substream T(2), giving a substream T (4) which is rich in hydrogen peroxide and a gaseous substream T(6); (iv) fractionation of the substream T(1) to give at least one propane-rich substream T(5) and at least one propene-rich substream T(3); (v) reaction of the at least one substream T(3) with substream T(4) to give propylene oxide.
摘要翻译：本发明涉及一种用于合成环氧丙烷的综合方法，其包括至少以下步骤：（i）丙烷脱氢得到至少包含丙烷，丙烯和氢的分支T（O）; （ii）分流T（0）以产生至少一个富含气体的气流T（2）和至少包含丙烯和丙烷的子流T（1）; （iii）使用子流T（2）合成过氧化氢，得到富含过氧化氢的气流T（4）和气态分支T（6）; （iv）分流T（1）以产生至少一个富含丙烷的子流T（5）和至少一个富含丙烯的子流T（3）; （v）至少一个子流T（3）与子流T（4）的反应，得到环氧丙烷。

4. 发明授权

US07291761B2 Partial dehydrogenation method using continuous heterogeneous catalysis 有权
标题翻译：使用连续多相催化的部分脱氢方法
公开(公告)号：US07291761B2
公开(公告)日：2007-11-06
申请号：US10507001
申请日：2003-03-04
申请人： Otto Machhammer , Goetz-Peter Schindler , Klaus Harth , Peter Zehner
发明人： Otto Machhammer , Goetz-Peter Schindler , Klaus Harth , Peter Zehner
IPC分类号： C07C5/327 , C07C5/333
CPC分类号： B01J19/26 , B01J8/025 , B01J8/0278 , B01J23/002 , B01J27/199 , B01J2523/00 , C07C45/33 , C07C45/35 , Y02P20/582 , C07C47/22 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要： A process for the continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon in the gas phase and in the presence of molecular oxygen, in which part of the product gas is recirculated to the reaction zone, and a reactor for carrying out such a process.
摘要翻译：在气相和分子氧存在下，烃的连续不均匀催化部分脱氢的方法，其中部分产物气体再循环到反应区，以及用于进行这种方法的反应器。

5. 发明授权

US07271279B2 Method for the production of unsaturated nitriles from alkanes 失效
标题翻译：从烷烃生产不饱和腈的方法
公开(公告)号：US07271279B2
公开(公告)日：2007-09-18
申请号：US10482326
申请日：2002-06-25
申请人： Frieder Borgmeier , Frank Rosowski , Goetz-Peter Schindler
发明人： Frieder Borgmeier , Frank Rosowski , Goetz-Peter Schindler
IPC分类号： C07C253/18 , C07C255/08
CPC分类号： C07C253/26 , B01J27/199 , C07C45/33 , C07C45/35 , Y02P20/52 , C07C47/22 , C07C255/08
摘要： The invention relates to a process for preparing unsaturated nitrites from the corresponding alkanes which comprises the steps: a) feeding an alkane into a dehydrogenation zone and catalytically dehydrogenating the alkane to the corresponding alkene to obtain a product gas stream A which comprises the alkene, unconverted alkane and possibly one or more further gas components selected from the group consisting of steam, hydrogen, carbon oxides, hydrocarbons having a lower boiling point than the alkane or the alkene (low-boilers), nitrogen and noble gases, b) at least partially removing further gas components from the product gas stream A to give a feed gas stream B which comprises the alkane and the alkene, c) feeding the feed gas stream B, ammonia, an oxygen-containing gas and, if desired, steam into an oxidation zone and catalytically ammoxidizing the alkene to the corresponding unsaturated nitrile to give a product gas stream C which comprises the unsaturated nitrile, ammoxidation by-products, unconverted alkane and alkene and possibly one or more further gas components selected from the group consisting of steam, oxygen, carbon oxides, ammonia, nitrogen and noble gases, d) optionally removing ammonia from the product gas stream C to give an ammonia-depleted product gas stream D, e) removing the unsaturated nitrile and ammoxidation by-products from the product gas stream C or D by absorption in an aqueous absorbent to give a gas stream E which comprises unconverted alkane and alkene and possibly one or more further gas components selected from the group consisting of oxygen, carbon oxides, ammonia, nitrogen and noble gases, and an aqueous stream which comprises the nitrile and the by-products, and recovery of the unsaturated nitrile from the aqueous stream, f) recycling the gas stream E into the dehydrogenation zone.
摘要翻译：本发明涉及从相应的烷烃制备不饱和亚硝酸盐的方法，其包括以下步骤：a）将烷烃进料到脱氢区中，并将烷烃催化脱氢至相应的烯烃，得到产物气流A，其包含未转化的烯烃烷烃和可能的一种或多种另外的气体组分，其选自蒸汽，氢气，碳氧化物，沸点低于烷烃或烯烃（低沸点）的烃，氮气和惰性气体，b）至少部分从产物气流A中除去进一步的气体组分，得到包含烷烃和烯烃的进料气流B，c）将进料气流B，氨，含氧气体和如果需要的话进料到氧化物并将烯烃催化氨基化成相应的不饱和腈，得到包含不饱和腈的产物气流C，通过 - 产物，未转化的烷烃和烯烃以及可能的一种或多种另外的气体组分，其选自蒸汽，氧气，碳氧化物，氨，氮气和惰性气体，d）任选地从产物气流C除去氨，得到氨分离的产物气流D，e）通过在含水吸收剂中吸收从产物气流C或D中除去不饱和腈和氨氧化副产物，得到包含未转化的烷烃和烯烃的气流E，以及可能一个或多个另外的选自氧，碳氧化物，氨，氮和惰性气体的气体组分和包含腈和副产物的水流，以及从水流中回收不饱和腈，f）将气体再循环流E进入脱氢区。

6. 发明授权

US07910766B2 Preparation of at least one partial oxidation and/or ammoxidation product of a hydrocarbon 有权
标题翻译：制备烃的至少一种部分氧化和/或氨氧化产物
公开(公告)号：US07910766B2
公开(公告)日：2011-03-22
申请号：US10813010
申请日：2004-03-31
申请人： Goetz-Peter Schindler , Otto Machhammer , Klaus Joachim Mueller-Engel , Claus Hechler , Jochen Petzoldt , Christoph Adami , Klaus Harth
发明人： Goetz-Peter Schindler , Otto Machhammer , Klaus Joachim Mueller-Engel , Claus Hechler , Jochen Petzoldt , Christoph Adami , Klaus Harth
IPC分类号： C07C253/08 , C07C255/06 , C07C51/16
CPC分类号： B01J23/63 , B01J23/626 , C07C45/33 , C07C45/34 , C07C45/35 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C47/22 , C07C57/04 , C07C255/08
摘要： A process for preparing at least one partial oxidation and/or ammoxidation product of a hydrocarbon by partially dehydrogenating at least one saturated hydrocarbon H under heterogeneous catalysis and using the resulting product gas mixture A, which comprises the partially dehydrogenated hydrocarbon H, as such or in modified form for heterogeneously catalyzed partial oxidation and/or ammoxidation of the partially dehydrogenated hydrocarbon present in the product gas mixture A, said process including at least one mechanical separating operation inserted between the product gas mixture A and the heterogeneously catalyzed partial oxidation and/or ammoxidation.
摘要翻译：通过在非均相催化下部分脱氢至少一种饱和烃H并且使用所得到的产物气体混合物A（其包含部分脱氢的烃H）本身或其中的方法制备烃的至少一种部分氧化和/或氨氧化产物的方法产物气体混合物A中存在的部分脱氢的烃的非均相催化部分氧化和/或氨氧化的改性形式，所述方法包括插入产物气体混合物A和非均相催化的部分氧化和/或氨氧化之间的至少一个机械分离操作。

7. 发明授权

US07348443B2 Method for producing partial oxidation products and/or partial ammoxidation products of at least one olefinic hydrocarbon 有权
标题翻译：用于制备至少一种烯烃的部分氧化产物和/或部分氨氧化产物的方法
公开(公告)号：US07348443B2
公开(公告)日：2008-03-25
申请号：US10482191
申请日：2002-06-21
申请人： Theo Proll , Otto Machhammer , Goetz-Peter Schindler , Klaus Joachim Mueller-Engel
发明人： Theo Proll , Otto Machhammer , Goetz-Peter Schindler , Klaus Joachim Mueller-Engel
IPC分类号： C07D301/06
CPC分类号： C07C45/33 , B01J27/199 , C07C45/35 , C07C47/22
摘要： Partial oxidation products and/or ammoxidation products of an olefinic hydrocarbon A′ are prepared by a process in which said olefinic hydrocarbon is produced during normal operation by partial dehydrogenation and/or oxydehydrogenation of hydrocarbon A and fed in from another source during partial or complete nonoperation of the dehydrogenation and/or oxydehydrogenation.
摘要翻译：通过一种方法制备烯烃A'的部分氧化产物和/或氨氧化产物，其中在正常操作期间通过部分脱氢和/或烃A的氧化脱氢产生所述烯烃并在部分或完全不操作期间从另一来源进料的脱氢和/或氧化脱氢。

8. 发明授权

US07388109B2 Preparation of acrolein or acrylic acid or a mixture thereof from propane 有权
标题翻译：从丙烷制备丙烯醛或丙烯酸或其混合物
公开(公告)号：US07388109B2
公开(公告)日：2008-06-17
申请号：US11131248
申请日：2005-05-18
申请人： Otto Machhammer , Goetz-Peter Schindler , Christoph Adami , Claus Hechler , Martin Dieterle
发明人： Otto Machhammer , Goetz-Peter Schindler , Christoph Adami , Claus Hechler , Martin Dieterle
IPC分类号： C07C51/16
CPC分类号： C07C45/33 , B01J8/0453 , B01J8/0457 , B41J2/17513 , C07C45/35 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing acrolein or acrylic acid or a mixture thereof from propane, in which the propane is initially dehydrogenated under heterogeneous catalysis to give propene, secondary components are removed and the remaining gas mixture, comprising propane and propene, is subjected to the heterogeneously catalyzed partial oxidation to acrolein or acrylic acid or a mixture thereof as the target product, target product is removed from the product gas mixture and the remaining residual gas, comprising excess oxygen and unconverted propane, is recycled into the propane dehydrogenation in such a way that the other propane fed to the dehydrogenation is at least partly converted under dehydrogenating conditions at the recycle point.
摘要翻译：从丙烷制备丙烯醛或丙烯酸或其混合物的方法，其中丙烷最初在非均相催化下脱氢以得到丙烯，次要组分被除去，剩余的包含丙烷和丙烯的气体混合物经历非均相催化部分氧化成丙烯醛或丙烯酸或其混合物作为目标产物，将目标产物从产物气体混合物中除去，剩余的包含过量氧气和未转化的丙烷的残余气体以这样的方式循环到丙烷脱氢中：进料到脱氢的其它丙烷在再循环点的脱氢条件下至少部分转化。

9. 发明授权

US07176335B2 Method for producing methacrolein from isobutane 失效
标题翻译：从异丁烷生产甲基丙烯醛的方法
公开(公告)号：US07176335B2
公开(公告)日：2007-02-13
申请号：US10482337
申请日：2002-06-28
申请人： Silke Berndt , Klaus Joachim Mueller-Engel , Goetz-Peter Schindler , Frank Rosowski , Jochen Petzoldt
发明人： Silke Berndt , Klaus Joachim Mueller-Engel , Goetz-Peter Schindler , Frank Rosowski , Jochen Petzoldt
IPC分类号： C07C45/29 , C07C51/16 , C07C67/00
CPC分类号： B01J23/002 , B01J27/199 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C47/22 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/43 , B01J2523/828 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/17 , B01J2523/51 , B01J2523/53 , B01J2523/55 , B01J2523/62
摘要： A process prepares methacrolein from isobutane by subjecting isobutane to a partial catalytic dehydrogenation in the gas phase and using the isobutenic product gas mixture to charge an oxidation zone in which the isobutene is oxidized to methacrolein in the gas phase with heterogeneous catalysis using molecular oxygen accompanied by molecular nitrogen as the oxygen source.
摘要翻译：一种方法是通过使异丁烷在气相中进行部分催化脱氢，并使用异丁烯产物气体混合物，在气相中将异丁烯氧化成甲基丙烯醛的氧化区，使用分子氧伴随着非均相催化，由异丁烷制备异丁烯醛分子氮作为氧源。

10. 发明申请

US20050171311A1 Method for the production of butadiene from n-butane 失效
标题翻译：从正丁烷生产丁二烯的方法
公开(公告)号：US20050171311A1
公开(公告)日：2005-08-04
申请号：US10516920
申请日：2003-07-10
申请人： Goetz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
发明人： Goetz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
IPC分类号： B01J23/62 , C07B61/00 , C07C5/333 , C07C11/167 , C08F36/00
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167
摘要： The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译：本发明涉及一种从正丁烷制备丁二烯的方法，包括步骤（A）提供含正丁烷的原料气流，（B）将含正丁烷的进料气流进料到第一脱氢区和非氧化反应将正丁烷催化脱氢为1-丁烯，2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷，1-丁烯和2-丁烯的第一产物气流，（C）将包含或不具有丁二烯和次要组分的正丁烷，1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯，得到包含丁二烯的第二产物气流正丁烷和蒸汽，具有或没有二级组分，（D）从第二产物气流回收丁二烯。

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