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1. 发明申请

US20080264789A1 Film-Type Solid Polymer Ionomer Sensor And Sensor Cell 失效
标题翻译：膜型固体聚合物离聚物离子传感器和传感器单元
公开(公告)号：US20080264789A1
公开(公告)日：2008-10-30
申请号：US12147019
申请日：2008-06-26
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/26
CPC分类号： G01N27/4045 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器电池不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样本的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号

2. 发明授权

US07404882B2 Film-type solid polymer ionomer sensor and sensor cell 失效
标题翻译：薄膜型固体聚合物离子交联聚合物传感器和传感器单元
公开(公告)号：US07404882B2
公开(公告)日：2008-07-29
申请号：US10738858
申请日：2003-12-17
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/407
CPC分类号： G01N27/4045 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area.
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器电池不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样品的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号。

3. 发明授权

US08123923B2 Film-type solid polymer ionomer sensor and sensor cell 失效
标题翻译：薄膜型固体聚合物离子交联聚合物传感器和传感器单元
公开(公告)号：US08123923B2
公开(公告)日：2012-02-28
申请号：US12147019
申请日：2008-06-26
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/407
CPC分类号： G01N27/4045 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area.
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器电池不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样品的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号。

4. 发明授权

US06936147B2 Hybrid film type sensor 失效
标题翻译：混合胶片型传感器
公开(公告)号：US06936147B2
公开(公告)日：2005-08-30
申请号：US10298323
申请日：2002-11-18
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/30 , G01N27/26 , G01N27/333 , G01N27/404 , G01N27/407 , G01N27/416 , G01N27/49 , G01N33/00
CPC分类号： G01N27/4045 , G01N27/4074 , G01N33/004
摘要： A miniaturized gas sensor comprised of thick- or thin-film type electrodes, on a non-conductive supportive substrate, and in contact with a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive substrate. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a constant-voltage, potentiostatic or potentiodynamic mode. A high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which provides contact with the solid ionomer electrolyte, as well as the gas sample via diffusion openings or holes that penetrate through the supportive substrate.
摘要翻译：微型气体传感器由厚膜或薄膜型电极组成，在非导电支撑基底上，并与固体离聚物电解质接触，用于检测有毒气体，即一氧化碳和其他可氧化或可还原的气体并描述蒸气。全固体平面传感器单元具有布置在支撑衬底的非导电平面上的两个或更多个膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器单元不含液体电解质，并以恒定电压，恒电位或电位动力学模式运行。通过用于感测电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，其提供与固体离聚物电解质的接触，以及通过穿过支撑衬底的扩散开口或孔的气体样品。

5. 发明授权

US07601250B2 Hybrid film type sensor 失效
标题翻译：混合胶片型传感器
公开(公告)号：US07601250B2
公开(公告)日：2009-10-13
申请号：US10987825
申请日：2004-11-12
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/407
CPC分类号： G01N27/4045 , G01N27/4074 , G01N33/004
摘要： A miniaturized gas sensor comprised of thick- or thin-film type electrodes, on a non-conductive supportive substrate, and in contact with a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive substrate. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a constant-voltage, potentiostatic or potentiodynamic mode. A high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which provides contact with the solid ionomer electrolyte, as well as the gas sample via diffusion openings or holes that penetrate through the supportive substrate.
摘要翻译：微型气体传感器由厚膜或薄膜型电极构成，在非导电支撑基板上，并与固体离聚物电解质接触，用于检测有毒气体，即一氧化碳和其他可氧化或可还原的气体并描述蒸气。全固体平面传感器单元具有布置在支撑衬底的非导电平面上的两个或更多个膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器单元不含液体电解质，并以恒定电压，恒电位或电位动力学模式运行。通过用于感测电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，其提供与固体离聚物电解质的接触，以及通过穿过支撑衬底的扩散开口或孔的气体样品。

6. 发明授权

US06682638B1 Film type solid polymer ionomer sensor and sensor cell 失效
标题翻译：膜型固体聚合物离聚物传感器和传感器电池
公开(公告)号：US06682638B1
公开(公告)日：2004-01-27
申请号：US09443875
申请日：1999-11-19
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27407
CPC分类号： G01N27/4074 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area.
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器单元不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样本的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号。

7. 发明授权

US07811433B2 Electrochemical carbon dioxide sensor 有权
标题翻译：电化学二氧化碳传感器
公开(公告)号：US07811433B2
公开(公告)日：2010-10-12
申请号：US11252090
申请日：2005-10-17
申请人： Mourad Manoukian , Anthony B. LaConti , Linda A. Tempelman , John Forchione
发明人： Mourad Manoukian , Anthony B. LaConti , Linda A. Tempelman , John Forchione
IPC分类号： G01N27/40
CPC分类号： G01N27/4074
摘要： An electrochemical sensor is provided for the detection of carbon dioxide gas. The sensor includes a non-conductive solid substrate and at least one each of a metal oxide sensing electrode, a reference electrode and a counter electrode positioned on the substrate. A solid polymer electrolyte anion-exchange membrane is in intimate contact with the sensing electrode, reference electrode and counter electrode. The sensor is highly sensitive and selective to carbon dioxide and has very rapid response time.
摘要翻译：提供了一种用于检测二氧化碳气体的电化学传感器。传感器包括非导电固体基板和位于基板上的金属氧化物感测电极，参考电极和对置电极中的至少一个。固体聚合物电解质阴离子交换膜与感测电极，参比电极和对电极紧密接触。传感器对二氧化碳具有高度敏感性和选择性，响应时间非常快。

8. 发明授权

US08361308B2 Electrochemical carbon dioxide sensor 有权
标题翻译：电化学二氧化碳传感器
公开(公告)号：US08361308B2
公开(公告)日：2013-01-29
申请号：US12878504
申请日：2010-09-09
申请人： Mourad Manoukian , Anthony B. Laconti , Linda A. Tempelman , John Forchione
发明人： Mourad Manoukian , Anthony B. Laconti , Linda A. Tempelman , John Forchione
IPC分类号： G01N27/417
CPC分类号： G01N27/4074
摘要： A method for the detection of carbon dioxide gas using an electrochemical sensor. The method includes exposing a gas to a sensor, which includes a non-conductive solid substrate and at least one each of a metal oxide sensing electrode, a reference electrode and a counter electrode positioned on the substrate. A solid polymer electrolyte anion-exchange membrane is in intimate contact with the sensing electrode, reference electrode and counter electrode. The method is highly sensitive and selective to carbon dioxide with a very rapid response time.
摘要翻译：一种使用电化学传感器检测二氧化碳气体的方法。该方法包括将气体暴露于传感器，该传感器包括非导电固体基底和位于基底上的金属氧化物感测电极，参考电极和对置电极中的至少一个。固体聚合物电解质阴离子交换膜与感测电极，参比电极和对电极紧密接触。该方法对二氧化碳具有高度敏感性和选择性，反应时间非常快。

9. 发明申请

US20100276287A1 Multi-gas microsensor assembly 失效
标题翻译：多气体微传感器组件
公开(公告)号：US20100276287A1
公开(公告)日：2010-11-04
申请号：US12660197
申请日：2010-02-22
申请人： Mourad Manoukian , Anthony B. LaConti , W. Michael Krebs , Linda A. Tempelman , John W. Forchione, JR. , Erich Muehlanger, JR.
发明人： Mourad Manoukian , Anthony B. LaConti , W. Michael Krebs , Linda A. Tempelman , John W. Forchione, JR. , Erich Muehlanger, JR.
IPC分类号： G01N27/26 , G01N27/28 , G01N27/407
CPC分类号： G01N27/404
摘要： A multi-gas microsensor assembly for simultaneously detecting carbon dioxide and oxygen in real time. According to one embodiment, the assembly comprises a non-conductive, solid substrate. A plurality of sensing electrodes, a single reference electrode, and a single counter electrode are positioned on one side of the non-conductive, solid substrate. In addition, all of the electrodes are in intimate contact with the same side of a solid-polymer electrolyte anion-exchange membrane, the solid polymer electrolyte membrane having at least one gas diffusion opening aligned with each sensing electrode. The sensor is operated in a three-electrode potentiostatic mode, in which a constant potential is maintained between the sensing and reference electrodes, and the current is measured between the sensing and counter electrodes. Control of the electrodes is achieved with a small bi-potentiostat. The design of the bi-potentiostat allows at least two different sensing electrodes to share the same counter and reference electrodes.
摘要翻译：用于同时检测二氧化碳和氧气的多气体微量传感器组件。根据一个实施例，组件包括非导电固体衬底。多个感测电极，单个参考电极和单个对电极位于非导电固体衬底的一侧。此外，所有电极与固体聚合物电解质阴离子交换膜的同一侧紧密接触，固体聚合物电解质膜具有与每个感测电极对准的至少一个气体扩散开口。传感器在三电极恒电位模式下工作，其中在感测和参考电极之间保持恒定电位，并且在感测和对电极之间测量电流。电极的控制通过小型双电位稳定器实现。双电位器的设计允许至少两个不同的感测电极共享相同的计数器和参考电极。

10. 发明授权

US08366894B2 Multi-gas microsensor assembly 失效
标题翻译：多气体微传感器组件
公开(公告)号：US08366894B2
公开(公告)日：2013-02-05
申请号：US12660197
申请日：2010-02-22
申请人： Mourad Manoukian , Anthony B. LaConti , W. Michael Krebs , Linda A. Tempelman , John W. Forchione, Jr. , Erich Muehlanger, Jr.
发明人： Mourad Manoukian , Anthony B. LaConti , W. Michael Krebs , Linda A. Tempelman , John W. Forchione, Jr. , Erich Muehlanger, Jr.
IPC分类号： G01N27/26 , G01N27/407
CPC分类号： G01N27/404
摘要： A multi-gas microsensor assembly for simultaneously detecting carbon dioxide and oxygen in real time. According to one embodiment, the assembly comprises a non-conductive, solid substrate. A plurality of sensing electrodes, a single reference electrode, and a single counter electrode are positioned on one side of the non-conductive, solid substrate. In addition, all of the electrodes are in intimate contact with the same side of a solid-polymer electrolyte anion-exchange membrane, the solid polymer electrolyte membrane having at least one gas diffusion opening aligned with each sensing electrode. The sensor is operated in a three-electrode potentiostatic mode, in which a constant potential is maintained between the sensing and reference electrodes, and the current is measured between the sensing and counter electrodes. Control of the electrodes is achieved with a small bi-potentiostat. The design of the bi-potentiostat allows at least two different sensing electrodes to share the same counter and reference electrodes.
摘要翻译：用于同时检测二氧化碳和氧气的多气体微量传感器组件。根据一个实施例，组件包括非导电固体衬底。多个感测电极，单个参考电极和单个对电极位于非导电固体衬底的一侧。此外，所有电极与固体聚合物电解质阴离子交换膜的同一侧紧密接触，固体聚合物电解质膜具有与每个感测电极对准的至少一个气体扩散开口。传感器在三电极恒电位模式下工作，其中在感测和参考电极之间保持恒定电位，并且在感测和对电极之间测量电流。电极的控制通过小型双电位稳定器实现。双电位器的设计允许至少两个不同的感测电极共享相同的计数器和参考电极。

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