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    • 1. 发明授权
    • Method for producing a barrier layer in soil
    • 在土壤中生产阻隔层的方法
    • US5120344A
    • 1992-06-09
    • US747467
    • 1991-08-13
    • Oszkar LiborGabor NagyTamas SzekelyRudolf MesterKalman KazareczkiTibor MullerJeno KissZoltan SaghiAdam Hosszu
    • Oszkar LiborGabor NagyTamas SzekelyRudolf MesterKalman KazareczkiTibor MullerJeno KissZoltan SaghiAdam Hosszu
    • A01G25/00C05G3/00C09K17/42
    • C05G3/0047C09K17/42A01G2025/003Y10S106/90Y10S71/903Y10S71/904
    • The present invention relates to a method for producing a closing layer which improves the water and nutrient retention of soils, particularly of sandy soils, characterized in that a layer of clay mineral/polymer gel capable of binding and releasing water in a reversible manner is introduced into the soil, preferably 20-60 cm below the soil surface, in such a way that a clay mineral is reacted either before or after or during activation in the presence of water, with 0.5-30% by weight, calculated for the weight of the clay mineral, of one or more water-soluble polymer capable of reacting with the clay mineral, the water content of the resulting gel is adjusted either before or after or during the reaction to a value at which the resistance of medium of the gel is at least three times higher than that of a polymer-free suspension containing the same amount of the clay mineral, if a non-activated clay mineral has been applied as starting substance, the clay mineral is activated with an alkaline activating agent after reacting it with the polymer, and, if desired, further amounts of a water-soluble polymer, one or more water-insoluble swelling xerogel capable of at least 100% water uptake and forming swollen particles less than 1 mm in diameter and/or one or more chemical for agricultural use, preferably a plant nutrient, a fungicidal substance acting against soil-borne fungi and/or a plant growth increasing substance, is added to the gel either before or after or during the reaction with the polymer, and/or, if desired, the gel and the non-reacted polymer molecules are cross-linked with an aldehyde, and finally the thus-formed gel layer is covered with a soil layer.
    • 本发明涉及一种用于生产封闭层的方法,该方法改善了土壤,特别是沙质土壤的水分和营养物质的保留性,其特征在于引入能够以可逆方式结合和释放水的粘土矿物/聚合物凝胶层 进入土壤,优选在土壤表面下方20-60厘米,使得粘土矿物在水的存在下在活化之前或之后或在水的存在下反应,其重量计为0.5-30重量% 一种或多种能够与粘土矿物反应的水溶性聚合物的粘土矿物,所得凝胶的水含量在反应之前或之后被调节至凝胶介质的电阻为 比含有相同量的粘土矿物的无聚合物悬浮液高至少三倍,如果未活化的粘土矿物被用作起始物质,则粘土矿物被激活 碱性活化剂在与聚合物反应后,如果需要,还可添加一定量的水溶性聚合物,一种或多种能够至少100%吸水并形成直径小于1mm的溶胀颗粒的水不溶性溶胀干凝胶 和/或一种或多种用于农业的化学品,优选植物营养物质,对土壤真菌和/或植物生长增加物质起作用的杀真菌剂,在与聚合物反应之前或期间或之后加入到凝胶中 ,和/或如果需要,凝胶和未反应的聚合物分子与醛交联,最后将如此形成的凝胶层用土壤层覆盖。
    • 2. 发明授权
    • Method for improving the strength and impermeability of soils and
engineering structures
    • 提高土壤和工程结构强度和不渗透性的方法
    • US4988238A
    • 1991-01-29
    • US429945
    • 1989-10-31
    • Tamas SzekelyGabor NagyAndras DankoJanos SzepvolgyiAndras GalOszkar Libor
    • Tamas SzekelyGabor NagyAndras DankoJanos SzepvolgyiAndras GalOszkar Libor
    • C09K17/12C09K17/46
    • C09K17/12C09K17/46
    • A method is disclosed for improving the strength and impermeability of soils or engineering structures, which comprises the steps of:(a) applying to the site of the soil or of the engineering structure, an alkaline water glass solution comprising water glass in an amount of 15 to 40% by weight, calculated as dry substance;(b) allowing a time period to pass sufficient to permit the alkali present in the water glass solution to move by diffusion;(c) applying to the same site as in step (a), a silicic acid sol comprising SiO.sub.2 in an amount of 5 to 50% by weight calculated as dry substance, and an organic dispersion medium in which 10 to 100% by volume of the dispersion medium consists of a water-miscible organic solvent capable of reacting with the alkali content of the water glass solution applied during step (a), thereby gellifying the water glass so that the reaction product of the water-miscible organic solvent and the alkali content of the water glass is trapped within the gelled water glass; and(d) allowing a time period to pass sufficient to permit the respective organic dispersion medium present in the silicic acid sol to move by diffusion, so that gellification of the water glass takes place evenly when mixing of the water glass solution applied during step (a) and the silicic acid sol applied during step (c) to the soils or to the engineering structures takes place to effect a plasticizing effect on the resulting water glass gel.
    • 公开了一种用于改善土壤或工程结构的强度和不渗透性的方法,其包括以下步骤:(a)向土壤或工程结构的位置施加包含水玻璃的碱性水玻璃溶液,其量为 15〜40重量%,以干物质计算; (b)允许时间段通过足以允许水玻璃溶液中存在的碱通过扩散而移动; (c)在与步骤(a)相同的部位施用含有按干物质计5〜50重量%SiO 2的硅酸溶胶,以及有机分散介质,其中10〜100体积% 分散介质由与步骤(a)中施加的水玻璃溶液的碱含量反应的水混溶性有机溶剂组成,从而将水玻璃凝胶化,使水溶性有机溶剂与碱的反应产物 水玻璃的含量被凝固在凝胶水玻璃内; 和(d)允许一段时间通过足以使存在于硅酸溶胶中的各有机分散介质通过扩散移动,使得在步骤期间施加的水玻璃溶液的混合时水玻璃的胶凝化发生均匀( a)和在步骤(c)中施加的硅酸溶胶施加到土壤或工程结构上以对所得水玻璃凝胶进行增塑作用。
    • 5. 发明申请
    • METHOD OF PRODUCING A MODIFIED SMECTITE OR SMECTITE-CONTAINING SUBSTANCE CAPABLE OF TAKING UP AND RELEASING WATER IN A REVERSIBLE MANNER
    • 生产修改后的电解质或含有能量的物质的方法可以在可逆的人中吸收和释放水
    • US20100087580A1
    • 2010-04-08
    • US12597179
    • 2008-04-22
    • Oszkar LiborJacobus Cornelis Wammes
    • Oszkar LiborJacobus Cornelis Wammes
    • C08K3/34
    • C01B33/44C09K17/40E02D31/04
    • The present invention relates to a method for producing a modified smectite or smectite-containing substance capable of forming gels which are not longer thixotropic, have a stable cross-linked structure and adhesive characteristic and are capable of taking up and releasing water in a reversible manner by treating a non-activated smectite or smectite-containing substance with a water soluble activating agent and with a water soluble polymer capable of reacting with said smectite, wherein 0-6% by weight, calculated on the weight of the smectite, of the water soluble activating agent and 0.3-6% by weight, calculated on the weight of the smectite, of the water soluble polymer are admixed with the smectite or smectite-containing substance, wherein: at least a part of the water soluble activating agent is added before and/or at latest simultaneously with the soluble polymer, wherein at least a part of the water soluble polymer is added as a dry solid, the mixture obtained contains an amount of water in a range of from 20% by weight of water to 50% by weight of water, on basis of the mixture.
    • 本发明涉及一种能够形成不具有触变性的凝胶的改性蒙脱石或含蒙脱石的物质的制造方法,具有稳定的交联结构和粘合特性,并且能够以可逆的方式吸收和释放水 通过用水溶性活化剂和能够与所述蒙脱石反应的水溶性聚合物处理未活化的蒙皂石或含蒙脱石的物质,其中根据蒙皂石的重量计算0-6重量%的水 将可溶性活化剂和根据蒙脱石的重量计算的0.3-6重量%的水溶性聚合物与蒙皂石或蒙皂石的物质混合,其中:至少一部分水溶性活化剂在 和/或最初与可溶性聚合物同时,其中至少一部分水溶性聚合物作为干固体加入,所得混合物含有一定量的 的水的范围为20重量%的水至50重量%的水,基于混合物。
    • 7. 发明授权
    • Clay-containing mixture and blend capable of forming a moisture
resistant gel, and use of that mixture and blend
    • 含有粘土的混合物和能够形成防潮凝胶的共混物,并使用该混合物和共混物
    • US5604168A
    • 1997-02-18
    • US495511
    • 1995-11-17
    • Oszkar Libor
    • Oszkar Libor
    • C09K17/22C01B33/40C04B41/00C09K17/00C09K17/42C09K17/48C09K103/00C04B33/00
    • C09K17/42Y10S106/90Y10S71/903
    • A dry mixture of (a) powdered or ground smectite and/or a smectite-containing natural rock, wherein the smectite is in an inactive state, (b) 1-10% by weight of a water-soluble polymer and (c) 0.8-6.0% by weight of a powdered activating agent can be combined with soil and water to provide a gel which is a barrier composition. The mixture may additionally contain a diluting agent, so as to form a dry blend, where the blend may likewise be combined with soil and water to provide a gel which is a barrier composition. The blend may be used to provide for water-tight insulation of vasins, damps and other objects exposed to damaging effects of water, and may also be used as a sealing for deponies, as a protecting layer for articles exposed to acidic liquids, and as a filling agent for cavities and cracks on articles exposed to water.
    • PCT No.PCT / NL94 / 00017 Sec。 371日期:1995年11月17日 102(e)1995年11月17日日期PCT 1994年1月25日PCT PCT。 第WO94 / 18284号公报 日期1994年8月18日(a)(a)粉状或研磨蒙脱石和/或蒙皂石的天然岩石的干混合物,其中蒙皂石处于非活性状态,(b)1-10重量%的水溶性聚合物 和(c)0.8-6.0重量%的粉末状活化剂可与土壤和水组合以提供作为阻隔组合物的凝胶。 混合物可以另外含有稀释剂,以便形成干混合物,其中共混物同样可与土壤和水组合以提供作为阻隔组合物的凝胶。 混合物可用于提供暴露于水的破坏作用的瓦斯,马桶和其他物体的防水绝缘,并且还可以用作污染物的密封,作为暴露于酸性液体的制品的保护层,以及作为 用于暴露于水的制品上的空腔和裂缝的填充剂。