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    • 10. 发明授权
    • Hydrogen storage alloy electrode and method for manufacturing the same
    • 储氢合金电极及其制造方法
    • US06309779B1
    • 2001-10-30
    • US09502537
    • 2000-02-11
    • Yoichiro TsujiOsamu YamamotoYoshinori ToyoguchiHiromu Matsuda
    • Yoichiro TsujiOsamu YamamotoYoshinori ToyoguchiHiromu Matsuda
    • H01M438
    • H01M4/383C01B3/0052H01M4/242Y02E60/327Y10S420/90
    • A hydrogen storage alloy electrode having a high capacity and excellent cycle characteristics is provided. The electrode is made from particulate active material comprising a hydrogen storage alloy of body-centered cubic crystal structure or body-centered tetragonal crystal structure, said hydrogen storage alloy being represented by the general formula TiaM1bCrcM2dLe, wherein M1 is at least one element selected from the group consisting of Nb and Mo; M2 is at least one element selected from the group consisting of Mn, Fe, Co, Cu, V, Zn, Zr, Ag, Hf, Ta, W, Al, Si, C, N, P and B; L is at least one element selected from the group consisting of rare-earth elements and Y; 0.2≦a≦0.7; 0.01≦b≦0.4; 0.1≦c≦0.7; 0≦d≦0.3; 0≦e≦0.03; and a+b+c+d+e=1.0, and said particulate active material having a Ti—Ni system alloy phase in the surface portion thereof.
    • 提供具有高容量和优异的循环特性的储氢合金电极。 电极由包含体心立方晶体结构或体心四方晶体结构的储氢合金的粒状活性物质制成,所述储氢合金由通式TiaM1bCrcM2dLe表示,其中M1为选自 由Nb和Mo组成的组; M2是选自Mn,Fe,Co,Cu,V,Zn,Zr,Ag,Hf,Ta,W,Al,Si,C,N,P和B中的至少一种元素; L是选自由稀土元素和Y组成的组中的至少一种元素; 0.2 <= a <= 0.7; 0.01 <= b <= 0.4; 0.1 <= c <= 0.7; 0 <= d <= 0.3; 0 <= e <= 0.03; a + b + c + d + e = 1.0,所述粒状活性物质在其表面部分具有Ti-Ni系合金相。