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1. 发明授权

US5308908A Polypropylene resin composition 失效
标题翻译：聚丙烯树脂组合物
公开(公告)号：US5308908A
公开(公告)日：1994-05-03
申请号：US936389
申请日：1992-08-28
申请人： Osamu Fukui , Kouhei Ueno , Yoshifumi Nakano , Ikunori Sakai , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
发明人： Osamu Fukui , Kouhei Ueno , Yoshifumi Nakano , Ikunori Sakai , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
IPC分类号： C08K3/34 , C08L23/08 , C08L23/16 , C08L53/00 , C08L23/04
CPC分类号： C08K3/34 , C08L53/00 , C08L2205/02 , C08L23/0815 , C08L23/16
摘要： A polypropylene resin composition comprising:(A) 45 to 70% by weight of an ethylene-propylene block copolymer synthesized under the process comprising the steps of;(a) polymerizing propylene with a Ziegler-Natta catalyst to obtain a highly crystalline polypropylene that contain not less than 97% by weight of a fraction insoluble in boiling n-heptane, and(b) copolymerizing ethylene with the polypropylene (a), and which(a) contains 0.5 to 10% by weight of ethylene,(b) contains 5 to 20% by weight of a fraction being soluble in p-xylene at room temperature and having an intrinsic viscosity value of not less than 2 (measured in decalin at 135.degree. C.),(c) has a melt-flow index value of 30 to 100 g/10 min., and,(d) has a value of flexural modulus of not less than 18,000 kg/cm.sup.2,(B) 10 to 20% by weight of an amorphous ethylene-propylene copolymer having(a) an ethylene content of 70 to 90% by weight,(b) a Mooney viscosity value (ML.sub.1+4 at 100.degree. C.) of 5 to 70,(C) 5 to 15% by weight of an ethylene-.alpha.-olefin copolymer having(a) an .alpha.-olefin content of 5 to 15% by mole,(b) a value of gravity of not more than 0.91, and(c) a melt-flow index value of 2.2 to 50 g/10 min. at 230.degree. C.,(D) 1 to 10% by weight of an amorphous ethylene-butene copolymer having(a) a butene content of 10 to 25% by weight, and(b) a Mooney viscosity value (ML.sub.1+4, at 100.degree. C.) of 5 to 20,(E) not more than 15% by weight of a talc that(a) has an average diameter D50 of from 1.0 to 3.0 .mu.m, and(b) does not contain a particle having a diameter of 10 .mu.m or more,wherein the component (B) is rubber reinforced by lamellae of components (C) and (D).
摘要翻译：一种聚丙烯树脂组合物，其包含：（A）45至70重量％的在包括以下步骤的方法中合成的乙烯 - 丙烯嵌段共聚物：（a）用齐格勒 - 纳塔催化剂聚合丙烯以获得含有不少于97重量％不溶于沸腾正庚烷的馏分的高度结晶的聚丙烯，和（b）使乙烯与聚丙烯（a）共聚，和（a）含有0.5〜10重量％的乙烯，（b）在室温下含有5〜20重量％的可溶于对二甲苯的馏分，其特性粘度值不小于2（以十氢萘在135℃），（c）的熔体流动指数值为30〜100g / 10分钟，（d）弯曲弹性模量值不小于18,000kg / cm 2，（B ）10〜20重量％的（a）乙烯含量为70〜90重量％，（b）门尼粘度值（100℃时ML1 + 4）为5〜70的无定形乙烯 - 丙烯共聚物，（C）5〜15重量％的（a）α-烯烃含量为5〜15摩尔％的乙烯-α-烯烃共聚物，（b）重力值不大于0.91，（ c）熔体流动inde x值为2.2〜50g / 10min。（D）1〜10重量％的（a）丁烯含量为10〜25重量％的无定形乙烯 - 丁烯共聚物，（b）门尼粘度值（ML1 + 4，在100℃下为5〜20，（E）不超过15重量％的滑石，（a）平均直径D50为1.0〜3.0μm，（b）不含有颗粒其直径为10μm以上，其中，成分（B）由成分（C）和（D）的薄片橡胶增强。

2. 发明授权

US5438091A Resin composition having excellent paint coatability 失效
标题翻译：树脂组合物具有优异的涂漆性
公开(公告)号：US5438091A
公开(公告)日：1995-08-01
申请号：US329136
申请日：1994-10-25
申请人： Yoshiharu Saito , Masao Sakaizawa , Kunio Iwanami , Kitsusho Kitano , Michihisa Tasaka , Kenji Kawazu , Shizuo Miyazaki , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
发明人： Yoshiharu Saito , Masao Sakaizawa , Kunio Iwanami , Kitsusho Kitano , Michihisa Tasaka , Kenji Kawazu , Shizuo Miyazaki , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
IPC分类号： C08K3/00 , C08L23/16 , C08L53/00
CPC分类号： C08L53/00 , C08K3/0033 , C08L23/16
摘要： A resin composition having excellent paint coatability containing (a) 50-80 weight % of a multi-stage polymerized propylene-ethylene block copolymer consisting essentially of (i) a propylene homopolymer portion, (ii) a propylene-ethylene random copolymer portion, and (iii) an ethylene homopolymer portion, (b) 20-40 weight % of an ethylene-.alpha.-olefin copolymer elastomer, and (c) 20 weight % or less of an inorganic filler, components in the components (a) and (b), which are soluble in p-xylene at a room temperature, having a number-average molecular weight of 4.times.10.sup.4 or more and a weight-average molecular weight of 20.times.10.sup.4 or more.
摘要翻译：一种树脂组合物，其具有优异的涂布性，其包含（a）50-80重量％的多阶段聚合丙烯 - 乙烯嵌段共聚物，其基本上由（i）丙烯均聚物部分，（ii）丙烯 - 乙烯无规共聚物部分和（iii）乙烯均聚物部分，（b）20-40重量％的乙烯-α-烯烃共聚物弹性体，和（c）20重量％或更少的无机填料，组分（a）和（b）中的组分），其在室温下可溶于对二甲苯，其数均分子量为4×10 4以上，重均分子量为20×10 4以上。

3. 发明授权

US6121363A Crystalline propylene block-copolymer composition for use in automobile parts 失效
标题翻译：用于汽车零件的结晶丙烯嵌段共聚物组合物
公开(公告)号：US6121363A
公开(公告)日：2000-09-19
申请号：US251331
申请日：1999-02-17
申请人： Ikunori Sakai , Mikio Hashimoto , Takayuki Nagai , Takao Nomura , Masatoshi Matsuda , Osamu Kito , Hisayuki Iwai
发明人： Ikunori Sakai , Mikio Hashimoto , Takayuki Nagai , Takao Nomura , Masatoshi Matsuda , Osamu Kito , Hisayuki Iwai
IPC分类号： B29C45/00 , B29K23/00 , C08K3/34 , C08L53/00 , C08L53/02 , C08K3/22 , C08L23/10
CPC分类号： C08L53/00
摘要： A crystalline propyleiie block-copolymer composition exhibiting superior flowability upon molding for use in automobile parts, which composition comprises 41 to 71% by weight of a crystalline propylene block-copolymer composed of a propylene homopolymer portion (Fp) and an ethylene/propylene random copolymer portion (Fc) and having an ethylene content of 1 to 10% by weight and a melt flow rate (MFR) of 20 to 100 g/10 min.; 12 to 22% by weight of a first hydrogenated product of a block-copolymer having a relatively smaller stylene content; 2 to 12% by weight of a second hydrogenated product of a block-copolymer having a relatively greater stylene content; and 15 to 25% by weight of talc, wherein the propylene homopolymer portion (Fp) contains 20 to 50% by weight of a low molecular weight propylene homopolymer having an MFR of 400 to 1,000 g/10 min., the average MFR being 100 to 350 g/10 min. and the isotactic pentad fraction being at least 98%, and wherein the said (Fc) has an intrinsic viscosity of 7 dl/g or higher.
摘要翻译：一种结晶丙烯嵌段共聚物组合物，其成型用于汽车部件时具有优异的流动性，该组合物包含41至71重量％的由丙烯均聚物部分（Fp）和乙烯/丙烯无规共聚物组成的结晶丙烯嵌段共聚物（Fc），乙烯含量为1〜10重量％，熔体流动速率（MFR）为20〜100g / 10分钟。 12至22重量％的具有相对较小的苯乙烯含量的嵌段共聚物的第一氢化产物; 2至12重量％的具有相对较大的苯乙烯含量的嵌段共聚物的第二个氢化产物; 和15〜25重量％的滑石，其中丙烯均聚物部分（Fp）含有20〜50重量％的MFR为400〜1000g / 10分钟的低分子量丙烯均聚物，平均MFR为100 至350g / 10min。和全同立构五单元组分数为98％以上，其中所述（Fc）的特性粘度为7dl / g以上。

4. 发明授权

US5461105A Resin composition having excellent paint coatability 失效
公开(公告)号：US5461105A
公开(公告)日：1995-10-24
申请号：US415566
申请日：1995-04-03
申请人： Yoshiharu Saito , Masao Sakaizawa , Kunio Iwanami , Kitsusho Kitano , Michihisa Tasaka , Kenji Kawazu , Shizuo Miyazaki , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
发明人： Yoshiharu Saito , Masao Sakaizawa , Kunio Iwanami , Kitsusho Kitano , Michihisa Tasaka , Kenji Kawazu , Shizuo Miyazaki , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
IPC分类号： C08K3/00 , C08L23/16 , C08L53/00
CPC分类号： C08K3/0033 , C08L23/16 , C08L53/00
摘要： A resin composition having excellent paint coatability containing (a) 50-80 weight % of a multi-stage polymerized propylene-ethylene block copolymer consisting essentially of (i) a propylene homopolymer portion, (ii) a propylene-ethylene random copolymer portion, and (iii) an ethylene homopolymer portion, (b) 20-40 weight % of an ethylene-.alpha.-olefin copolymer elastomer, and (c) 20 weight % or less of an inorganic filler, components in the components (a) and (b), which are soluble in p-xylene at a room temperature, having a number-average molecular weight of 4.times.10.sup.4 or more and a weight-average molecular weight of 20.times.10.sup.4 or more.

5. 发明授权

US5567759A Propylene polymer composition 失效
标题翻译：丙烯聚合物组成
公开(公告)号：US5567759A
公开(公告)日：1996-10-22
申请号：US427623
申请日：1995-04-21
申请人： Hiroshi Taniguchi , Akihiko Yamamoto , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
发明人： Hiroshi Taniguchi , Akihiko Yamamoto , Takao Nomura , Takeyoshi Nishio , Hisayuki Iwai
IPC分类号： C08K3/34 , C08L53/00
CPC分类号： C08L53/00 , C08K3/34
摘要： Propylene polymer compositions of the present invention comprising a specific propylene block copolymer, specific ethylene-propylene copolymer rubber, specific ethylene-propylene-diene copolymer rubber, specific ethylene-butene-1 copolymer rubber, and talc in specific proportions are provided. The propylene polymer compositions of the invention are capable of providing therefrom molded products excellent in balance between stiffness and impact resistance, and having high surface hardness with excellent scratch resistance.
摘要翻译：提供了包含特定丙烯嵌段共聚物，特定乙烯 - 丙烯共聚物橡胶，特定乙烯 - 丙烯 - 二烯共聚物橡胶，特定乙烯 - 丁烯-1共聚物橡胶和特定比例的滑石的本发明丙烯聚合物组合物。本发明的丙烯聚合物组合物能够提供刚性和抗冲击性之间的平衡优异的模塑制品，并且具有高的表面硬度和优异的耐擦伤性。

6. 发明授权

US06180709B2 Thermoplastic polypropylene composition 失效
标题翻译：热塑性聚丙烯组合物
公开(公告)号：US06180709B2
公开(公告)日：2001-01-30
申请号：US09079291
申请日：1998-05-15
申请人： Takeyoshi Nishio , Takayuki Nagai , Hisayuki Iwai , Yukihito Zanka , Izumi Ishii , Hiroki Satoh , Yoshihiro Sobajima , Mitsuhiro Murayama
发明人： Takeyoshi Nishio , Takayuki Nagai , Hisayuki Iwai , Yukihito Zanka , Izumi Ishii , Hiroki Satoh , Yoshihiro Sobajima , Mitsuhiro Murayama
IPC分类号： C08K334
CPC分类号： C08L53/00 , C08L2205/02 , C08L2205/06 , C08L2205/08 , C08L2666/04 , C08L2666/24
摘要： There is provided a thermoplastic resin composition comprising the following components (A) to (E): component (A): 50 to 74.7% by weight of a Ziegler-Natta catalyst sequentially polymerized blend of a propylene homopolymer and an ethylene-propylene copolymer, component (B): 5 to 10% by weight of an ethylene-octene random copolymer, component (C): 5 to 10% by weight of an ethylene-butene random copolymer, component (D): 0.3 to 5% by weight of an elastomer.
摘要翻译：提供了包含以下组分（A）至（E）的热塑性树脂组合物：组分（A）：50-74.7重量％的齐格勒 - 纳塔催化剂顺序聚合的丙烯均聚物和乙烯 - 丙烯共聚物的共混物，组分（B）：5-10重量％的乙烯 - 辛烯无规共聚物，组分（C）：5-10重量％的乙烯 - 丁烯无规共聚物，组分（D）：0.3-5重量％弹性体。

7. 发明授权

US6156836A Polypropylene resin composition 失效
标题翻译：聚丙烯树脂组合物
公开(公告)号：US6156836A
公开(公告)日：2000-12-05
申请号：US220440
申请日：1998-12-24
申请人： Kunio Iwanami , Akira Kobayashi , Mitsuhiro Murayama , Yuji Fujita , Takayuki Nagai , Takao Nomura , Masatoshi Matsuda , Osamu Kito , Hisayuki Iwai
发明人： Kunio Iwanami , Akira Kobayashi , Mitsuhiro Murayama , Yuji Fujita , Takayuki Nagai , Takao Nomura , Masatoshi Matsuda , Osamu Kito , Hisayuki Iwai
IPC分类号： C08L53/00 , C08L53/02 , C08K3/34 , C08L23/12 , C08L23/16
CPC分类号： C08L53/00 , C08L53/02 , C08L53/025
摘要： This invention provides polypropylene resin compositions which have sharply improved balance of physical properties in comparison with the related polypropylene materials, are materials that can be used in both interior and exterior parts of automobiles, have excellent thin-wall moldability and can sharply reduce generation of flow marks. Particularly, it provides a polypropylene resin composition which comprises specified amounts of (A) a specified ethylene-propylene block copolymer, (B) a specified thermoplastic elastomer and (C) talc, wherein it has specified values of physical properties measured by ASTM and has a degree of b-axis orientation of 720 or more which is calculated from the ratio of differential peak intensities measured by wide-angle X-ray diffraction of the central area of an ASTM No. 1 dumbbell prepared by injection molding.
摘要翻译：本发明提供与相关聚丙烯材料相比具有明显改善的物理平衡平衡的聚丙烯树脂组合物，可用于汽车内外部的材料，具有优异的薄壁成型性，并可大大减少流动的产生分数。特别地，它提供了一种聚丙烯树脂组合物，其包含规定量的（A）特定的乙烯 - 丙烯嵌段共聚物，（B）特定的热塑性弹性体和（C）滑石，其中其具有通过ASTM测量的具体的物理性质值，并具有由通过注射成型制备的ASTM No.1哑铃的中心区域的广角X射线衍射测得的差峰值强度的比率计算出的720°以上的b轴取向度。

8. 发明授权

US06759465B1 Thermoplastic resin composition and injection-molded object thereof 有权
标题翻译：热塑性树脂组合物及其注射成型体
公开(公告)号：US06759465B1
公开(公告)日：2004-07-06
申请号：US09720343
申请日：2000-12-22
申请人： Moriyasu Shimojo , Kenichi Ohkawa , Susumu Kanzaki , Takayuki Nagai , Takao Nomura , Masatoshi Matsuda , Hisayuki Iwai
发明人： Moriyasu Shimojo , Kenichi Ohkawa , Susumu Kanzaki , Takayuki Nagai , Takao Nomura , Masatoshi Matsuda , Hisayuki Iwai
IPC分类号： C08K334
CPC分类号： C08L23/10 , C08L23/0815 , C08L23/16 , C08L25/00 , C08L53/00 , C08L53/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/06 , C08L2666/04
摘要： A thermoplastic composition which is obtained by melt-kneading (1) 55 to 75 wt. % crystalline polypropylene resin together with (2) 10 to 30 wt. % elastomer comprising either a rubber containing a vinyl aromatic compound or a mixture thereof with an ethylene/&agr;-olefin random copolymer rubber and (3) 15 to 25 wt. % talc having an average particle diameter of 3 &mgr;m or smaller. The composition satisfies specific requirements with respect to: the long period obtained by X-ray small-angle scattering attributable to the vinyl aromatic-containing rubber in a blend obtained by melt-kneading the ingredients (1) and (2); the shape and diameter of the elastomer particles present near the polypropylene/elastomer interface in the blend; and the difference between the glass transition point of the ingredient (1) and that of the composition attributable to the crystalline polypropylene homopolymer parts. The composition has a satisfactory balance between impact resistance and rigidity and has excellent injection moldability.
摘要翻译：通过熔融捏合（1）55〜75重量％％结晶聚丙烯树脂与（2）10〜30重量％包括含有乙烯基芳族化合物的橡胶或其与乙烯/α-烯烃无规共聚物橡胶的混合物的弹性体，和（3）15至25wt。平均粒径为3μm以下的滑石粉。该组合物满足以下特征：通过熔融捏合成分（1）和（2）获得的共混物中通过由含乙烯基芳族化合物橡胶得到的X射线小角度散射得到的长时间; 存在于共混物中聚丙烯/弹性体界面附近的弹性体颗粒的形状和直径; 和成分（1）的玻璃化转变点与归因于结晶聚丙烯均聚物部件的组合物的玻璃化转变点之间的差异。组合物在耐冲击性和刚性之间具有令人满意的平衡，并且具有优异的注模成型性。

9. 发明授权

US06667359B1 Polypropylene compositions for automotive parts 有权
标题翻译：汽车零件用聚丙烯组合物
公开(公告)号：US06667359B1
公开(公告)日：2003-12-23
申请号：US09599884
申请日：2000-06-23
申请人： Masaru Nakagawa , Koki Hirano , Yutaka Obata , Yasuhisa Sugita , Takao Nomura , Masatoshi Matsuda , Hisayuki Iwai , Takayuki Nagai
发明人： Masaru Nakagawa , Koki Hirano , Yutaka Obata , Yasuhisa Sugita , Takao Nomura , Masatoshi Matsuda , Hisayuki Iwai , Takayuki Nagai
IPC分类号： C08K334
CPC分类号： C08L53/00 , C08L53/025 , C08L2666/06
摘要： There are disclosed a polypropylene composition for automotive parts which has a melt index at 230° C. and at 2.16 kgf of at least 30 g/10 minutes and which comprises 55 to 60% by weight of (1) propylene/ethylene block copolymer; 20 to 25% by weight of (2) rubber comprising a styrene/ethylene/propylene/styrene block copolymer and/or a styrene/ethylene/1-butene/styrene block copolymer and an olefinic elastomer; and 18 to 23% by weight of (3) talc, and also an automotive part which comprises the above polypropylene composition.
摘要翻译：公开了一种用于汽车部件的聚丙烯组合物，其在230℃和2.16kgf下的熔体指数为至少30g / 10分钟，并且包含55至60重量％的（1）丙烯/乙烯嵌段共聚物; 20至25重量％的（2）包含苯乙烯/乙烯/丙烯/苯乙烯嵌段共聚物和/或苯乙烯/乙烯/ 1-丁烯/苯乙烯嵌段共聚物和烯烃弹性体的橡胶; （3）滑石的18〜23重量％，以及包含上述聚丙烯组合物的汽车部件。

10. 发明授权

US06441081B1 Polypropylene-base resin composition and products of injection molding thereof 有权
标题翻译：聚丙烯基树脂组合物及其注射成型品
公开(公告)号：US06441081B1
公开(公告)日：2002-08-27
申请号：US09555826
申请日：2000-07-11
申请人： Hajime Sadatoshi , Kenichi Ohkawa , Susumu Kanzaki , Hisayuki Iwai , Takao Nomura , Shoichi Ichikawa
发明人： Hajime Sadatoshi , Kenichi Ohkawa , Susumu Kanzaki , Hisayuki Iwai , Takao Nomura , Shoichi Ichikawa
IPC分类号： C08K334
CPC分类号： C08L23/12 , C08F297/083 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L53/00 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： A polypropylene resin composition which comprises: (1) 55 to 75% by weight of (A) a polypropylene resin consisting of a mixture of the following polymers (i) and (ii): (i) a propylene-ethylene block copolymer having a propylene homopolymer part which is the first segment and having a propylene-ethylene random copolymer part which is the second segment and (ii) a propylene homopolymer having an intrinsic viscosity [&eegr;]P of 0.8 to 1.8 dl/g as measured in tetralin at 135° C., (2) 21 to 30% by weight of (B) an ethylene-1-octene copolymer rubber having a melt flow rate (JIS-K-6758 at 190° C.) of 2 to 10 g/10 min and having a 1-octene component content of 20 to 25% by weight, and (3) 5 to 20% by weight of (C) talc having an average particle diameter of not more than 3 &mgr;m, wherein when the amount of the second segment contained in the propylene-ethylene block copolymer of the polypropylene resin (A) is designated as (A)′ and the ethylene-1-octene copolymer rubber content is designated as (B)′, the following expression is satisfied: 0.10≦{(A)′/[(A)′+(B)′]}≦0.30, and when the above composition is subjected to a tensile test according to ASTM D638, it exhibits, an ultimate elongation of at least 400%, and the melt flow rate (JIS-K-6758 at 230° C.) of the composition is at least 30 g/10 min, and an injection-molded article obtained by injection molding the above polypropylene resin composition.
摘要翻译：一种聚丙烯树脂组合物，其包含：（1）55至75重量％的（A）由以下聚合物（i）和（ii）的混合物组成的聚丙烯树脂：（i）丙烯 - 乙烯嵌段共聚物，其具有丙烯均聚物部分，其是第一链段并且具有作为第二链段的丙烯 - 乙烯无规共聚物部分和（ii）在135℃下在四氢化萘中测得的特性粘度ηP为0.8至1.8dl / g的丙烯均聚物（2）熔体流动速率（JIS-K-6758，190℃）的（B）乙烯-1-辛烯共聚物橡胶的21〜30重量％为2〜10g / 10分钟并且具有20至25重量％的1-辛烯组分含量，和（3）5至20重量％的（C）平均粒径不大于3μm的滑石，其中当第二包含在聚丙烯树脂（A）的丙烯 - 乙烯嵌段共聚物中的链段被称为（A）'，乙烯-1-辛烯共聚物橡胶含量指定为（B）'，满足以下表达式：当根据ASTM D638对上述组合物进行拉伸试验时，其表现出至少400％的极限伸长率和熔体流动速率（JIS-K-6758在230℃））为30g / 10分钟以上，注射成型上述聚丙烯树脂组合物得到的注射成型体。

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