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1. 发明授权

US4987106A Process for producing clay mineral of chain structure 失效
标题翻译：链结构粘土矿物生产工艺
公开(公告)号：US4987106A
公开(公告)日：1991-01-22
申请号：US457835
申请日：1989-12-27
申请人： Tadashi Mizutani , Yoshiaki Fukushima , Haruo Doi , Osami Kamigaito
发明人： Tadashi Mizutani , Yoshiaki Fukushima , Haruo Doi , Osami Kamigaito
IPC分类号： C01B33/26 , B28C1/00 , C01B25/45 , C01B33/20 , C01B33/22 , C01B33/36 , C01B33/40 , C01B33/44
CPC分类号： B28C1/006 , C01B33/36 , C01B33/405 , C01B33/44
摘要： A process for producing a clay mineral of chain structure such as sepiolite and attapulgite. The process comprises suspending a metal silicate gel in an aqueous solution which has a pH value of 3-11 at room temperature and contains a clay mineral of chain structure suspending therein, and then heating the resulting suspension at a temperature below 350.degree. C. According to this process, it is possible to produce a clay mineral of chain structure in a simple, stable manner.
摘要翻译：一种生产链状结构的粘土矿物的方法，如海泡石和绿坡缕石。该方法包括在室温下将金属硅酸盐凝胶悬浮在pH值为3-11的水溶液中，并含有悬浮在其中的链状结构的粘土矿物，然后在低于350℃的温度下加热得到的悬浮液。根据在该过程中，可以以简单，稳定的方式生产链结构的粘土矿物。

2. 发明授权

US4486235A Clay mineral sheet 失效
标题翻译：粘土矿物片
公开(公告)号：US4486235A
公开(公告)日：1984-12-04
申请号：US506222
申请日：1983-06-21
申请人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
发明人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
IPC分类号： C04B30/00 , C09K3/00 , B05D1/18 , B32B5/16
CPC分类号： C04B30/00 , Y10T428/2982 , Y10T428/2993 , Y10T428/2995 , Y10T428/31663
摘要： The vermiculite sheet is immersed in a silane compound in liquid state so that the silane compound is permeated into the sheet to react with the water absorbed on the whole surface of each thin leave of vermiculite and to form silanol. Thin leaves of vermiculite are strongly bonded with one another through such silanol to form a strong composite sheet.
摘要翻译：将蛭石片浸入液态的硅烷化合物中，使得硅烷化合物渗透到片中以与每个薄蛭石的整个表面吸收的水反应并形成硅烷醇。蛭石的薄叶通过这种硅烷醇彼此牢固地结合以形成强的复合片材。

3. 发明授权

US4497869A Formed product of vermiculite and method for producing the same 失效
标题翻译：蛭石成型品及其制造方法
公开(公告)号：US4497869A
公开(公告)日：1985-02-05
申请号：US476014
申请日：1983-03-15
申请人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
发明人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
IPC分类号： C04B30/00 , C04B14/20 , C04B26/02 , C04B30/02 , B32B3/26
CPC分类号： C04B30/02 , C04B14/206 , C04B26/02 , Y10T428/2911 , Y10T428/2982
摘要： A formed product of vermiculite comprising thin leaves of vermiculite containing cations of one or more elements selected from the group consisting of copper, aluminum, manganese, II group elements, IV group elements and VIII group elements, substituted for exchangeable cations retained in vermiculite. Such a formed vermiculite product has high strength as well as excellent heat resistance. The formed product of vermiculite can be obtained by a method comprising the steps of crushing vermiculite to obtain thin leaves thereof, subjecting the thin leaves to ion exchange to substitute exchangeable cations retained therein by cations of one or more elements selected from the group consisting of copper, aluminum, manganese, II group elements, IV group elements and VIII group elements, and forming the resulting thin leaves into a stack or laminate. The formed vermiculite product thus obtained can retain further properties, such as an ability to expand and water resistance. More particularly, when the formed product (subjected to such ion exchange) is contacted with hydrogen peroxide, the resulting expanded formed product of vermiculite is suitable as a fixing material, shock absorber and the like, further retaining excellent compressibility, on the other hand, the product is heated in an oxidative atmosphere to obtain a formed vermiculite product having excellent water resistance as well as high strength, which is useful for a heat-insulating material and a refractory-facing material for a building.
摘要翻译：包含蛭石的成形物，其包含选自铜，铝，锰，II族元素，IV族元素和VIII族元素中的一种或多种元素的阳离子的蛭石的叶，代替保留在蛭石中的可交换阳离子。这种形成的蛭石产品具有高强度以及优异的耐热性。蛭石的形成产物可以通过包括以下步骤的方法获得，该方法包括以下步骤：碾碎蛭石以获得其薄的叶片，使薄叶片进行离子交换，以使其中保留的可交换的阳离子中的一种或多种元素的阳离子选自铜，铝，锰，II族元素，IV族元素和VIII族元素，并将所得薄叶形成为叠层或层压体。由此获得的成形蛭石产品可以保持进一步的性能，例如膨胀能力和耐水性。更具体地，当形成的产品（经过这样的离子交换）与过氧化氢接触时，所得到的蛭石膨胀成型产品适合作为固定材料，减震器等，另外保持优异的压缩性，将产物在氧化气氛中加热以获得具有优异的耐水性和高强度的成形蛭石产品，其可用于建筑物的绝热材料和耐火材料材料。

4. 发明授权

US4472538A Composite material composed of clay mineral and organic high polymer and method for producing the same 失效
标题翻译：由粘土矿物和有机高分子组成的复合材料及其制造方法
公开(公告)号：US4472538A
公开(公告)日：1984-09-18
申请号：US318862
申请日：1981-11-06
申请人： Osami Kamigaito , Yoshiaki Fukushima , Haruo Doi
发明人： Osami Kamigaito , Yoshiaki Fukushima , Haruo Doi
IPC分类号： C08K3/00 , C08F2/00 , C08F2/44 , C08F4/00 , C08F4/42 , C08F4/58 , C08F4/72 , C08F36/06 , C08F292/00 , C08G83/00 , C08K3/34 , C08K3/36 , C08L7/00 , C08L21/00 , C09C1/42 , C08K3/10
CPC分类号： C09C1/42 , C08F2/44 , C08F36/06 , C08G83/001 , C01P2002/08 , C01P2002/72 , C01P2002/82 , C01P2002/88 , C01P2006/32 , C01P2006/90 , Y10S428/92 , Y10S428/921 , Y10T428/2995 , Y10T428/2998
摘要： A composite material is provided by contacting a clay mineral having laminated aluminum silicate layers with an organic monomer to allow the organic monomer to be adsorbed on or intercalated between the aluminum silicate layers, and contacting the clay mineral with a silane compound having 2 to 4 chlorine atoms to promote polymerization of the organic monomer, thereby forming a composite material composed of a clay mineral having organic high polymer adsorbed thereon or intercalated therebetween. The composite material thus obtained has a strong chemical bond between inorganic clay mineral and organic high polymer.
摘要翻译：通过使具有层叠铝硅酸盐层的粘土矿物与有机单体接触以使有机单体吸附在硅酸铝层之间或插入硅酸铝层之间并使粘土矿物与具有2-4个氯的硅烷化合物接触来提供复合材料原子以促进有机单体的聚合，从而形成由其上吸附有有机高聚物的粘土矿物或其间插入的复合材料。由此获得的复合材料在无机粘土矿物和有机高分子之间具有强烈的化学键。

5. 发明授权

US06194650B1 Coated object and process for producing the same 有权
标题翻译：涂层物体及其制造方法
公开(公告)号：US06194650B1
公开(公告)日：2001-02-27
申请号：US09297051
申请日：1999-04-27
申请人： Hiroaki Wakayama , Yoshiaki Fukushima , Narihito Tatsuda , Yoshitsugu Kojima , Osami Kamigaito , Yasutomo Goto , Shinji Inagaki , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Kazuo Higuchi , Norihiko Setoyama
发明人： Hiroaki Wakayama , Yoshiaki Fukushima , Narihito Tatsuda , Yoshitsugu Kojima , Osami Kamigaito , Yasutomo Goto , Shinji Inagaki , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Kazuo Higuchi , Norihiko Setoyama
IPC分类号： H01L3100
CPC分类号： H01G4/005 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3236 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/38 , B01J23/42 , B01J37/0215 , B01J37/0219 , B01J37/033 , H01G4/10 , H01G4/12
摘要： A coated material comprising a substrate which has micropores and a reaction product coated thereon along the surface configuration of the substrate and an inner wall of the micropores thereof. The coated material is preferably produced by performing a supercritical coating step wherein a reaction precursor is dissolved in a supercritical fluid to form a precursor fluid and then the precursor fluid is brought into contact with a substrate in the presence with a reaction initiator to allow a reaction between the reaction precursor and the reaction initiator, thereby coating a reaction product onto the substrate.
摘要翻译：一种涂覆材料，其包括具有微孔的基底和沿着基底的表面形状涂覆在其上的反应产物及其微孔的内壁。涂覆的材料优选通过进行超临界涂覆步骤来制备，其中将反应前体溶解在超临界流体中以形成前体流体，然后在反应引发剂存在下将前体流体与底物接触以允许反应在反应前体和反应引发剂之间，从而将反应产物涂覆到基材上。

6. 再颁专利

USRE37385E1 Composite material and process for manufacturing same 有权
标题翻译：复合材料及其制造方法相同
公开(公告)号：USRE37385E1
公开(公告)日：2001-09-18
申请号：US09396871
申请日：1999-09-15
申请人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
发明人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C08K302
CPC分类号： B82Y30/00 , C08J5/005 , C08J2377/00 , C08K3/346 , C08L77/02 , C08L77/00
摘要： Composite material with high mechanical strength and excellent high-temperature characteristics comprising a polymer matrix containing polyamide and layers of a silicate uniformly dispersed in the order of molecules in the polymer matrix, each of said silicate layers being 7 to 12 Å thick and the interlayer distance being at least 20 Å; and a process for manufacturing such composite material.
摘要翻译：具有高机械强度和优异的高温特性的复合材料包括含有聚酰胺的聚合物基体和以聚合物基质中的分子顺序均匀分散的硅酸盐层，每个所述硅酸盐层的厚度为7至12埃，层间距离至少20Å; 以及这种复合材料的制造方法。

7. 发明授权

US4889885A Composite material containing a layered silicate 失效
标题翻译：含有层状硅酸盐的复合材料
公开(公告)号：US4889885A
公开(公告)日：1989-12-26
申请号：US164217
申请日：1988-03-04
申请人： Arimitsu Usuki , Tadashi Mizutani , Yoshiaki Fukushima , Megumi Fujimoto , Kenzo Fukumori , Yoshitsugu Kojima , Norio Sato , Toshio Kurauchi , Osami Kamigaito
发明人： Arimitsu Usuki , Tadashi Mizutani , Yoshiaki Fukushima , Megumi Fujimoto , Kenzo Fukumori , Yoshitsugu Kojima , Norio Sato , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C01B33/44 , C04B14/10 , C04B14/20 , C04B24/42 , C04B26/02 , C08F2/44 , C08K3/34 , C08K9/04 , C10M113/16 , C10M169/00
CPC分类号： C08K3/34 , C01B33/44 , C04B14/10 , C04B14/206 , C04B24/425 , C04B26/02 , C08F2/44 , C08K9/04 , C10M113/16 , C10M169/00 , C08K2201/014 , C10M2201/103 , C10M2201/14 , C10M2201/145 , C10M2205/003 , C10M2209/00 , C10M2209/02 , C10M2209/10 , C10M2209/101 , C10M2215/02
摘要： A composite material comprising a resin other than polyamide resin and a layered silicate dispersed therein, said layered silicate having a layer thickness of 7 to 12 .ANG. and an interlayer distance of 30 .ANG. or above. Owing to the layered silicate uniformly dispersed in the resin matrix, the composite material is superior in mechanical characteristics and heat resistance. It also has good water resistance and chemical resistance.
摘要翻译：一种复合材料，其包含除了聚酰胺树脂之外的树脂和分散在其中的层状硅酸盐，所述层状硅酸盐的层厚度为7至12安培，层间距离为30安培或更高。由于层状硅酸盐均匀分散在树脂基体中，复合材料的机械性能和耐热性都优异。它还具有良好的耐水性和耐化学性。

8. 发明授权

US4739007A Composite material and process for manufacturing same 失效
标题翻译：复合材料及其制造方法相同
公开(公告)号：US4739007A
公开(公告)日：1988-04-19
申请号：US909472
申请日：1986-09-19
申请人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
发明人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C08K3/34 , C08L77/02
CPC分类号： B82Y30/00 , C08J5/005 , C08K3/346 , C08L77/02 , C08J2377/00
摘要： Composite material with high mechanical strength and excellent high-temperature characteristics comprising a polymer matrix containing polyamide and layers of a silicate uniformly dispersed in the order of molecules in the polymer matrix, each of said silicate layers being 7 to 12 .ANG. thick and the interlayer distance being at least 20 .ANG.; and a process for manufacturing such composite material.
摘要翻译：具有高机械强度和优异的高温特性的复合材料包括含有聚酰胺的聚合物基体和分层的均匀分散的硅酸盐层，每个硅酸盐层的厚度为7至12，层间距离至少有20个ANGSTROM; 以及这种复合材料的制造方法。

9. 发明授权

US08034509B2 Polymer electrolyte membrane with an inorganic backbone 有权
标题翻译：具有无机骨架的聚合物电解质膜
公开(公告)号：US08034509B2
公开(公告)日：2011-10-11
申请号：US10379812
申请日：2003-03-06
申请人： Shinji Inagaki , Yoshiaki Fukushima , Masaya Kawasumi , Naoki Hasegawa , Yu Morimoto , Kyoko Tsusaka
发明人： Shinji Inagaki , Yoshiaki Fukushima , Masaya Kawasumi , Naoki Hasegawa , Yu Morimoto , Kyoko Tsusaka
IPC分类号： H01M8/10 , C01B33/20 , C08J5/20
CPC分类号： C25B9/10 , H01M4/861 , H01M4/926 , H01M8/1004 , H01M8/1037 , H01M8/1051 , H01M8/1067 , H01M8/1074 , H01M2300/0082 , H01M2300/0094 , Y02P70/56
摘要： The membrane electrode assembly 1 has an anode 10, a cathode 20, and an electrolyte membrane 30 disposed between the anode and cathode; the anode and cathode are gas diffusion electrodes; the electrolyte membrane contains a solid electrolyte in which a plurality of pores with mean pore diameters of 1 to 30 nm are formed; and the solid electrolyte has a backbone comprising organic groups having one or more metal atoms, oxygen atoms bonded to the metal atoms, and carbon atoms bonded to the metal atoms or oxygen atoms, and also has functional groups with ion-exchange capabilities that are bonded to the organic groups in the pores.
摘要翻译：膜电极组件1具有阳极10，阴极20和设置在阳极和阴极之间的电解质膜30; 阳极和阴极是气体扩散电极; 电解质膜含有固体电解质，其中形成平均孔径为1〜30nm的多个孔; 并且所述固体电解质具有包含具有一个或多个金属原子的有机基团，与所述金属原子键合的氧原子和与所述金属原子或氧原子键合的碳原子的骨架，并且还具有键合的离子交换能力的官能团到毛孔中的有机基团。

10. 发明授权

US07198825B2 Method of manufacturing carbonate film, carbonate composite material, and method of manufacturing the same 有权
标题翻译：制造碳酸盐膜，碳酸盐复合材料的方法及其制造方法
公开(公告)号：US07198825B2
公开(公告)日：2007-04-03
申请号：US10817839
申请日：2004-04-06
申请人： Hiroaki Wakayama , Yoshiaki Fukushima
发明人： Hiroaki Wakayama , Yoshiaki Fukushima
IPC分类号： B05D3/00 , B05D1/38
CPC分类号： C03C17/42 , C04B14/28 , C04B26/02 , C04B28/10 , C04B2111/00482 , C08L1/286 , C04B40/0231 , C04B2103/0067 , C04B14/26
摘要： A pressure container is filled with a base material having at least part of the surface coated with an organic matrix including at least one member selected from the specific functional groups, and a material solution containing a carbonate material as a material for carbonate film and an organic polymer including at least one member selected from the specific groups. In succession, by supplying CO2 into the pressure container at 2 atm or higher, a carbonate film is deposited on the surface of the organic matrix.
摘要翻译：压力容器填充有至少部分表面涂覆有包含选自特定官能团的至少一种的有机基质的基材，以及含有碳酸盐材料作为碳酸盐膜和有机物的材料的材料溶液聚合物，其包含选自特定基团中的至少一个。接着，通过在2atm以上的压力容器中供给CO 2 2，在有机基体的表面上沉积碳酸盐膜。

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