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    • 1. 发明申请
    • POLYMERIC DYE FOR OPTICAL POWER LIMITING
    • 用于光功率限制的聚合染料
    • WO2011037619A1
    • 2011-03-31
    • PCT/US2010/002586
    • 2010-09-22
    • OXAZOGEN, INC.SARKAR, AbhijitDVORNIC, Petar, R.GODSCHALX, James, P.
    • SARKAR, AbhijitDVORNIC, Petar, R.GODSCHALX, James, P.
    • B01J19/10B05D3/06
    • G02B5/223B82Y20/00C09B47/0675C09B69/108Y10S977/742Y10S977/75Y10S977/752Y10S977/753
    • This invention concerns a polymer coating composition for use as non-focal optical power limiting dye containing polymeric materials. This composition contains: (1) one or more Modified Polymers comprising a Polymer, such as a hyperbranched polymer family, especially HB-PCS, HB-PU, HB-PUSOX or PC with one or more of: a) reverse saturable dye (RSA), b) multi-photon absorption dye (MPA), c) an azo dye, or d) absorption dye, which dye is chemically bonded to the pendant groups of the Polymer (along its chain and/or termini) or which forms a part of the backbone of the Polymer; (2) carbon nanotubes (CNT) as optical power limiters (OPL); and (3) a self-focusing component. This Modified Polymer composition contains the dye incorporated into the polymer chain backbone or chemically bonded to the terminal groups at the ends or along the chain of the polymer, which provides efficient protection from laser beam damage along with its self-focusing mechanism.
    • 本发明涉及一种聚合物涂料组合物,其用作含有聚合物材料的非焦点光学功率限制性染料。 该组合物包含:(1)一种或多种包含聚合物的改性聚合物,例如超支化聚合物族,特别是HB-PCS,HB-PU,HB-PUSOX或具有以下一种或多种的PC:a)反向可饱和染料(RSA ),b)多光子吸收染料(MPA),c)偶氮染料或d)吸收染料,该染料与聚合物(沿其链和/或末端)的侧基化学键合,或形成 聚合物骨架的一部分; (2)碳纳米管(CNT)作为光功率限制器(OPL); 和(3)自聚焦部件。 该改性聚合物组合物含有掺入聚合物链骨架中的化学键或化学键合在聚合物端部或沿着链的端基,其提供了与激光束损伤及其自聚焦机制的有效保护。
    • 4. 发明申请
    • LASER PROTECTION POLYMERIC MATERIALS
    • 激光防护聚合物材料
    • WO2010008422A1
    • 2010-01-21
    • PCT/US2009/001602
    • 2009-03-13
    • OXAZOGEN, INC.SARKAR, AbhijitRAYFIELD, George
    • SARKAR, AbhijitRAYFIELD, George
    • B32B5/16G11B5/706C08G73/10
    • C09D201/005B82Y30/00C08G77/50C08K3/041C08K3/08C08K5/0091C08K5/01C08K5/353C08K5/41C08K5/5455C08K13/04C08L83/10C08L83/14C09D183/10C09D183/14C08L63/00
    • This invention concerns a polymer coating material composition (PCM) comprising as components a polymer matrix, carbon nanotubes (CNT) as optical power limiters (OPL), and carbon rich molecules. One aspect of the invention is where the Polymer Matrix is a hyperbranched polymer, such as a hyperbranched polycarbosiloxane polymer. Another aspect of the invention is where the CNT is a short multiwall carbon nanotube (sMWNT). A further aspect of the invention is where the carbon-rich molecules are triethoxysilyl anthracene derivatives. The composition wherein the ratio in weight percent of Polymer Matrix to CNT to carbon-rich molecule is from 94:3:3 to 99.8:0.1:0.1. The composition can further contain one or more of multi-photon absorbers (MPA) chromophores or reverse saturable absorbers (RSA) chromophores. These compositions can be used as: a) a film, b) a coating, c) a liquid, d) a solution, or e) a sandwiched film between two transparent substrates.
    • 本发明涉及一种聚合物涂层材料组合物(PCM),其包含作为组分的聚合物基质,作为光学功率限制器(OPL)的碳纳米管(CNT)和富含碳的分子。 本发明的一个方面是聚合物基体是超支化聚合物,例如超支化聚碳硅氧烷聚合物。 本发明的另一方面是CNT是短多壁碳纳米管(sMWNT)。 本发明的另一方面是其中富碳分子是三乙氧基甲硅烷基蒽衍生物。 其中聚合物基质与CNT与富碳分子的重量百分比的比例为94:3:3至99.8:0.1:0.1。 该组合物可以进一步含有一种或多种多光子吸收剂(MPA)发色团或反饱和吸收剂(RSA)发色团。 这些组合物可以用作:a)薄膜,b)涂层,c)液体,d)溶液,或者e)两个透明基材之间的夹层薄膜。