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1. 发明申请

WO2005109549A3 NICKEL METAL HYDRIDE BATTERY DESIGN 审中-公开
公开(公告)号：WO2005109549A3
公开(公告)日：2005-11-17
申请号：PCT/US2005/009613
申请日：2005-03-22
申请人： OVONIC BATTERY COMPANY, INC. , YOUNG, Kwo
发明人： YOUNG, Kwo , FIERRO, Cristian , REICHMAN, Benjamin , FETCENKO, Michael, A. , KOCH, John , ZALLEN, Avram
IPC分类号： H01M4/58 , H01M4/52 , H01M4/62
摘要： The present invention relates to rechargeable nickel metal hydride batteries and methods for making the same. More particularly, the present invention relates to rechargeable nickel metal hydride batteries having a precharge in the negative electrode sufficient for oxidation prevention in the negative electrode. The present invention discloses a nickel metal hydride battery, wherein the precharge of the negative electrode may be supplied by a variety of sources. The positive active material of the positive electrode may have positive active particles, such as nickel hydroxide, having a precursor coating that incorporates cobalt material capable of forming a conductive network. Sources other than cobalt-containing materials in the positive electrode include hydrogen gas provided directly to the negative active material, nickel aluminum mixed with the negative active material, the etching of the negative active material with an alkaline solution and borohydride chemically charging the negative active material. Preferably, a majority of the precharge of the negative electrode is supplied by sources other than cobalt-containing materials in the positive electrode.

2. 发明申请

WO2004094680A1 HYDROGEN STORAGE ALLOYS HAVING A HIGH POROSITY SURFACE LAYER 审中-公开
标题翻译：具有高孔隙度表面层的氢储存合金
公开(公告)号：WO2004094680A1
公开(公告)日：2004-11-04
申请号：PCT/US2004/008831
申请日：2004-03-23
申请人： OVONIC BATTERY COMPANY, INC.
发明人： FETCENKO, Michael, A. , OVSHINSKY, Stanford, R. , YOUNG, Kwo , REICHMAN, Benjamin , OUCHI, Taihei , KOCH, John , MAYS, William
IPC分类号： C22C30/00
CPC分类号： H01M4/383 , H01M10/345 , Y02E60/324 , Y10S420/90
摘要： Electrochemical and thermal hydrogen storage alloy compositions that provide superior performance, including an electrochemical hydrogen storage alloy that provides superior low temperature discharge characteristics. The alloy compositions include microstructures in the interface region that are highly porous and that include catalytic metallic particles. The microstructures include a large volume fraction of voids having spherical or channel-like shapes and are sufficiently open structurally to facilitate greater mobility of reactive species within the microstructure and in the vicinity of catalytic metallic particles. Greater accessibility to reactive sites accordingly results. The greater mobility of reactive species and/or the greater density of catalytic particles lead to faster kinetics and improved performance (e.g. higher power), especially at low operating temperatures. The microstructures may be formed through inclusion of a microstructure tuning element in the alloy composition, through control of processing conditions and/or through inclusion of etching steps in the post-formation processing of hydrogen storage alloys.
摘要翻译：提供优异性能的电化学和热储氢合金组合物，包括提供优异的低温放电特性的电化学储氢合金。合金组合物包括界面区域中的高度多孔的微结构，并且包括催化金属颗粒。微结构包括具有球形或通道状形状的大体积分数的空隙，并且在结构上足够开放以促进反应性物质在微结构内和催化金属颗粒附近的更大迁移率。因此可以更好地获得反应性网站。活性物质的较大迁移率和/或更大密度的催化剂颗粒导致更快的动力学和改进的性能（例如更高的功率），特别是在低的操作温度下。可以通过在合金组合物中包含微结构调谐元件，通过控制加工条件和/或通过在储氢合金的后形成处理中包括蚀刻步骤来形成微观结构。

3. 发明公开

EP1093528A1 MODIFIED ELECTROCHEMICAL HYDROGEN STORAGE ALLOY HAVING INCREASED CAPACITY, RATE CAPABILITY AND CATALYTIC ACTIVITY 有权
标题翻译：由于容量的增加，创记录的速度及催化活性的改性电化学储氢合金
公开(公告)号：EP1093528A1
公开(公告)日：2001-04-25
申请号：EP00923229.9
申请日：2000-04-11
申请人： OVONIC BATTERY COMPANY, INC.
发明人： FETCENKO, Michael, A. , YOUNG, Kwo , OVSHINSKY, Stanford, R. , REICHMAN, Benjamin , KOCH, John , MAYS, William
IPC分类号： C22C14/00 , C22C16/00 , C22C27/02 , C22C27/06
CPC分类号： C01B3/0031 , C22C14/00 , C22C16/00 , C22C27/025 , C22C27/06 , H01M4/383 , Y02E60/327 , Y10S420/90 , Y10T428/12104
摘要： A modified Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy which has at least one of the following characteristics: 1) an increased charge/discharge rate capability over that the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy; 2) a formation cycling requirement which is reduced to one tenth that of the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy; 3) no chemical/thermal activation of the modified alloy is required to attain full operating capacity as is required by the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy: and 4) an oxide surface layer having a higher electrochemical hydrogen storage catalytic activity than the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy.

4. 发明授权

EP1093528B1 MODIFIED ELECTROCHEMICAL HYDROGEN STORAGE ALLOY HAVING INCREASED CAPACITY, RATE CAPABILITY AND CATALYTIC ACTIVITY 有权
标题翻译：由于容量的增加，创记录的速度及催化活性的改性电化学储氢合金
公开(公告)号：EP1093528B1
公开(公告)日：2006-03-08
申请号：EP00923229.9
申请日：2000-04-11
申请人： OVONIC BATTERY COMPANY, INC.
发明人： FETCENKO, Michael, A. , YOUNG, Kwo , OVSHINSKY, Stanford, R. , REICHMAN, Benjamin , KOCH, John , MAYS, William
IPC分类号： C22C14/00 , C22C16/00 , C22C27/02 , C22C27/06 , C22C19/05 , C22C22/00 , C22C19/00 , H01M4/38 , C01B3/00
CPC分类号： C01B3/0031 , C22C14/00 , C22C16/00 , C22C27/025 , C22C27/06 , H01M4/383 , Y02E60/327 , Y10S420/90 , Y10T428/12104
摘要： A modified Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy which has at least one of the following characteristics: 1) an increased charge/discharge rate capability over that the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy; 2) a formation cycling requirement which is reduced to one tenth that of the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy; 3) no chemical/thermal activation of the modified alloy is required to attain full operating capacity as is required by the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy: and 4) an oxide surface layer having a higher electrochemical hydrogen storage catalytic activity than the base Ti-V-Zr-Ni-Mn-Cr electrochemical hydrogen storage alloy.

5. 发明公开

EP1741154A2 NICKEL METAL HYDRIDE BATTERY DESIGN 审中-公开
标题翻译：镍METALLHYDRID-BATTERIEENTWURF
公开(公告)号：EP1741154A2
公开(公告)日：2007-01-10
申请号：EP05726067.1
申请日：2005-03-22
申请人： OVONIC BATTERY COMPANY, INC.
发明人： YOUNG, Kwo , FIERRO, Cristian , REICHMAN, Benjamin , FETCENKO, Michael, A. , KOCH, John , ZALLEN, Avram
IPC分类号： H01M4/58 , H01M4/52 , H01M4/62
CPC分类号： H01M10/345 , H01M4/0438 , H01M4/0445 , H01M4/0492 , H01M4/242 , H01M4/32 , H01M4/366 , H01M4/383 , H01M4/52 , H01M4/62 , H01M4/621 , H01M10/4235 , H01M10/446 , H01M10/52 , H01M2004/027
摘要： The present invention relates to rechargeable nickel metal hydride batteries and methods for making the same. More particularly, the present invention relates to rechargeable nickel metal hydride batteries having a precharge in the negative electrode sufficient for oxidation prevention in the negative electrode. The present invention discloses a nickel metal hydride battery, wherein the precharge of the negative electrode may be supplied by a variety of sources. The positive active material of the positive electrode may have positive active particles, such as nickel hydroxide, having a precursor coating that incorporates cobalt material capable of forming a conductive network. Sources other than cobalt-containing materials in the positive electrode include hydrogen gas provided directly to the negative active material, nickel aluminum mixed with the negative active material, the etching of the negative active material with an alkaline solution and borohydride chemically charging the negative active material. Preferably, a majority of the precharge of the negative electrode is supplied by sources other than cobalt-containing materials in the positive electrode.
摘要翻译：本发明涉及可充电镍氢电池及其制造方法。更具体地说，本发明涉及在负极中具有足够的氧化防止的预充电的可再充电的镍金属氢化物电池。本发明公开了一种镍金属氢化物电池，其中负极的预充电可以由各种源提供。正极的正极活性材料可以具有正的活性颗粒，例如氢氧化镍，其具有引入可形成导电网络的钴材料的前体涂层。来自正极中的含钴材料以外的源包括直接设置在负极活性物质上的氢气，与负极活性物质混合的镍铝，用碱性溶液腐蚀负极活性物质，并将硼氢化钠化学充电负极活性物质。优选地，负极的预充电的大部分由正极内的含钴材料以外的源供给。

6. 发明授权

EP1608790B1 HYDROGEN STORAGE ALLOYS HAVING A HIGH POROSITY SURFACE LAYER 有权
标题翻译：具有高多孔表面层贮氢合金
公开(公告)号：EP1608790B1
公开(公告)日：2007-11-14
申请号：EP04759728.1
申请日：2004-03-23
申请人： OVONIC BATTERY COMPANY, INC.
发明人： FETCENKO, Michael, A. , OVSHINSKY, Stanford, R. , YOUNG, Kwo , REICHMAN, Benjamin , OUCHI, Taihei , KOCH, John , MAYS, William
IPC分类号： C22C30/00 , H01M4/38
CPC分类号： H01M4/383 , H01M10/345 , Y02E60/324 , Y10S420/90
摘要： Electrochemical and thermal hydrogen storage alloy compositions that provide superior performance, including an electrochemical hydrogen storage alloy that provides superior low temperature discharge characteristics. The alloy compositions include microstructures in the interface region that are highly porous and that include catalytic metallic particles. The microstructures include a large volume fraction of voids having spherical or channel-like shapes and are sufficiently open structurally to facilitate greater mobility of reactive species within the microstructure and in the vicinity of catalytic metallic particles. Greater accessibility to reactive sites accordingly results. The greater mobility of reactive species and/or the greater density of catalytic particles lead to faster kinetics and improved performance (e.g. higher power), especially at low operating temperatures. The microstructures may be formed through inclusion of a microstructure tuning element in the alloy composition, through control of processing conditions and/or through inclusion of etching steps in the post-formation processing of hydrogen storage alloys.

7. 发明公开

EP1608790A1 HYDROGEN STORAGE ALLOYS HAVING A HIGH POROSITY SURFACE LAYER 有权
标题翻译：具有高多孔表面层贮氢合金
公开(公告)号：EP1608790A1
公开(公告)日：2005-12-28
申请号：EP04759728.1
申请日：2004-03-23
申请人： OVONIC BATTERY COMPANY, INC.
发明人： FETCENKO, Michael, A. , OVSHINSKY, Stanford, R. , YOUNG, Kwo , REICHMAN, Benjamin , OUCHI, Taihei , KOCH, John , MAYS, William
IPC分类号： C22C30/00 , H01M4/38
CPC分类号： H01M4/383 , H01M10/345 , Y02E60/324 , Y10S420/90
摘要： Electrochemical and thermal hydrogen storage alloy compositions that provide superior performance, including an electrochemical hydrogen storage alloy that provides superior low temperature discharge characteristics. The alloy compositions include microstructures in the interface region that are highly porous and that include catalytic metallic particles. The microstructures include a large volume fraction of voids having spherical or channel-like shapes and are sufficiently open structurally to facilitate greater mobility of reactive species within the microstructure and in the vicinity of catalytic metallic particles. Greater accessibility to reactive sites accordingly results. The greater mobility of reactive species and/or the greater density of catalytic particles lead to faster kinetics and improved performance (e.g. higher power), especially at low operating temperatures. The microstructures may be formed through inclusion of a microstructure tuning element in the alloy composition, through control of processing conditions and/or through inclusion of etching steps in the post-formation processing of hydrogen storage alloys.

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