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    • 3. 发明授权
    • Recording medium having a specified photopolymerization initiator
    • 具有特定光聚合引发剂的记录介质
    • US4992351A
    • 1991-02-12
    • US453171
    • 1989-12-26
    • Norio OhkumaMasanori TakenouchiMasashi MiyagawaTadashi Yamamoto
    • Norio OhkumaMasanori TakenouchiMasashi MiyagawaTadashi Yamamoto
    • C07C45/00C07C45/29C07C49/796C07C49/813C07C49/83C07C49/84G03F7/00G03F7/031
    • G03F7/031C07C45/00C07C45/29C07C49/796C07C49/813C07C49/83C07C49/84G03F7/002Y10S430/114Y10T428/2984Y10T428/2989
    • A recording medium has a recording layer comprising image-forming elements (A), (B) and (C) containing at least a compound having unsaturated double bond and a photopolymerization initiator. The photopolymerization initiator in the element (A) is a compound represented by the following formula (I): ##STR1## (wherein Ar.sub.1 and Ar.sub.2 are ech aromatic ring or heterocyclis ring). The photopolymerization initiator in the element (B) has an absorption maximum in a wavelength region of 360 to 430 nm. The photopolymerization initiator in the element (C) has an absorption maximum in a wavelength region of 430 nm or longer. The recording medium is suitably used as a transfer recording medium in a recording apparatus which includes heating means and light irradiating means to provide the recording layer with heat energy and photoenergy to change the transfer characteristic of the recording layer. The light irradiating means includes a phosphor of thallium-activated calcium phosphate or thallium-activated calcium zinc phosphate, a phosphor having a fluorescent peak wavelength of 360 to 430 nm and a phosphor having a fluorescent peak wavelength of 430 nm or longer, and a light source for exciting the phosphors.
    • 记录介质具有包含至少含有不饱和双键的化合物和光聚合引发剂的图像形成元件(A),(B)和(C)的记录层。 元素(A)中的光聚合引发剂是由下式(I)表示的化合物:其中Ar1和Ar2是芳族环或杂环基。 元件(B)中的光聚合引发剂在360〜430nm的波长范围内具有吸收最大值。 元件(C)中的光聚合引发剂在430nm以上的波长范围内具有吸收最大值。 记录介质适合用作包括加热装置和光照射装置的记录装置中的转印记录介质,以向记录层提供热能和光能以改变记录层的转印特性。 光照射装置包括铊激活的磷酸钙或铊激活的磷酸钙锌的荧光体,荧光峰值波长为360〜430nm的荧光体和荧光峰值波长为430nm以上的荧光体,以及光 来源激发荧光粉。
    • 6. 发明授权
    • Transfer recording medium
    • 转移记录介质
    • US4973542A
    • 1990-11-27
    • US130555
    • 1987-12-08
    • Masanori TakenouchiMasashi MiyagawaNorio Ohkuma
    • Masanori TakenouchiMasashi MiyagawaNorio Ohkuma
    • B41M5/382G03C1/72G03F7/34
    • B41M5/38242Y10S428/913Y10S428/914Y10T428/2984Y10T428/2989
    • A transfer recording medium comprises a substrate and a transfer recording layer disposed thereon capable of changing its transfer characteristic when provided with light energy and heat energy. The transfer recording layer comprises image forming elements which are solid at room temperature and comprise at least a colorant and a functional component sensitive to the provision of light energy and heat energy. Since the image forming elements have a mode particle size of 5-25 .mu.m and comprise 50% by number or more of those having a particle size of .+-.4 .mu.m or less from the mode particle size, the transfer recording medium affords a clear transferred image with high resolution at a high transfer rate when provided with light and heat energies, at least one of which is applied imagewise.
    • 转印记录介质包括基板和设置在其上的转印记录层,当提供光能和热能时能够改变其转印特性。 转印记录层包括在室温下为固体并且至少包含着色剂和对提供光能和热能敏感的功能组分的图像形成元件。 由于图像形成元件具有5-25μm的模式粒径,并且包含从模式粒径的粒径为+/-4μm以下的那些的50重量%以上,所以转印记录介质提供 当具有光和热能时,以高传输速率具有高分辨率的清晰转印图像,其中至少一个被成像应用。
    • 8. 发明授权
    • Transfer recording medium comprising a layer changing its
transferability when provided with light and heat
    • 转印记录介质包括在提供光和热时改变其转印性的层
    • US4952478A
    • 1990-08-28
    • US127948
    • 1987-12-02
    • Masashi MiyagawaMasanori TakenouchiNorio Ohkuma
    • Masashi MiyagawaMasanori TakenouchiNorio Ohkuma
    • G03F7/00
    • G03F7/002Y10S428/913Y10S428/914
    • A transfer recording medium comprises a support and a transfer recording layer formed thereon capable of changing its transferability when provided with light energy and heat energy. The transfer recording layer comprises at least a colorant, a binder component an a functional component sensitive to the provision of light energy and heat energy. The functional component comprises at least a photo-initiator and a polymerizing component selected from the group consisting of monomers, oligomers and prepolymers each having an unsaturated double bond. The binder component comprises a thermoplastic polymer having a glass transition temperature of 30.degree. C. or higher and a weight-average molecular weight of 5.times.10.sup.4 or larger. The thermoplastic polymer is contained in a proportion of 5-70 wt. % of the transfer recording layer. Because of the inclusion of the polymer binder component, the transfer recording layer has an increased sensitivity contrast to illumination between under heating and under no heating.
    • 转印记录介质包括支撑体和形成在其上的转印记录层,当提供光能和热能时能够改变其转印性。 转印记录层至少包含着色剂,粘合剂组分和对提供光能和热能敏感的功能组分。 功能组分至少包含光引发剂和选自单体,低聚物和各自具有不饱和双键的预聚物的聚合组分。 粘合剂组分包括玻璃化转变温度为30℃或更高,重均分子量为5×10 4或更大的热塑性聚合物。 热塑性聚合物的含量为5-70wt。 %的转印记录层。 由于包含聚合物粘合剂组分,转印记录层与加热和加热之间的照明具有增加的灵敏度对比度。