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    • 7. 发明申请
    • SUBSTITUTED BIPYRIDYL COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE
    • 取代的双嘧啶化合物和有机电致发光器件
    • US20110001129A1
    • 2011-01-06
    • US12735885
    • 2009-02-25
    • Norimasa YokoyamaShuichi HayashiMakoto NagaokaYoshio TaniguchiMusubu Ichikawa
    • Norimasa YokoyamaShuichi HayashiMakoto NagaokaYoshio TaniguchiMusubu Ichikawa
    • H01L51/50C07D401/14C07D403/14C07D471/04
    • H01L51/0067C07D213/22C09K11/06C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1059H01L51/0085H05B33/10
    • [Problem] To provide an organic compound which shows an excellent electron-injecting/transporting performance, has a hole-blocking ability and shows a high stability as a film, that is, having excellent characteristics as a material for organic electroluminescent device having high efficiency and high durability; and to provide an organic EL device comprising the compound and having high efficiency and high durability.[Means for Solution] A substituted bipyridyl compound represented by the general formula (1); and an organic electroluminescent device comprising a pair of electrodes and at least one organic layer sandwiched between then, wherein the compound is used as the constitutive material of at least one organic layer. (wherein R1 to R7 may be the same or different, each representing a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a linear or branched alkyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group; n indicates an integer of from 2 to 4; A represents a di- to tetra-valent, substituted or unsubstituted aromatic hydrocarbon group, a di- to tetra-valent, substituted or unsubstituted aromatic heterocyclic group, a di- to tetra-valent, substituted or unsubstituted condensed polycyclic aromatic group, or a trivalent group represented by the following general formula (2): (wherein X, Y and Z each represents a carbon atom or a nitrogen atom); provided that when n=2, the two bipyridyl structures may direct bond to each other, and in the case, A is absent).
    • 为了提供一种显示出优异的电子注入/传输性能的有机化合物,具有空穴阻挡能力并且显示出作为膜的高稳定性,即作为高效率的有机电致发光器件的材料具有优异的特性 耐用性高; 并且提供包含该化合物并具有高效率和高耐久性的有机EL器件。 [解决方案]由通式(1)表示的取代的联吡啶基化合物; 以及包括一对电极和夹在之间的至少一个有机层的有机电致发光器件,其中所述化合物用作至少一个有机层的组成材料。 (其中R 1至R 7可以相同或不同,各自表示氢原子,氟原子,氯原子,氰基,三氟甲基,具有1至6个碳原子的直链或支链烷基,取代的 或未取代的芳香族烃基,取代或未取代的芳香族杂环基或取代或未取代的稠合多环芳香族基; n表示2〜4的整数,A表示二价至四价的取代或未取代的芳香族烃基 ,二价至四元,取代或未取代的芳族杂环基,二价至四价,取代或未取代的稠合多环芳族基团或由以下通式(2)表示的三价基团:(其中X, Y和Z各自表示碳原子或氮原子);条件是当n = 2时,两个联吡啶基结构可以彼此直接键合,在此情况下,A不存在)。