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1. 发明申请

US20100016507A1 THERMOPLASTIC RESIN, PROCESS FOR PRODUCTION OF THE SAME, AND MOLDED ARTICLE MANUFACTURED FROM THE SAME 审中-公开
标题翻译：热塑性树脂，其制造方法和从其制造的模制品
公开(公告)号：US20100016507A1
公开(公告)日：2010-01-21
申请号：US11916065
申请日：2006-06-01
申请人： Norifumi Sumimoto , Wataru Kakuno , Tetsuya Kubota , Atsushi Watanabe , Toshio Oohama , Takeshi Watanabe
发明人： Norifumi Sumimoto , Wataru Kakuno , Tetsuya Kubota , Atsushi Watanabe , Toshio Oohama , Takeshi Watanabe
IPC分类号： C08L51/04
CPC分类号： C08F265/06 , C08F265/00 , C08F265/04 , C08L51/003 , C08L51/04 , C08L2666/02
摘要： The objective of the present invention is to provide a thermoplastic resin capable of producing a thin-walled article such as a film, a sheet and a bag stably by extrusion such as calender molding, and of leading to a thin-walled article wherein an undesirable phenomenon due to flow marks generated on the surface is improved and which is excellent in whitening resistance upon bending, and the like, and a method for the production thereof, a molded article and a composite article comprising thereof. The present thermoplastic resin comprises an acryl-based rubbery polymer reinforced resin having a graft ratio of 80% to 170%, a number-average particle diameter of an acryl-based rubbery polymer of 60 to 150 nm, an intrinsic viscosity of a component dissolved by acetonitrile of 0.4 to 0.8 dl/g, a content of a bound cyanidated vinyl compound in the component dissolved by acetonitrile of 20% to 30% by mass, and standard deviation of a distribution of the content of a bound cyanidated vinyl compound measured using liquid chromatography is 5 or less.
摘要翻译：本发明的目的是提供一种热塑性树脂，其能够通过诸如压延成型的挤出来稳定地制造薄膜，片材和袋子等薄壁制品，并且导致薄壁制品，其中不期望的表面上产生的流痕产生的现象得到改善，弯曲时的耐白化性优异等，以及其制造方法，成型品及其组合物。本发明的热塑性树脂包括接枝率为80〜170％，丙烯酸系橡胶质聚合物的数均粒径为60〜150nm，溶解成分的特性粘度的丙烯酸类橡胶状聚合物强化树脂通过乙腈为0.4〜0.8dl / g，由乙腈溶解的成分中的结合的氰化乙烯基化合物的含量为20〜30质量％，使用结合的氰化乙烯基化合物的含量的分布的标准偏差液相色谱法为5以下。

2. 发明授权

US08221892B2 Rubber-reinforced resin, anti-static resin composition, molded article and laminate 失效
标题翻译：橡胶增强树脂，防静电树脂组合物，模制品和层压材料
公开(公告)号：US08221892B2
公开(公告)日：2012-07-17
申请号：US12063116
申请日：2006-08-23
申请人： Norifumi Sumimoto , Wataru Kakuno
发明人： Norifumi Sumimoto , Wataru Kakuno
IPC分类号： B32B27/30 , B32B25/14 , B32B33/00 , C08L33/06 , C08L33/24
CPC分类号： C08F279/06 , B32B25/08 , B32B25/14 , C08F279/02 , C08F279/04 , C08F287/00 , C08L9/00 , C08L33/18 , C08L51/04 , C08L53/025 , C08L55/02 , Y10T428/31786 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935 , C08L2666/08 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The objective of the present invention is to provide a rubber-reinforced resin which, when formed into a molded article, can prevent contamination or soiling of an article contacted with the molded article or a device on the periphery of the molded article and is excellent in impact resistance and transparency, and an anti-static resin composition which is excellent in impact resistance and anti-static properties. The present rubber-reinforced resin comprises a rubber-reinforced copolymeric resin produced by polymerization of 20 to 95 parts by mass of monomer components comprising methyl methacrylate, an aromatic vinyl compound and a cyanidated vinyl compound in the presence of a rubbery polymer having a predetermined volume-average particle diameter, or comprises a mixture of the rubber-reinforced copolymeric resin and a copolymer of the above-mentioned monomer components. Additionally, the present anti-static resin composition comprises the above-mentioned rubber-reinforced resin and a polymer type anti-static agent, wherein the rubbery polymer is contained in an amount from 5% to 40% by mass. In each of the rubber-reinforced resin and the anti-static resin composition, the total amount of substances detected at a retention time of 10 to 24 minutes is 20,000 μg or less per gram of the sample as determined by pyrolysis GC analysis.
摘要翻译：本发明的目的是提供一种橡胶增强树脂，其在形成成型品时能够防止与模制品接触的制品或模制品的周边上的装置的污染或污染，并且在耐冲击性和透明性，以及抗冲击性和抗静电性优异的抗静电性树脂组合物。本发明的橡胶增强树脂包括通过在具有预定体积的橡胶状聚合物的存在下聚合20至95质量份包含甲基丙烯酸甲酯，芳族乙烯基化合物和氰化乙烯基化合物的单体组分而制备的橡胶增强共聚树脂平均粒径，或包含橡胶增强共聚树脂和上述单体成分的共聚物的混合物。此外，本发明的抗静电树脂组合物包含上述橡胶增强树脂和聚合物型防静电剂，其中橡胶状聚合物的含量为5〜40质量％。在每种橡胶增强树脂和防静电树脂组合物中，通过热分解GC分析测定，在每10克样品中，在10至24分钟的保留时间内检测的物质的总量为20,000μg或更少。

3. 发明申请

US20090104466A1 RUBBER-REINFORCED RESIN, ANTI-STATIC RESIN COMPOSITION, MOLDED ARTICLE AND LAMINATE 失效
标题翻译：橡胶增强树脂，防静电树脂组合物，模制品和层压板
公开(公告)号：US20090104466A1
公开(公告)日：2009-04-23
申请号：US12063116
申请日：2006-08-23
申请人： Norifumi Sumimoto , Wataru Kakuno
发明人： Norifumi Sumimoto , Wataru Kakuno
IPC分类号： B32B27/08 , C08L33/06 , C08L33/24
CPC分类号： C08F279/06 , B32B25/08 , B32B25/14 , C08F279/02 , C08F279/04 , C08F287/00 , C08L9/00 , C08L33/18 , C08L51/04 , C08L53/025 , C08L55/02 , Y10T428/31786 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935 , C08L2666/08 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The objective of the present invention is to provide a rubber-reinforced resin which, when formed into a molded article, can prevent contamination or soiling of an article contacted with the molded article or a device on the periphery of the molded article and is excellent in impact resistance and transparency, and an anti-static resin composition which is excellent in impact resistance and anti-static properties. The present rubber-reinforced resin comprises a rubber-reinforced copolymeric resin produced by polymerization of 20 to 95 parts by mass of monomer components comprising methyl methacrylate, an aromatic vinyl compound and a cyanidated vinyl compound in the presence of a rubbery polymer having a predetermined volume-average particle diameter, or comprises a mixture of the rubber-reinforced copolymeric resin and a copolymer of the above-mentioned monomer components. Additionally, the present anti-static resin composition comprises the above-mentioned rubber-reinforced resin and a polymer type anti-static agent, wherein the rubbery polymer is contained in an amount from 5% to 40% by mass. In each of the rubber-reinforced resin and the anti-static resin composition, the total amount of substances detected at a retention time of 10 to 24 minutes is 20,000 μg or less per gram of the sample as determined by pyrolysis GC analysis.
摘要翻译：本发明的目的是提供一种橡胶增强树脂，其在形成成型品时能够防止与模制品接触的制品或模制品的周边上的装置的污染或污染，并且在耐冲击性和透明性，以及抗冲击性和抗静电性优异的抗静电性树脂组合物。本发明的橡胶增强树脂包括通过在具有预定体积的橡胶状聚合物的存在下聚合20至95质量份包含甲基丙烯酸甲酯，芳族乙烯基化合物和氰化乙烯基化合物的单体组分而制备的橡胶增强共聚树脂平均粒径，或包含橡胶增强共聚树脂和上述单体成分的共聚物的混合物。此外，本发明的抗静电树脂组合物包含上述橡胶增强树脂和聚合物型防静电剂，其中橡胶状聚合物的含量为5〜40质量％。在每种橡胶增强树脂和抗静电树脂组合物中，通过热解GC分析测定，每10克样品中保留时间为10至24分钟时检测的物质总量为20,000杯或更少。

4. 发明授权

US09074057B2 Printing film and face material 有权
标题翻译：印刷胶片和面料
公开(公告)号：US09074057B2
公开(公告)日：2015-07-07
申请号：US12919337
申请日：2009-02-27
申请人： Masanori Hashimoto , Atsushi Watanabe , Wataru Kakuno
发明人： Masanori Hashimoto , Atsushi Watanabe , Wataru Kakuno
IPC分类号： B32B3/10 , B32B27/00 , C08L77/00 , C08L51/00 , C08K3/34 , B32B37/00 , C08J5/18 , B32B27/06 , B32B27/30 , B32B27/34 , C08L51/04 , C08L55/02 , C08L77/02
CPC分类号： C08J5/18 , B32B5/18 , B32B13/042 , B32B13/12 , B32B15/06 , B32B15/08 , B32B21/02 , B32B21/045 , B32B21/08 , B32B25/06 , B32B25/08 , B32B25/14 , B32B27/06 , B32B27/08 , B32B27/20 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2262/101 , B32B2262/106 , B32B2264/10 , B32B2264/101 , B32B2270/00 , B32B2307/306 , B32B2307/4023 , B32B2307/412 , B32B2307/50 , B32B2307/546 , B32B2307/558 , B32B2307/5825 , B32B2307/714 , B32B2307/7246 , B32B2307/734 , B32B2307/75 , B32B2419/00 , B32B2451/00 , B32B2457/00 , B32B2479/00 , B32B2509/00 , B32B2605/00 , C08J2351/04 , C08J2377/00 , C08L51/00 , C08L51/04 , C08L55/02 , C08L77/00 , C08L77/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： The present invention provides a resin film which is excellent in various properties such as heat resistance, printability, mechanical strength, moisture absorption resistance, film-forming property and flexibility and can be suitably used in the printing applications. There is provided a printing film obtained by molding a thermoplastic resin composition (I) comprising 100 parts by mass in total of a mixed resin comprising 25 to 75% by mass of a rubber-modified styrene-based resin (A) and 25 to 75% by mass of a polyamide-based resin (B). The component (A) comprises a graft copolymer obtained by polymerizing a vinyl-based monomer in the presence of a rubber polymer, or a mixture comprising the graft copolymer and a (co)polymer of the vinyl-based monomer. The vinyl-based monomer comprises an aromatic vinyl compound and a cyanided vinyl compound, and further comprises a functional group-containing vinyl-based monomer in an amount of 0.1 to 1.2% by mass based on the component (A) in which an acetone-soluble component in the component (A) has an intrinsic viscosity of 0.15 to 1.5 dL/g (as measured at 30° C. in methyl ethyl ketone). The composition (I) comprises the rubber polymer in an amount of 5 to 30 parts by mass based on 100 parts by mass of the composition.
摘要翻译：本发明提供了耐热性，印刷性，机械强度，耐吸湿性，成膜性和柔软性等各种性能优异的树脂膜，可适用于印刷用途。提供一种通过模制热塑性树脂组合物（I）而得到的印刷膜，该热塑性树脂组合物（I）包含100质量份，总共包含25〜75质量％的橡胶改性苯乙烯类树脂（A）和25〜75 质量％的聚酰胺类树脂（B）。组分（A）包括通过在橡胶聚合物存在下聚合乙烯基类单体或包含接枝共聚物和乙烯基类单体的（共）聚合物的混合物而获得的接枝共聚物。乙烯基类单体包含芳香族乙烯基化合物和氰化乙烯基化合物，并且还含有相对于其中丙酮 - 丙烯酸类单体的成分（A）为0.1〜1.2质量％的含官能团的乙烯基类单体，组分（A）中的可溶成分的特性粘度为0.15〜1.5dL / g（在甲基乙基酮中在30℃下测定）。组合物（I）相对于100质量份组合物，含有5〜30质量份的橡胶聚合物。

5. 发明申请

US20130037098A1 INFRARED REFLECTIVE LAMINATE 审中-公开
标题翻译：红外反射层压板
公开(公告)号：US20130037098A1
公开(公告)日：2013-02-14
申请号：US13584589
申请日：2012-08-13
申请人： Atsushi Watanabe , Masanori Hashimoto , Wataru Kakuno
发明人： Atsushi Watanabe , Masanori Hashimoto , Wataru Kakuno
IPC分类号： G02B1/04 , H01L31/0203
CPC分类号： B32B7/02 , B32B17/10018 , B32B17/10788 , B32B25/08 , B32B25/14 , B32B25/20 , B32B27/08 , B32B27/30 , B32B27/32 , B32B2307/306 , B32B2307/4026 , B32B2307/412 , B32B2307/416 , B32B2307/712 , B32B2307/7246 , B32B2307/7265 , B32B2325/00 , B32B2457/12 , H01L31/049 , Y02E10/50 , Y10T428/2495 , Y10T428/31663 , Y10T428/31721 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： The infrared reflective layered product can reflect infrared radiation with certain wavelengths to prevent heat accumulation and, at the same time, has excellent heat resistance. The infrared reflective layered product comprises a layer (B) as a base layer, a layer (A) layered on one side of the layer (B), and a layer (C) layered on the other side of the layer (B).
摘要翻译：红外反射层叠体可以反射具有一定波长的红外线辐射，以防止热积聚，同时具有优异的耐热性。红外线反射层叠体包括层（B）作为基底层，层（A）层叠在层（B）的一面上，层（C）层叠在层（B）的另一侧。

6. 发明申请

US20100189975A1 LAYERED PRODUCT 审中-公开
标题翻译：分层产品
公开(公告)号：US20100189975A1
公开(公告)日：2010-07-29
申请号：US12670865
申请日：2008-07-29
申请人： Wataru Kakuno , Atsushi Watanabe , Masanori Hashimoto
发明人： Wataru Kakuno , Atsushi Watanabe , Masanori Hashimoto
IPC分类号： B32B27/08 , B32B7/02 , B32B27/30 , B32B27/28 , B32B25/20
CPC分类号： B32B27/08 , B32B7/02 , B32B25/042 , B32B25/08 , B32B25/14 , B32B25/16 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2270/00 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/50 , B32B2307/546 , B32B2307/712 , B32B2307/714 , B32B2457/12 , Y10T428/2495 , Y10T428/31663 , Y10T428/31721 , Y10T428/31931 , Y10T428/31935
摘要： A layered product is provided which is excellent in heat resistance, difficult to hydrolyze and excellent in weatherability, and has such flexibility that it can hardly crack even when folded, and further is prevented from curling, and thus is excellent in processability, productivity and handleability. The layered product comprises a base layer made of a thermoplastic resin (I) having a glass transition temperature of 120° C. or higher, the base layer being layered on at least one side thereof with a layer made of an aromatic vinyl resin (II) having a lower glass transition temperature than the thermoplastic resin (I). The aromatic vinyl resin (II) is preferably a rubber-reinforced aromatic vinyl resin which contains a rubber-like polymer (a) selected from ethylene-α-olefin rubbers, hydrogenated conjugated diene rubbers, acrylic rubbers, silicone rubbers and silicone/acrylic composite rubbers in an amount of 5-40 parts by mass. The difference in glass transition temperature between the thermoplastic resin (I) and the aromatic vinyl resin (II) is preferably 10° C. or more.
摘要翻译：提供了耐热性好，难以水解，耐候性优异的层叠体，具有柔软性，即使在折叠时也难以龟裂，并且防止卷曲，因此加工性，生产率和处理性优异。所述层叠体包含由玻璃化转变温度为120℃以上的热塑性树脂（I）构成的基材层，所述基材层的至少一面层叠有由芳香族乙烯基树脂（II）构成的层）具有比热塑性树脂（I）低的玻璃化转变温度。芳族乙烯基树脂（II）优选为含有选自乙烯-α-烯烃橡胶，氢化共轭二烯橡胶，丙烯酸橡胶，硅橡胶和硅酮/丙烯酸复合材料的橡胶状聚合物（a）的橡胶增强芳族乙烯基树脂橡胶的用量为5-40质量份。热塑性树脂（I）和芳香族乙烯基树脂（II）之间的玻璃化转变温度的差异优选为10℃以上。

7. 发明授权

US08339700B2 Infrared reflective laminate 失效
标题翻译：红外反射层压板
公开(公告)号：US08339700B2
公开(公告)日：2012-12-25
申请号：US12739575
申请日：2008-10-23
申请人： Atsushi Watanabe , Masanori Hashimoto , Wataru Kakuno
发明人： Atsushi Watanabe , Masanori Hashimoto , Wataru Kakuno
IPC分类号： F21V9/04 , F21V9/06 , G02B5/08 , G02B5/20 , H01L31/042
CPC分类号： B32B7/02 , B32B17/10018 , B32B17/10788 , B32B25/08 , B32B25/14 , B32B25/20 , B32B27/08 , B32B27/30 , B32B27/32 , B32B2307/306 , B32B2307/4026 , B32B2307/412 , B32B2307/416 , B32B2307/712 , B32B2307/7246 , B32B2307/7265 , B32B2325/00 , B32B2457/12 , H01L31/049 , Y02E10/50 , Y10T428/2495 , Y10T428/31663 , Y10T428/31721 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： The infrared reflective layered product can reflect infrared radiation with certain wavelengths to prevent heat accumulation while exhibiting excellent heat resistance. The product includes a base layer (B), a layer (A) layered on one side of the layer (B), and a layer (C) layered on the other side of the layer (B). Layer (A) is a colored resin layer which has an absorptance of a light with a wavelength of 800-1400 nm of not more than 10%. Layer (B) is a thermoplastic resin layer which shows a dimensional change (s) satisfying 1%≧s≧−1% when left at 150° C. for 30 min. Layer C is a colored resin layer having a reflectance of a light with a wavelength of 400-1400 nm of not less than 50%. The product may also include a water vapor barrier layer (D).
摘要翻译：红外反射层叠体可以反射具有一定波长的红外线辐射，以防止热积聚，同时具有优异的耐热性。该产品包括基层（B），层（B）的一侧上的层（A）和层（B）的另一侧上的层（C）。层（A）是具有不超过10％的波长为800-1400nm的光的吸收率的有色树脂层。层（B）是在150℃下放置30分钟时显示满足1％≥s≥-1％的尺寸变化的热塑性树脂层。层C是具有400-1400nm波长的光的反射率不小于50％的着色树脂层。产品还可以包括水蒸气阻隔层（D）。

8. 发明申请

US20110043901A1 INFRARED REFLECTIVE LAMINATE 失效
标题翻译：红外反射层压板
公开(公告)号：US20110043901A1
公开(公告)日：2011-02-24
申请号：US12739575
申请日：2008-10-23
申请人： Atsushi Watanabe , Masanori Hashimoto , Wataru Kakuno
发明人： Atsushi Watanabe , Masanori Hashimoto , Wataru Kakuno
IPC分类号： F21V9/04
CPC分类号： B32B7/02 , B32B17/10018 , B32B17/10788 , B32B25/08 , B32B25/14 , B32B25/20 , B32B27/08 , B32B27/30 , B32B27/32 , B32B2307/306 , B32B2307/4026 , B32B2307/412 , B32B2307/416 , B32B2307/712 , B32B2307/7246 , B32B2307/7265 , B32B2325/00 , B32B2457/12 , H01L31/049 , Y02E10/50 , Y10T428/2495 , Y10T428/31663 , Y10T428/31721 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： This invention provides an infrared reflective layered product, particularly a back sheet for solar cells, which, even when it has a black colored or chromatically colored appearance, can reflect infrared radiation with certain wavelengths to prevent heat accumulation and, at the same time, has excellent heat resistance. The infrared reflective layered product comprises the following layer (B) as a base layer, the following layer (A) layered on one side of the layer (B), and the following layer (C) layered on the other side of the layer (B). Layer (A): a colored resin layer which has an absorptance of a light with a wavelength of 800-1400 nm of not more than 10%. Layer (B): a thermoplastic resin layer which shows a dimensional change (s) satisfying 1%≧s≧−1% when left at 150° C. for 30 minutes. Layer C: a colored resin layer having a reflectance of a light with a wavelength of 400-1400 nm of not less than 50%. Preferably, the layer (A) is formed of a resin containing an infrared transmittable coloring agent, and the layer (C) is formed of a resin containing a white pigment. A water vapor barrier layer (D) may be additionally provided.
摘要翻译：本发明提供一种红外线反射层叠体，特别是太阳能电池用背板，即使具有黑色或彩色外观，也能够反射具有一定波长的红外线辐射，防止热积聚，同时具有优良的耐热性。红外线反射层叠体包含以下的层（B）作为基底层，在层（B）的一面上分层的以下层（A）和层叠在层的另一侧的下层（C） B）。层（A）：具有波长为800-1400nm的光的吸收率为10％以下的有色树脂层。层（B）：在150℃下放置30分钟时，表现出满足1％≥s≥-1％的尺寸变化的热塑性树脂层。层C：具有波长为400-1400nm的光的反射率为50％以上的着色树脂层。优选地，层（A）由含有红外透射着色剂的树脂形成，并且层（C）由含有白色颜料的树脂形成。可以另外提供水蒸气阻隔层（D）。

9. 发明申请

US20110039080A1 PRINTING FILM AND FACE MATERIAL 有权
标题翻译：印刷电影和面料
公开(公告)号：US20110039080A1
公开(公告)日：2011-02-17
申请号：US12919337
申请日：2009-02-27
申请人： Masanori Hashimoto , Atsushi Watanabe , Wataru Kakuno
发明人： Masanori Hashimoto , Atsushi Watanabe , Wataru Kakuno
IPC分类号： B32B3/10 , C08L77/00 , C08L51/00 , C08K3/34 , B32B27/00 , B32B37/00
CPC分类号： C08J5/18 , B32B5/18 , B32B13/042 , B32B13/12 , B32B15/06 , B32B15/08 , B32B21/02 , B32B21/045 , B32B21/08 , B32B25/06 , B32B25/08 , B32B25/14 , B32B27/06 , B32B27/08 , B32B27/20 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2262/101 , B32B2262/106 , B32B2264/10 , B32B2264/101 , B32B2270/00 , B32B2307/306 , B32B2307/4023 , B32B2307/412 , B32B2307/50 , B32B2307/546 , B32B2307/558 , B32B2307/5825 , B32B2307/714 , B32B2307/7246 , B32B2307/734 , B32B2307/75 , B32B2419/00 , B32B2451/00 , B32B2457/00 , B32B2479/00 , B32B2509/00 , B32B2605/00 , C08J2351/04 , C08J2377/00 , C08L51/00 , C08L51/04 , C08L55/02 , C08L77/00 , C08L77/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： The present invention provides a resin film which is excellent in various properties such as heat resistance, printability, mechanical strength, moisture absorption resistance, film-forming property and flexibility and can be suitably used in the printing applications. There is provided a printing film obtained by molding a thermoplastic resin composition (I) comprising 100 parts by mass in total of a mixed resin comprising 25 to 75% by mass of a rubber-modified styrene-based resin (A) and 25 to 75% by mass of a polyamide-based resin (B). The component (A) comprises a graft copolymer obtained by polymerizing a vinyl-based monomer in the presence of a rubber polymer, or a mixture comprising the graft copolymer and a (co)polymer of the vinyl-based monomer. The vinyl-based monomer comprises an aromatic vinyl compound and a cyanided vinyl compound, and further comprises a functional group-containing vinyl-based monomer in an amount of 0.1 to 1.2% by mass based on the component (A) in which an acetone-soluble component in the component (A) has an intrinsic viscosity of 0.15 to 1.5 dL/g (as measured at 30° C. in methyl ethyl ketone). The composition (I) comprises the rubber polymer in an amount of 5 to 30 parts by mass based on 100 parts by mass of the composition.
摘要翻译：本发明提供了耐热性，印刷性，机械强度，耐吸湿性，成膜性和柔软性等各种性能优异的树脂膜，可适用于印刷用途。提供一种通过模制热塑性树脂组合物（I）而制备的印刷膜，该热塑性树脂组合物（I）包含100质量份，总共包含25至75质量％的橡胶改性的苯乙烯基树脂（A）和25至75 质量％的聚酰胺类树脂（B）。组分（A）包括通过在橡胶聚合物存在下聚合乙烯基类单体或包含接枝共聚物和乙烯基类单体的（共）聚合物的混合物而获得的接枝共聚物。乙烯基类单体包含芳香族乙烯基化合物和氰化乙烯基化合物，并且还含有相对于其中丙酮 - 丙烯酸类单体的成分（A）为0.1〜1.2质量％的含官能团的乙烯基类单体，组分（A）中的可溶成分的特性粘度为0.15〜1.5dL / g（在甲基乙基酮中在30℃下测定）。组合物（I）相对于100质量份组合物，含有5〜30质量份的橡胶聚合物。

10. 发明授权

US08183323B2 Molding material and molded article for laser fusion 有权
标题翻译：用于激光熔合的成型材料和模制品
公开(公告)号：US08183323B2
公开(公告)日：2012-05-22
申请号：US13208921
申请日：2011-08-12
申请人： Ryoichi Motoshige , Wataru Kakuno
发明人： Ryoichi Motoshige , Wataru Kakuno
IPC分类号： C08F8/00 , C08L9/00 , C08L23/04 , C08L23/10
CPC分类号： C08L55/02 , B29C65/16 , B29C65/1606 , B29C65/1616 , B29C65/1635 , B29C65/8215 , B29C65/8253 , B29C66/1122 , B29C66/43 , B29C66/71 , B29C66/7392 , B29C66/73921 , B29C66/9161 , B29C66/919 , B29C66/929 , B29C66/939 , B29K2021/00 , B29K2101/12 , C08F279/02 , C08L25/12 , C08L51/04 , C08L2666/02 , C08L2666/04 , B29C65/00 , B29K2025/08 , B29K2009/00
摘要： A molding material and a molded article for laser welding are provided, which comprise a thermoplastic resin (A) comprising a rubber-reinforced resin (A1) obtained by polymerizing a vinyl monomer in a presence of a rubber-like polymer (a), or a composition (A2) of the rubber-reinforced resin (A1) and a (co)polymer (b) of a vinyl monomer, and which have a light transmittance at a wavelength of 808 nm in a range of 5% or higher when molded into a 4 mm-thick sample piece. The rubber-like polymer (a) dispersed in the thermoplastic resin (A) preferably has a weight average particle size of 50 to 220 nm, and preferably comprises particles of 300 nm or larger in diameter in an amount of 0 to 20 wt % relative to 100 wt % of the component (a). A laser light can transmit the molding material and the molded article, and allow the molding material and the molded article to be laser-welded with various resin moldings.
摘要翻译：提供了一种用于激光焊接的成型材料和模制品，其包括热塑性树脂（A），其包含通过在橡胶状聚合物（a）的存在下聚合乙烯基单体而获得的橡胶增强树脂（A1），或橡胶增强树脂（A1）的组合物（A2）和乙烯基单体的（共）聚合物（b），并且当成型时具有在5nm以上的范围的808nm的光透射率成4mm厚的样品。分散在热塑性树脂（A）中的橡胶状聚合物（a）的重均粒径优选为50〜220nm，优选相对于粒径为0〜20重量％的直径为300nm以上的粒子至100重量％的组分（a）。激光可以传送模塑材料和模塑制品，并且允许模塑材料和模制品用各种树脂模制品进行激光焊接。

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