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    • 1. 发明授权
    • High resolution i-line photoresist of high sensitivity
    • 高灵敏度的高分辨率i线光刻胶
    • US5759740A
    • 1998-06-02
    • US748298
    • 1996-11-13
    • Norbert MunzelReinhard SchulzHeinz HolzwarthStephan Ilg
    • Norbert MunzelReinhard SchulzHeinz HolzwarthStephan Ilg
    • C07D333/24C07C309/28G03F7/004G03F7/038G03F7/039H01L21/027
    • G03F7/0045Y10S430/11Y10S430/111Y10S430/12Y10S430/122Y10S430/123
    • The invention relates to the use of oxime sulfonates of formula 1 ##STR1## wherein R is naphthyl, ##STR2## Ar is an unsubstituted aryl group or an aryl group which carries one or more than one substituent selected from the group consisting of nitro, chloro, bromo, hydroxyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 perfluoroalkyl, C.sub.1 -C.sub.4 alkoxy and acid degradable substituent; R.sub.0 is either a R.sub.1 -X group or R.sub.2 ; X is an oxygen or a sulfur atom; R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or unsubstituted phenyl or phenyl which is substituted by a member selected from the group consisting of chloro, bromo, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 alkoxy, and R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or an acid-degradable substituent, as radiation-sensitive photoacid generator in a chemically amplified photoresist which is developable in alkaline medium and is sensitive to radiation of a wavelength in the range from 340-390 nm, and to corresponding positive-working and negative-working photoresists for the cited wavelength range.
    • 本发明涉及式1的肟磺酸盐,其中R是萘基,Ar是未取代的芳基或芳基,其携带一个或多于一个选自以下的取代基: 硝基,氯,溴,羟基,C 1 -C 4烷基,C 1 -C 4全氟烷基,C 1 -C 4烷氧基和酸可降解取代基; R0是R1-X基团或R2; X是氧或硫原子; R 1是氢,C 1 -C 4烷基或未取代的苯基或被选自氯,溴,C 1 -C 4烷基和C 1 -C 4烷氧基的成员所取代的苯基,R 2是氢,C 1 -C 4烷基或酸可降解取代基 作为在碱性介质中可显影并对波长在340-390nm范围内的辐射敏感的化学放大光致抗蚀剂中的辐射敏感光致酸产生剂,以及用于所述波长的相应的正性和负性光致抗蚀剂 范围。
    • 2. 发明授权
    • High resolution i-line photoresist of high sensitivity
    • 高灵敏度的高分辨率i线光刻胶
    • US5627011A
    • 1997-05-06
    • US440388
    • 1995-05-12
    • Norbert MunzelReinhard SchulzHeinz HolzwarthStephan Ilg
    • Norbert MunzelReinhard SchulzHeinz HolzwarthStephan Ilg
    • C07D333/24C07C309/28G03F7/004G03F7/038G03F7/039H01L21/027
    • G03F7/0045Y10S430/11Y10S430/111Y10S430/12Y10S430/122Y10S430/123
    • The invention relates to the use of oxime sulfonates of formula 1 ##STR1## wherein R is naphthyl, ##STR2## Ar is an unsubstituted aryl group or an aryl group which carries one or more than one substituent selected from the group consisting of nitro, chloro, bromo, hydroxyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 perfluoroalkyl, C.sub.1 -C.sub.4 alkoxy and acid degradable substituents;R.sub.0 is either a R.sub.1 --X group or R.sub.2 ;X is an oxygen or a sulfur atom;R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or unsubstituted phenyl or phenyl which is substituted by a member selected from the group consisting of chloro, bromo, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 alkoxy, andR.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or an acid-degradable substituent, as radiation-sensitive photoacid generator in a chemically amplified photoresist which is developable in alkaline medium and is sensitive to radiation of a wavelength in the range from 340-390 nm, and to corresponding positive-working and negative-working photoresists for the cited wavelength range.
    • 本发明涉及式1的肟磺酸盐,其中R是萘基,Ar是未取代的芳基或芳基,其携带一个或多于一个选自以下的取代基: 硝基,氯,溴,羟基,C 1 -C 4烷基,C 1 -C 4全氟烷基,C 1 -C 4烷氧基和酸可降解取代基; R0是R1-X基团或R2; X是氧或硫原子; R 1是氢,C 1 -C 4烷基或未取代的苯基或被选自氯,溴,C 1 -C 4烷基和C 1 -C 4烷氧基的成员所取代的苯基,R 2是氢,C 1 -C 4烷基或酸可降解取代基 作为在碱性介质中可显影并对波长在340-390nm范围内的辐射敏感的化学放大光致抗蚀剂中的辐射敏感光致酸产生剂,以及用于所述波长的相应的正性和负性光致抗蚀剂 范围。
    • 3. 发明授权
    • High-resolution negative photoresist with wide process latitude
    • 高分辨率负光刻胶,工艺宽广
    • US5650262A
    • 1997-07-22
    • US417119
    • 1995-04-05
    • Norbert MunzelReinhard SchulzHeinz Holzwarth
    • Norbert MunzelReinhard SchulzHeinz Holzwarth
    • C07C39/04G03F7/004G03F7/038H01L21/027
    • G03F7/038G03F7/0045G03F7/0382Y10S430/106Y10S430/122
    • The invention relates to a chemically amplified negative photoresist which can be developed in aqueous alkaline media, which contains a radiation-sensitive acid generator and a compound which reduces the solubility of the resist in aqueous alkaline solutions in the presence of acid, and a polyhydroxyl compound of the formula I ##STR1## in which n is an integer between 2 and 6,R is hydrogen, halogen, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkyl, andZ is an n-valent radical which is unsubstituted or substituted by one or more substituents from the group consisting of hydroxyl, halogen and C.sub.1 -C.sub.4 alkoxy, and is selected from the group consisting of:a) aliphatic radicals having 1 to 12 carbon atoms,b) cycloaliphatic radicals having 5 to 20 carbon atoms,c) aromatic radicals having 6 to 20 carbon atoms andd) radicals having 7 to 30 carbon atoms which comprise at least two different structural units selected from aliphatic, cycloaliphatic or aromatic groups. The resists described make it possible to reduce the demands made on the focusing accuracy during imagewise exposure.
    • 本发明涉及一种可在含水碱性介质中显影的化学放大型负性光致抗蚀剂,其含有辐射敏感性酸产生剂和在酸存在下降低抗蚀剂在碱性水溶液中的溶解度的化合物,以及多羟基化合物 其中n是2和6之间的整数,R是氢,卤素,C 1 -C 4烷氧基或C 1 -C 4烷基,Z是未被取代或被一个取代的n价基团的式I 或更多的选自羟基,卤素和C 1 -C 4烷氧基的取代基,并且选自:a)具有1至12个碳原子的脂族基团,b)具有5至20个碳原子的脂环族基团,c)芳族 具有6至20个碳原子的基团和d)具有7至30个碳原子的基团,其包含至少两个选自脂肪族,脂环族或芳族基团的不同结构单元。 所描述的抗蚀剂使得可以降低在成像曝光期间对聚焦精度的要求。
    • 6. 发明授权
    • Iodonium salts as latent acid donors
    • 碘盐作为潜酸供体
    • US06306555B1
    • 2001-10-23
    • US09740205
    • 2000-12-18
    • Reinhard SchulzJean-Luc BirbaumJean-Pierre WolfStephan IlgHitoshi YamatoToshikage Asakura
    • Reinhard SchulzJean-Luc BirbaumJean-Pierre WolfStephan IlgHitoshi YamatoToshikage Asakura
    • G03F7004
    • G03F7/0382B33Y70/00C07C17/00C07C25/18C07C2601/14C08G59/68C08G65/105G03F7/0045G03F7/038G03F7/0392Y10S430/115
    • Radiation-sensitive compositions comprising (a1) a cationically or acid-catalytically polymerisable or crosslinkable compound or (a2) a compound that increases its solubility in a developer under the action of acid; and (b) at least one diaryliodonium salt of formula I X is branched C3-C20alkyl or C3-C8cycloalkyl; X1 is hydrogen, linear C1-C20alkyl, branched C3-C20alkyl or C3-C8cycloalkyl; with the proviso that the sum of the carbon atoms in X and X1 is at least 4; Y is linear C1-C10alkyl, branched C3-C10alkyl or C3-C8cycloalkyl; A− is a non-nucleophilic anion, selected from the group (BF4)−, (SbF6)−, (PF6)−, (B(C6F5))4−, C1-C20alkylsulfonate, C2-C20haloalkylsulfonate, unsubstituted C6-C10arylsulfonate, camphorsulfonate, and C6-C10arylsulfonate substituted by halogen, NO2, C1-C12alkyl, C1-C12halo-alkyl, C1-C12alkoxy or by COOR1; and R1 is C1-C20alkyl, phenyl, benzyl; or phenyl mono- or poly-substituted by C1-C12alkyl, C1-C12alkoxy or by halogen; with the proviso that the two phenyl rings on the iodine atom are not identically substituted.
    • 辐射敏感性组合物,其包含(a1)阳离子或酸可催化聚合或交联的化合物或(a2)在酸的作用下增加其在显影剂中的溶解度的化合物; 和(b)式IX的至少一种二芳基碘鎓盐是支链C 3 -C 20烷基或C 3 -C 8环烷基; X 1是氢,直链C 1 -C 20烷基,支链C 3 -C 20烷基或C 3 -C 8环烷基; 条件是X和X 1中的碳原子总数至少为4; Y为直链C 1 -C 10烷基,支链C 3 -C 10烷基或C 3 -C 8环烷基; A-为非亲核阴离子,选自(BF 4 ) - ,(SbF 6) - ,(PF 6) - ,(B(C 6 F 5))4-,C 1 -C 20烷基磺酸酯,C 2 -C 20卤代烷基磺酸酯,未取代的C 6 -C 10芳基磺酸酯,樟脑磺酸酯和C 6 -C 10芳基磺酸酯,被卤素, ,C 1 -C 12卤代烷基,C 1 -C 12烷氧基或COOR 1; 并且R 1是C 1 -C 20烷基,苯基,苄基; 或被C 1 -C 12烷基,C 1 -C 12烷氧基或卤素单取代或多取代的苯基;条件是碘原子上的两个苯环不同等取代。
    • 7. 发明申请
    • PNEUMATIC HAMMER MECHANISM AND CONTROL METHOD
    • 气动锤机理及控制方法
    • US20100224380A1
    • 2010-09-09
    • US12697066
    • 2010-01-29
    • Alexander JOHNReinhard SchulzEduard Pfeiffer
    • Alexander JOHNReinhard SchulzEduard Pfeiffer
    • B25D11/06
    • B25D11/125B25D11/005B25D2250/245
    • A pneumatic hammer mechanism is disclosed. The hammer mechanism features: a flying mass, which is movable along an impact axis; an impact surface, which limits a movement of the flying mass along the impact axis in the impact direction; a hammer piston, which limits a movement of the flying mass along the impact axis opposite from the impact direction; a pneumatic chamber between the flying mass and hammer piston; a drive for periodically moving the hammer piston with a stroke along the impact axis, wherein the flying mass is excited to a periodic movement between the impact surface and hammer piston. The stroke is selected as a function of a maximum length of the pneumatic chamber such that the periodic movement of the flying mass on the path between an impact on the impact surface and a minimum approach of the hammer piston intermittently has a velocity of zero.
    • 公开了一种气动锤机构。 锤子机构具有:可沿着冲击轴线移动的飞行质量块; 撞击表面,其限制飞行质量沿冲击轴线在冲击方向上的运动; 一个锤子活塞,其限制飞行质量块沿冲击轴线与冲击方向相反的运动; 飞行质量块和锤式活塞之间的气动室; 驱动器,用于沿着冲击轴线周期性地移动锤子活塞,其中飞行质量被激发以在冲击表面和锤形活塞之间的周期性运动。 作为气动室的最大长度的函数来选择行程,使得飞行质量在冲击表面上的冲击和锤式活塞的最小接近之间的路径上的周期性运动具有零速度。