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1. 发明授权

US4538009A Preparation of substituted phenols 失效
标题翻译：取代苯酚的制备
公开(公告)号：US4538009A
公开(公告)日：1985-08-27
申请号：US599574
申请日：1984-04-12
申请人： Norbert Goetz , Harald Laas , Peter Tavs , Leopold Hupfer , Karl Baer
发明人： Norbert Goetz , Harald Laas , Peter Tavs , Leopold Hupfer , Karl Baer
IPC分类号： C07C37/055 , B01J23/00 , B01J23/42 , B01J23/44 , B01J23/58 , B01J23/60 , B01J23/89 , C07B61/00 , C07C27/00 , C07C37/06 , C07C37/07 , C07C39/06 , C07C67/00
CPC分类号： C07C37/07 , B01J23/005 , B01J23/58 , B01J23/60 , B01J23/89 , C07C37/06
摘要： Substituted phenols of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each hydrogen or an aliphatic or aromatic hydrocarbon radical, are prepared by dehydrogenating a cyclic alcohol of the general formula II ##STR2## or a cyclic ketone of the general formula III ##STR3## where one of the broken lines can be an additional C-C bond, in the gas phase at from 150.degree. to 380.degree. C. over a supported noble metal catalyst, by a process in which the dehydrogenation catalyst used is palladium or platinum on an aluminum spinel carrier, in particular an aluminum spinel which has a BET specific surface area of from 5 to 150 m.sup.2 /g or, for the dehydrogenation of cyclohexenones, preferably from 10 to 50 m.sup.2 /g. Particularly suitable aluminum spinels are those which, in addition to aluminum, contain magnesium, zinc, cobalt or nickel.In the novel process, substituted phenols are obtained in high yields and selectivities, and the catalyst has an extremely long life without a significant decrease in activity.
摘要翻译：通式Ⅰ的取代的酚Ⅰ，其中R 1，R 2，R 3，R 4和R 5各自为氢或脂族或芳族烃基，通过将通式II II的环醇脱氢或环状酮，其中一条虚线可以是额外的CC键，在负载型贵金属催化剂的150〜380℃的气相中，其中，所用的脱氢催化剂是钯尖晶石载体上的钯或铂，特别是BET比表面积为5〜150m 2 / g的尖晶石，或者环己烯酮的脱氢优选为10〜50m2 / g。特别合适的铝尖晶石是除了铝之外还含有镁，锌，钴或镍的铝尖晶石。在新方法中，以高产率和选择性获得取代的酚，并且催化剂具有极长的寿命而没有显着降低活性。

2. 发明授权

US5130435A Preparation of vinyl ethers 失效
标题翻译：乙烯的制备
公开(公告)号：US5130435A
公开(公告)日：1992-07-14
申请号：US565180
申请日：1990-08-09
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C41/28
CPC分类号： C07C41/28 , Y02P20/582
摘要： Vinyl ethers of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are identical to or different from one another, each being hydrogen, straight-chain or branched alkyl or alkenyl of up to 12 carbon atoms, cycloalkyl or cycloalkylene of from 5 to 8 carbon atoms, aryl, alkylaryl, alkenylaryl, aralkyl and aralkenyl of from 6 to 16 carbon atoms, halogen-substituted aryl or heterocyclyl, and in addition the radicals R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, can form a cycloalkane, cycloalkene or a heterocycle, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by eliminating an alcohol from an acetal/ketal of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each as defined above, in the presence of a phosphate of zeolite structure and/or a precipitated phosphate of the elements B, Zr, Ce or Fe and/or phosphoric acid or boric acid on carrier material and/or acidic undoped metal oxide as catalyst, the reaction being preferably carried out in the gas phase.
摘要翻译：式中，R 1，R 2和R 3彼此相同或不同的乙烯基醚，各自为氢，直至12个碳原子的直链或支链烷基或烯基，5至8的环烷基或亚环烷基碳原子，芳基，烷基芳基，烯基芳基，芳烷基和具有6至16个碳原子的芳烯基，卤素取代的芳基或杂环基，此外基团R 1和R 2或R 1和R 3与它们所键合的碳原子一起可以形成环烷烃，环烯烃或杂环，并且R 4是烷基，烷基芳基或芳烷基，通过从式（I）的缩醛/缩酮中除去醇来制备，其中R 1，R 2，R 3和R 4各自如上所定义在载体材料和/或酸性未掺杂的金属氧化物作为催化剂的沸石结构的磷酸盐和/或元素B，Zr，Ce或Fe和/或磷酸或硼酸的沉淀磷酸盐存在下，反应为优选在气相中进行。

3. 发明授权

US4891451A Preparation of vinyl ethers 失效
标题翻译：乙烯基醚的制备
公开(公告)号：US4891451A
公开(公告)日：1990-01-02
申请号：US213589
申请日：1988-06-30
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C41/28
CPC分类号： C07C41/28 , C07C2101/14 , Y02P20/582
摘要： Vinyl ethers of the formula (I) ##STR1## where R.sup.1 to R.sup.3 are identical or different and are each hydrogen, a straight-chain or branched alkyl or alkenyl radical of not more than 12 carbon atoms, halogen-substituted alkyl, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, alkenylaryl, aralkyl or aralkenyl radical of 6 to 16 carbon atoms, halogen-substituted aryl or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, may form a cycloalkane, cycloalkene or heterocyclic structure, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by a process in which an alcohol is eliminated from an acetal or ketal of the formula (II) ##STR2## where R.sup.1 to R.sup.4 have the above meanings, in the presence of borosilicate and/or iron silicate zeolites as catalysts.
摘要翻译：式（I）的乙烯基醚其中R 1至R 3相同或不同并且各自为氢，不超过12个碳原子的直链或支链烷基或烯基，卤素取代的烷基， 5至8个碳原子的环烷基或环烯基，6至16个碳原子的芳基，烷基芳基，烯基芳基，芳烷基或芳烯基，卤素取代的芳基或杂环基，此外R1和R2或R1和R3连同其键合的碳原子可以通过其中从式（II）的缩醛或缩酮中除去醇的方法制备环烷烃，环烯烃或杂环结构，并且R 4是烷基，烷基芳基或芳烷基，在有硼硅酸盐和/或铁硅酸盐沸石作为催化剂的情况下，R1至R4具有上述含义的图像（II）。

4. 发明授权

US4812593A Preparation of bifunctional compounds 失效
标题翻译：双功能化合物的制备
公开(公告)号：US4812593A
公开(公告)日：1989-03-14
申请号：US82127
申请日：1987-08-06
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C45/51 , C07C45/67 , C07C45/71 , C07C47/198 , C07C47/277 , C07C49/175 , C07C49/255 , C07C67/327 , C07C69/708 , C07C69/734 , C07C69/73
CPC分类号： C07C45/71 , C07C45/515 , C07C45/673 , C07C47/198 , C07C47/277 , C07C49/175 , C07C49/255 , C07C67/327
摘要： Bifunctional compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of 1 to 6 carbon atoms, R.sup.2 and R.sup.3 may furthermore be hydrogen, R.sup.2 is furthermore alkoxy and R.sup.4 is hydrogen, alkyl of 1 to 6 carbon atoms or alkoxy, and a double bond may be present between carbon atoms 2 and 3, are prepared by converting a tetraalkoxyalkane or a dialkoxyalkanoate of the formulae ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meanings, in the presence of a catalyst, such as a zeolite, in particular one of the pentasil type, and/or a phosphate and/or phosphoric acid on a carrier.
摘要翻译：其中R 1，R 2和R 3各自为1至6个碳原子的烷基，R 2和R 3可以另外为氢，R 2为烷氧基，且R 4为氢，具有1-6个碳原子的烷基或烷氧基，并且碳原子2和3之间可以存在双键，通过在催化剂存在下，将式Ia，R2，R3和R4具有上述含义的四烷氧基烷烃或二烷氧基烷酸酯进行转化来制备，例如沸石，特别是pentasil类中的一种，和/或载体上的磷酸盐和/或磷酸。

5. 发明授权

US4298733A Preparation of cis-2,6-dimethylmorpholine 失效
标题翻译：顺式-2,6-二甲基吗啉的制备
公开(公告)号：US4298733A
公开(公告)日：1981-11-03
申请号：US184816
申请日：1980-09-08
申请人： Norbert Goetz , Walter Himmele , Leopold Hupfer
发明人： Norbert Goetz , Walter Himmele , Leopold Hupfer
IPC分类号： C07D265/30 , B01J23/60 , B01J23/656 , C07B61/00 , C07D295/023
CPC分类号： C07D295/023
摘要： A process for the preparation of cis-2,6-dimethylmorpholine by isomerizing trans-2,6-dimethylmorpholine, wherein trans-2,6-dimethylmorpholine is converted, in the presence of hydrogen and of a catalyst containing palladium as well as zinc, cadmium or manganese or a mixture of these, at from 150.degree. to 250.degree. C. under a pressure of from 1 to 200 bar.
摘要翻译：通过异构化反式-2,6-二甲基吗啉，其中反式-2,6-二甲基吗啉在氢气和含有钯的催化剂以及锌的存在下转化而制备顺式-2,6-二甲基吗啉的方法，镉或锰或它们的混合物，在150-250℃，1至200巴的压力下进行。

6. 发明授权

US4980511A Preparation of aldehydes and/or ketones BU conversion of epoxides 失效
标题翻译：醛和/或酮的制备BU转化环氧化物
公开(公告)号：US4980511A
公开(公告)日：1990-12-25
申请号：US100725
申请日：1987-09-25
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Helmut Lermer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Helmut Lermer
IPC分类号： B01J27/16 , B01J27/18 , B01J27/182 , B01J27/185 , B01J29/04 , C07C45/58
CPC分类号： C07C45/58 , B01J27/16 , B01J27/1804 , B01J27/182 , B01J27/1853 , B01J29/04 , Y02P20/582
摘要： Aldehydes and ketones are prepared from epoxides of the formula ##STR1## where R.sup.1 and R.sup.2 are each alkyl, alkenyl, aryl, alkoxy or aralkyl and R.sup.3 has the same meanings or is hydrogen, by a catalytic rearrangement reaction in the presence of various catalysts, in particular zeolites of the pentasil type.
摘要翻译：醛和酮是由各种催化剂存在下的催化重排反应由式（Ⅰ）的环氧化物制备，其中R 1和R 2各自为烷基，烯基，芳基，烷氧基或芳烷基，R 3具有相同的含义或为氢，特别是pentasil类型的沸石。

7. 发明授权

US4968831A Preparation of .alpha.-ketocarboxylic esters 失效
标题翻译： α-酮羧酸酯的制备
公开(公告)号：US4968831A
公开(公告)日：1990-11-06
申请号：US323861
申请日：1989-03-15
申请人： Norbert Goetz , Wolfgang Hoelderich , Leopold Hupfer
发明人： Norbert Goetz , Wolfgang Hoelderich , Leopold Hupfer
IPC分类号： C07C67/313 , C07C69/738 , C07C69/76
CPC分类号： C07C67/313 , C07C69/738
摘要： .alpha.-Ketocarboxylic esters ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are identical to or different from one another and are each hydrogen or straight-chain or branched alkyl, alkenyl, hydroxyl, alkoxy cycloalkyl or halogen and R.sup.6 is unbranched lower alkyl, are prepared by reacting glycidic esters of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, in the presence of zeolites or phosphates and/or phosphoric acid or boric acid on a carrier material and/or acidic metal oxides as catalysts and are used for preparing phenylacetic esters.
摘要翻译： α-酮羧酸酯，其中R 1，R 2，R 3，R 4和R 5彼此相同或不同，各自为氢或直链或支链烷基，烯基，羟基，烷氧基环烷基或卤素，R6为未分支的烷基，通过在载体上的沸石或磷酸盐和/或磷酸或硼酸的存在下使式（I）的缩水甘油酯反应来制备，其中R 1，R 2，R 3，R 4，R 5和R 6各自如上所定义材料和/或酸性金属氧化物作为催化剂，并用于制备苯乙酸酯。

8. 发明授权

US4824973A Preparation of 4-formyltetrahydropyrans 失效
标题翻译： 4-甲酰基四氢吡喃的制备
公开(公告)号：US4824973A
公开(公告)日：1989-04-25
申请号：US89752
申请日：1987-08-26
申请人： Wolfgang Spiegler , Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Jochen Wild
发明人： Wolfgang Spiegler , Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Jochen Wild
IPC分类号： A01N43/18 , B01J29/40 , B01J29/70 , B01J29/83 , B01J29/85 , B01J29/86 , C07D309/06 , C07D405/04 , C07D407/04 , C07D409/04 , C07D333/22
CPC分类号： C07D309/06 , Y02P20/582
摘要： 4-Formyltetrahydropyrans of the general formula I ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl, C.sub.1 -C.sub.6 -alkoxy-substituted C.sub.1 -C.sub.12 -alkyl, C.sub.4 -C.sub.12 -cycloalkyl, unsubstituted or substituted aryl, hetaryl or aralkyl, or an unsubstituted or substituted, saturated or unsaturated 5-membered or 6-membered ring which may be interrupted by N, O or S, are prepared by a process in which a pyran derivative of the general formula II ##STR2## where R.sup.1 is as defined above, R.sup.2 and R.sup.3 are each OH or together are an oxygen atom and thus form an oxirane ring, and R.sup.4 is hydrogen where R.sup.2 and R.sup.3 are each OH, and is hydrogen or tert-butoxycarbonyl where R.sup.2 and R.sup.3 together are an oxygen atom, is treated at elevated temperatures with a catalyst selected from the group consisting of zeolites, phosphates, boric acid on a carrier and silica or mixtures of these. Novel 4-formyltetrahydropyrans are also proposed.
摘要翻译：其中R 1是氢，C 1 -C 12烷基，C 2 -C 12链烯基，C 1 -C 6烷氧基取代的C 1 -C 12烷基，C 4 -C 12环烷基，C 1 -C 12 - 烷基，未取代或取代的芳基，杂芳基或芳烷基，或可被N，O或S中断的未取代或取代的饱和或不饱和的5元或6元环，是通过一般方法制备的，式II其中R 1如上所定义，R 2和R 3各自为OH或一起为氧原子，因此形成环氧乙烷环，并且R 4为氢，其中R 2和R 3各自为OH并且为氢或叔丁氧基羰基，其中R 2和R 3一起是氧原子，在高温下用选自沸石，磷酸盐，载体上的硼酸和二氧化硅或它们的混合物的催化剂进行处理。还提出了新的4-甲酰基四氢吡喃。

9. 发明授权

US5225602A Phenylacetaldehydes and the preparation of phenylacetaldehydes 失效
标题翻译：苯乙酮和苯乙酮的制备
公开(公告)号：US5225602A
公开(公告)日：1993-07-06
申请号：US425372
申请日：1989-10-17
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Rudolf Kropp , Hans Theobald , Bernd Wolf
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer , Rudolf Kropp , Hans Theobald , Bernd Wolf
IPC分类号： C07C47/228 , C07C45/00 , C07C45/41 , C07C45/51 , C07C45/52 , C07C45/54 , C07C45/58 , C07C47/24 , C07C47/277 , C07C67/00 , C07C313/00 , C07C323/22
CPC分类号： C07C47/277 , C07C323/00 , C07C45/41 , C07C45/512 , C07C45/513 , C07C45/52 , C07C45/54 , C07C45/58 , C07C47/24 , Y02P20/582
摘要： Phenylacetaldehydes of the structure (I) ##STR1## where the substituents X are 2,4-dichloro, difluoro, trifluoro, tetrafluoro, p-trifluoromethyl, 2-methyl-4-fluoro, haloalkoxy or haloalkylthio radicals or are adjacent Cl, F, CF.sub.3, alkyl, alkoxy, haloalkoxy and/or haloalkylthio radicals.
摘要翻译：其中取代基X为2,4-二氯，二氟，三氟，四氟，对三氟甲基，2-甲基-4-氟，卤代烷氧基或卤代烷硫基，或与Cl相邻的苯基乙醛，F，CF 3，烷基，烷氧基，卤代烷氧基和/或卤代烷基硫基。

10. 发明授权

US4990684A Preparation of phenylacetaldehydes 失效
标题翻译：苯乙醛的制备
公开(公告)号：US4990684A
公开(公告)日：1991-02-05
申请号：US378984
申请日：1989-07-12
申请人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
发明人： Wolfgang Hoelderich , Norbert Goetz , Leopold Hupfer
IPC分类号： C07C45/51 , C07C45/52 , C07C45/54 , C07C45/58
CPC分类号： C07C45/58 , C07C45/512 , C07C45/513 , C07C45/52 , C07C45/54 , Y02P20/582
摘要： Phenylacetaldehydes of the general formula I ##STR1## where each of R.sup.1 to R.sup.5 is independently of the others hydrogen, halogen, unsubstituted or halogen-substituted alkyl, alkenyl, alkoxyl, alkylthio or cycloalkyl, are prepared by converting glycidic esters of the general formula II ##STR2## where each of R.sup.1 to R.sup.5 is as defined above and R.sup.6 is tertbutyl or i-propyl, in the presence of zeolites and/or phosphates and/or phosphoric or boric acid on a carrier material and/or acidic metal oxides as catalysts.
摘要翻译：通式Ⅰ（I）的苯基乙醛通过将式（I）的缩水甘油酯转化成其中R1至R5各自独立地为氢，卤素，未取代或卤素取代的烷基，烯基，烷氧基，烷硫基或环烷基，在载体材料上的沸石和/或磷酸盐和/或磷酸或硼酸存在下，通式II（II）其中R 1至R 5各自如上所定义，R 6为叔丁基或异丙基，和/ 或酸性金属氧化物作为催化剂。

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