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1. 发明授权

US08124503B2 Carbon nanotube diameter selection by pretreatment of metal catalysts on surfaces 有权
标题翻译：通过在表面上预处理金属催化剂的碳纳米管直径选择
公开(公告)号：US08124503B2
公开(公告)日：2012-02-28
申请号：US12281611
申请日：2007-03-05
申请人： Robert H. Hauge , Ya-Qiong Xu , Hongwei Shan , Nolan Walker Nicholas , Myung Jong Kim , Howard K. Schmidt , W. Carter Kittrell
发明人： Robert H. Hauge , Ya-Qiong Xu , Hongwei Shan , Nolan Walker Nicholas , Myung Jong Kim , Howard K. Schmidt , W. Carter Kittrell
IPC分类号： H01L21/20
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02 , C01B2202/08 , C01B2202/36
摘要： A new and useful nanotube growth substrate conditioning processes is herein disclosed that allows the growth of vertical arrays of carbon nanotubes where the average diameter of the nanotubes can be selected and/or controlled as compared to the prior art.
摘要翻译：本文公开了一种新的有用的纳米管生长衬底调理方法，其允许碳纳米管的垂直阵列的生长，其中与现有技术相比，可以选择和/或控制纳米管的平均直径。

2. 发明申请

US20090294753A1 CARBON NANOTUBE DIAMETER SELECTION BY PRETREATMENT OF METAL CATALYSTS ON SURFACES 有权
标题翻译：通过预处理金属催化剂在表面上的碳纳米管直径选择
公开(公告)号：US20090294753A1
公开(公告)日：2009-12-03
申请号：US12281611
申请日：2007-03-05
申请人： Robert H. Hauge , Ya-Qiong Xu , Hongwei Shan , Nolan Walker Nicholas , Myung Jong Kim , Howard K. Schmidt , W. Carter Kittrell
发明人： Robert H. Hauge , Ya-Qiong Xu , Hongwei Shan , Nolan Walker Nicholas , Myung Jong Kim , Howard K. Schmidt , W. Carter Kittrell
IPC分类号： H01L29/66 , H01L21/20 , C01B31/02 , B05D5/12
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02 , C01B2202/08 , C01B2202/36
摘要： A new and useful nanotube growth substrate conditioning processes is herein disclosed that allows the growth of vertical arrays of carbon nanotubes where the average diameter of the nanotubes can be selected and/or controlled as compared to the prior art.
摘要翻译：本文公开了一种新的有用的纳米管生长衬底调理方法，其允许碳纳米管的垂直阵列的生长，其中与现有技术相比，可以选择和/或控制纳米管的平均直径。

3. 发明授权

US09067791B2 Embedded arrays of vertically aligned carbon nanotube carpets and methods for making them 有权
标题翻译：垂直排列的碳纳米管地毯的嵌入式阵列及其制造方法
公开(公告)号：US09067791B2
公开(公告)日：2015-06-30
申请号：US12297115
申请日：2007-04-23
申请人： Myung Jong Kim , Nolan Walker Nicholas , W. Carter Kittrell , Howard K. Schmidt
发明人： Myung Jong Kim , Nolan Walker Nicholas , W. Carter Kittrell , Howard K. Schmidt
IPC分类号： B32B5/16 , B29C45/14 , H01B1/04 , B82Y30/00 , C01B31/02 , B82Y10/00 , B82Y40/00 , H01L51/00
CPC分类号： C01B31/0206 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , H01L51/0048 , Y10T428/249924
摘要： According to some embodiments, the present invention provides a system and method for supporting a carbon nanotube array that involve an entangled carbon nanotube mat integral with the array, where the mat is embedded in an embedding material. The embedding material may be depositable on a carbon nanotube. A depositable material may be metallic or nonmetallic. The embedding material may be an adhesive material. The adhesive material may optionally be mixed with a metal powder. The embedding material may be supported by a substrate or self-supportive. The embedding material may be conductive or nonconductive. The system and method provide superior mechanical and, when applicable, electrical, contact between the carbon nanotubes in the array and the embedding material. The optional use of a conductive material for the embedding material provides a mechanism useful for integration of carbon nanotube arrays into electronic devices.
摘要翻译：根据一些实施方案，本发明提供了一种用于支撑碳纳米管阵列的系统和方法，所述碳纳米管阵列涉及与所述阵列整合的缠结碳纳米管垫，其中所述垫嵌入嵌入材料中。嵌入材料可以沉积在碳纳米管上。可存放材料可以是金属或非金属的。嵌入材料可以是粘合剂材料。粘合剂材料可以任选地与金属粉末混合。嵌入材料可以由衬底支撑或自支撑。嵌入材料可以是导电的或非导电的。该系统和方法在阵列中的碳纳米管和嵌入材料之间提供优异的机械性能，并且在适用时提供电气接触。可选地使用用于嵌入材料的导电材料提供了用于将碳纳米管阵列集成到电子器件中的机制。

4. 发明授权

US08394664B2 Electrical device fabrication from nanotube formations 失效
标题翻译：电子器件制造从纳米管形成
公开(公告)号：US08394664B2
公开(公告)日：2013-03-12
申请号：US11910522
申请日：2007-02-02
申请人： Nolan Walker Nicholas , W. Carter Kittrell , Myung Jong Kim , Howard K. Schmidt
发明人： Nolan Walker Nicholas , W. Carter Kittrell , Myung Jong Kim , Howard K. Schmidt
IPC分类号： H01L51/10 , H01L51/40
CPC分类号： H01L51/057 , B82Y10/00 , H01L51/0048
摘要： A method for forming nanotube electrical devices, arrays of nanotube electrical devices, and device structures and arrays of device structures formed by the methods. Various methods of the present invention allow creation of semiconducting and/or conducting devices from readily grown SWNT carpets rather than requiring the preparation of a patterned growth channel and takes advantage of the self-controlling nature of these carpet heights to ensure a known and controlled channel length for reliable electronic properties as compared to the prior methods.
摘要翻译：用于形成纳米管电子器件的方法，纳米管电子器件的阵列，以及通过该方法形成的器件结构和器件结构的阵列。本发明的各种方法允许从容易生长的SWNT地毯制造半导体和/或导电装置，而不需要制备图案化的生长通道，并利用这些毯子高度的自我控制性质来确保已知和受控的通道与现有方法相比可靠的电子性能。

5. 发明申请

US20120107597A1 EMBEDDED ARRAYS OF VERTICALLY ALIGNED CARBON NANOTUBE CARPETS AND METHODS FOR MAKING THEM 有权
标题翻译：垂直对准碳纳米管地毯的嵌入阵列及其制备方法
公开(公告)号：US20120107597A1
公开(公告)日：2012-05-03
申请号：US12297115
申请日：2007-04-23
申请人： Myung Jong Kim , Nolan Walker Nicholas , W. Carter Kittrell , Howard K. Schmidt
发明人： Myung Jong Kim , Nolan Walker Nicholas , W. Carter Kittrell , Howard K. Schmidt
IPC分类号： B32B5/16 , B29C45/14 , H01B1/04 , B82Y30/00
CPC分类号： C01B31/0206 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , H01L51/0048 , Y10T428/249924
摘要： According to some embodiments, the present invention provides a system and method for supporting a carbon nanotube array that involve an entangled carbon nanotube mat integral with the array, where the mat is embedded in an embedding material. The embedding material may be depositable on a carbon nanotube. A depositable material may be metallic or nonmetallic. The embedding material may be an adhesive material. The adhesive material may optionally be mixed with a metal powder. The embedding material may be supported by a substrate or self-supportive. The embedding material may be conductive or nonconductive. The system and method provide superior mechanical and, when applicable, electrical, contact between the carbon nanotubes in the array and the embedding material. The optional use of a conductive material for the embedding material provides a mechanism useful for integration of carbon nanotube arrays into electronic devices.
摘要翻译：根据一些实施方案，本发明提供了一种用于支撑碳纳米管阵列的系统和方法，所述碳纳米管阵列涉及与所述阵列整合的缠结碳纳米管垫，其中所述垫嵌入嵌入材料中。嵌入材料可以沉积在碳纳米管上。可存放材料可以是金属或非金属的。嵌入材料可以是粘合剂材料。粘合剂材料可以任选地与金属粉末混合。嵌入材料可以由衬底支撑或自支撑。嵌入材料可以是导电的或非导电的。该系统和方法在阵列中的碳纳米管和嵌入材料之间提供优异的机械性能，并且在适用时提供电气接触。可选地使用用于嵌入材料的导电材料提供了用于将碳纳米管阵列集成到电子器件中的机制。

6. 发明申请

US20100140591A1 ELECTRICAL DEVICE FABRICATION FROM NANOTUBE FORMATIONS 失效
标题翻译：电子设备制造从NANOTUBE FORMATIONS
公开(公告)号：US20100140591A1
公开(公告)日：2010-06-10
申请号：US11910522
申请日：2007-02-02
申请人： Nolan Walker Nicholas , W Carter Kittrell , Myung Jong Kim , Howard K. Schmidt
发明人： Nolan Walker Nicholas , W Carter Kittrell , Myung Jong Kim , Howard K. Schmidt
IPC分类号： H01L51/10 , H01L51/40
CPC分类号： H01L51/057 , B82Y10/00 , H01L51/0048
摘要： A method for forming nanotube electrical devices, arrays of nanotube electrical devices, and device structures and arrays of device structures formed by the methods. Various methods of the present invention allow creation of semiconducting and/or conducting devices from readily grown SWNT carpets rather than requiring the preparation of a patterned growth channel and takes advantage of the self-controlling nature of these carpet heights to ensure a known and controlled channel length for reliable electronic properties as compared to the prior methods.
摘要翻译：用于形成纳米管电子器件的方法，纳米管电子器件的阵列，以及通过该方法形成的器件结构和器件结构的阵列。本发明的各种方法允许从容易生长的SWNT地毯制造半导体和/或导电装置，而不需要制备图案化的生长通道，并利用这些毯子高度的自我控制性质来确保已知和受控的通道与现有方法相比可靠的电子性能。

7. 发明申请

US20230071676A1 SYSTEM AND METHOD FOR MODULATING ELECTRICAL PROCESSES IN CONTACT WITH A CONDENSED PHASE 有权
公开(公告)号：US20230071676A1
公开(公告)日：2023-03-09
申请号：US17903299
申请日：2022-09-06
申请人： Nolan Walker Nicholas
发明人： Nolan Walker Nicholas
IPC分类号： G01N27/414 , H01L29/76
摘要： A device for interacting with a quantity of a sample, the device, comprising: a substrate comprising a first surface and a second surface, wherein the first surface is opposite to the second surface; an electrically-thin conductive layer disposed on the first surface of the substrate and configured to contact a first portion of the sample; a buried electrode disposed on the second surface of the substrate, the buried electrode being capacitively coupled with the electrically-thin conductive layer; and at least one electrode in contact with a second portion of the sample, wherein the second portion of the sample is remote from the first portion of the sample, and further wherein the at least one electrode and the electrically-thin conductive layer electrically interact via the sample; wherein the substrate is configured such that the substrate does not substantially conduct the flow of electric current through the electrically-thin conductive layer.

8. 发明申请

US20120071610A1 REGIOFUNCTIONAL CARBON NANOTUBE BEAM AND METHOD 审中-公开
标题翻译：功能性碳纳米管束和方法
公开(公告)号：US20120071610A1
公开(公告)日：2012-03-22
申请号：US13045047
申请日：2011-03-10
申请人： Nolan Walker Nicholas
发明人： Nolan Walker Nicholas
IPC分类号： C08F8/00 , C01B31/04 , C01B33/00 , C07C2/00 , C07C41/01 , C01B35/00 , B82Y40/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168
摘要： The present invention is generally directed toward a method to create an enhanced carbon nanotube spaceframe network. The spaceframe network contains an assembly of regiofunctional carbon nanotube beams by crown-to-crown connection into nodes to form a networked lattice configuration. The inventive method includes selecting crown materials and applying appropriate processing conditions which result in the production of secondary forms. The crown materials include polymers with unsaturated sites, polymeric crowns, silicon boron, poly(hydridocarbyne). The processing conditions include radical initiation, vulcanization, pyrolysis, hydroboration at unsaturation sites, using silicon bearing polymers in the Rf-CNB crowns, dissolution of silicon containing organics into the nodes and poly(hydridocarbyne). The secondary forms include cross-linked polymers, carbonized, graphitized, ceramic, diamond-like along with tailored functionalization.
摘要翻译：本发明一般涉及一种创建增强型碳纳米管空间框架网络的方法。空间框架网络包含通过冠 - 冠连接到节点中的区域功能性碳纳米管束的组合以形成网络格子构型。本发明的方法包括选择冠状材料并施加导致二次形式生产的适当的加工条件。冠状材料包括具有不饱和位点的聚合物，聚合物冠，硅硼，聚（hydridcarbyne）。处理条件包括自由基引发，硫化，热解，不饱和位点的硼氢化，在Rf-CNB冠中使用含硅聚合物，将含硅有机物溶解于节点和聚（hydridocarbyne）中。二次形式包括交联聚合物，碳化，石墨化，陶瓷，类金刚石以及定制的功能化。

9. 发明申请

US20120041153A1 REGIOFUNCTIONAL CARBON NANOTUBE BEAM AND METHOD 审中-公开
标题翻译：功能性碳纳米管束和方法
公开(公告)号：US20120041153A1
公开(公告)日：2012-02-16
申请号：US12854763
申请日：2010-08-11
申请人： Nolan Walker Nicholas
发明人： Nolan Walker Nicholas
IPC分类号： C08F8/14 , C01B31/00 , C23F1/00 , B01J19/00 , C07D493/02 , C08F36/06 , B82Y40/00 , B82Y30/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174
摘要： The present invention is generally directed toward a regiofunctional carbon nanotube beam structures and a method the same. The regiofunctional carbon nanotube beam structures contain chemical moieties attached selectively to the ends and/or the sidewalls of the nanotube which differentiate the physico-chemical properties of the nanotube ends from the physico-chemical of the sidewalls to enable directed self-assembly. The method comprises the steps including opening carbon nanotube ends, protecting those ends from sidewall functionalization chemistry by chemically differentiating the open carbon nanotube ends from the nanotube sidewall, functionalizing the sidewalls, functionalizing the ends of the carbon nanotube and attaching crown to ends.
摘要翻译：本发明一般涉及区域功能性碳纳米管束结构及其方法。区域功能性碳纳米管束结构包含选择性地连接到纳米管的端部和/或侧壁的化学部分，其将纳米管末端的物理化学性质与侧壁的物理化学性质区分开，使得能够引导自组装。该方法包括以下步骤：打开碳纳米管末端，通过将开放碳纳米管末端与纳米管侧壁进行化学分化来保护端部免受侧壁官能化化学反应，使侧壁功能化，使碳纳米管的端部官能化并将冠部附着到端部。

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