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1. 发明授权

US5124291A Method for deagglomerating and re-exposing catalyst in a fluid bed reactor 失效
标题翻译：催化剂在流化床反应器中解聚和再曝光的方法
公开(公告)号：US5124291A
公开(公告)日：1992-06-23
申请号：US614311
申请日：1990-11-15
申请人： Noel J. Bremer , Louis R. Trott , Timothy R. McDonel
发明人： Noel J. Bremer , Louis R. Trott , Timothy R. McDonel
IPC分类号： B01J8/00 , B01J8/24 , B01J8/38 , B01J38/04 , B01J38/30 , C01B7/04 , C07C51/215 , C07C51/31 , C07C57/04 , C07C253/26 , C07C255/08 , C10B53/00 , C10G11/18 , C10J3/54
CPC分类号： B01J8/1827 , B01J38/04 , B01J38/30 , B01J8/0055 , B01J8/386 , C07C51/215 , C07C51/31 , B01J2208/00681 , Y02P20/584 , Y10S502/518
摘要： A fluid bed catalyst which has lost activity or fluidization quality through agglomeration, contamination, or a physical or chemical change on the surface of the catalyst is deagglomerated and/or its surface re-exposed, by contacting the fluidized catalyst with a high velocity gas sufficient to cause multiple collisions among the catalyst particles and thereby deagglomerating the particles and/or abrading the surface of the particles to expose fresh catalyst.
摘要翻译：通过使流化催化剂与足够的高速气体接触，使催化剂表面上通过附聚，污染或物理或化学变化而失去活性或流化性质的流化床催化剂被解聚和/或其表面再暴露以引起催化剂颗粒之间的多次碰撞，从而使颗粒解聚和/或研磨颗粒的表面以暴露新鲜的催化剂。

2. 发明授权

US5474960A Process for reactivating a fluid bed catalyst in a reactor dipley 失效
标题翻译：在反应器二次重复活化流化床催化剂的方法
公开(公告)号：US5474960A
公开(公告)日：1995-12-12
申请号：US259814
申请日：1994-06-15
申请人： Noel J. Bremer , Louis R. Trott , David R. Woodbury
发明人： Noel J. Bremer , Louis R. Trott , David R. Woodbury
IPC分类号： B01J27/28 , B01J38/04 , B01J38/22 , C07C51/215 , B01J38/10 , B01J27/198
CPC分类号： B01J27/285 , C07C51/215 , Y02P20/584
摘要： The present invention relates to improvements of fluid bed catalysts. More particularly, the present invention relates to improvements of fluid bed oxidation catalysts useful in the preparation of maleic anhydride from C.sub.4 hydrocarbons, including n-butane. The present invention includes a process of contacting a fluid bed catalyst with a reactivating agent in a catalyst standpipe. The present invention also provides a catalyst containing the mixed oxides of vanadium and phosphorus, treated using the above process. The present invention further provides a process for producing maleic anhydride, utilizing the catalyst prepared using the above process. The present invention additionally provides for a reactor standpipe, utilized for regenerating catalyst according to the above process.
摘要翻译：本发明涉及流化床催化剂的改进。更具体地说，本发明涉及用于从C4烃（包括正丁烷）制备马来酸酐的流化床氧化催化剂的改进。本发明包括使流化床催化剂与催化剂立管中的再活化剂接触的方法。本发明还提供了使用上述方法处理的含有钒和磷的混合氧化物的催化剂。本发明还提供使用上述方法制备的催化剂生产马来酸酐的方法。本发明另外提供了一种用于根据上述方法再生催化剂的反应器立管。

3. 发明授权

US4563439A Preparation of mixed vanadium phosphorus oxide catalysts 失效
标题翻译：混合钒氧化磷催化剂的制备
公开(公告)号：US4563439A
公开(公告)日：1986-01-07
申请号：US640641
申请日：1984-08-14
申请人： Noel J. Bremer , Dennis E. Dria
发明人： Noel J. Bremer , Dennis E. Dria
IPC分类号： B01J27/198 , C07C51/215 , B01J27/188 , B01J27/19 , B01J27/192
CPC分类号： C07C51/215 , B01J23/002 , B01J27/198 , B01J2523/00
摘要： Vanadium phosphorus mixed oxide containing catalysts are prepared by sequentially forming an alpha-VOPO.sub.4 catalyst precursor in aqueous media, and thereafter partially reducing a portion of the vanadium to a valence state of +4 in an organic liquid reducing media, in the absence of corrosive reducing agents. The catalysts exhibit excellent activity for the production of maleic anhydride from 4 carbon atom hydrocarbons such as n-butane.
摘要翻译：通过在水性介质中依次形成α-VOPO 4催化剂前体，然后在不存在腐蚀性还原的情况下，在有机液体还原介质中部分还原一部分钒至+4的价态来制备含钒磷混合氧化物的催化剂代理商该催化剂对于从4个碳原子烃如正丁烷生产马来酸酐具有优异的活性。

4. 发明授权

US4507212A Nitrile compounds as oil field biocides 失效
标题翻译：腈化合物作为油田杀菌剂
公开(公告)号：US4507212A
公开(公告)日：1985-03-26
申请号：US441874
申请日：1982-11-15
申请人： Dennis E. Dria , Noel J. Bremer , Myra A. Dria , Rodger W. McKain
发明人： Dennis E. Dria , Noel J. Bremer , Myra A. Dria , Rodger W. McKain
IPC分类号： C09K8/60 , E21B43/22
CPC分类号： C09K8/605 , Y10S507/92 , Y10S507/936
摘要： Unsaturated nitrile compounds, e.g., acrylonitrile, are used as microbiocides to inhibit undesired bacterial growth in injection water used in enhanced oil recovery methods. The biocides are efficacious for the control of sulfate reducing bacteria, including Desulfovibrio desulfuricans.
摘要翻译：使用不饱和腈化合物，例如丙烯腈作为杀微生物剂，以抑制用于增强采油方法的注射用水中的不需要的细菌生长。杀生物剂对于控制硫酸盐还原细菌（包括脱硫抗乙酰病毒脱硫剂）是有效的。

5. 发明授权

US4396536A Preparation of vanadium phosphorous catalysts using olefinic oxygenated media 失效
标题翻译：使用烯烃氧合介质制备钒磷催化剂
公开(公告)号：US4396536A
公开(公告)日：1983-08-02
申请号：US301555
申请日：1981-09-14
申请人： Noel J. Bremer , Dennis E. Dria
发明人： Noel J. Bremer , Dennis E. Dria
IPC分类号： B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , B01J27/14
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into an olefinic oxygenated organic liquid medium, a phosphorus-containing compound is added to the medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the phosphorus-containing compound, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.
摘要翻译：本发明提供了一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的，或气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。将钒化合物引入烯烃充氧有机液体介质中，向介质中加入含磷化合物，将至少一部分钒还原至+4价态可在添加或含磷化合物和得到的钒 - 磷氧化物催化剂前体被回收，干燥并煅烧。

6. 发明授权

US4350639A Preparation of maleic anhydride 失效
标题翻译：马来酸酐的制备
公开(公告)号：US4350639A
公开(公告)日：1982-09-21
申请号：US258712
申请日：1981-04-29
申请人： Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
发明人： Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
IPC分类号： B01J23/22 , B01J27/198 , C07C51/215 , C07D307/60
CPC分类号： C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J2523/00
摘要： The present invention provides improved oxidation catalysts containing mixed oxides of vanadium and phosphorus and the method for the preparation thereof, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce excellent yields of maleic anhydride with very good selectivity. At least one vanadium compound, a substantial portion of which is in the pentavalent state, and at least one phosphorus-containing compound is added to an organic liquid medium capable of reducing at least a portion of the vanadium to a +4 valence state, to form a reaction mixture. Partial reduction of the vanadium is effected in the presence of the phosphorus-containing compound and a highly ordered and uniform mixed vanadium phosphorus oxide-containing catalyst precursor is formed.
摘要翻译：本发明提供了含有钒和磷的混合氧化物的改进的氧化催化剂及其制备方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子的混合物中的氧化中特别有效氧气或含氧气体，以非常好的选择性产生优异的马来酸酐产率。将至少一种钒化合物（其大部分为五价态）和至少一种含磷化合物加入到能够将至少一部分钒还原成+4价态的有机液体介质中，至形成反应混合物。在含磷化合物的存在下进行钒的部分还原，形成高度均匀的混合的含氧化钒的催化剂前体。

7. 发明授权

US5562834A Waste concentration and destruction process 失效
标题翻译：废物集中和破坏过程
公开(公告)号：US5562834A
公开(公告)日：1996-10-08
申请号：US388564
申请日：1995-02-14
申请人： Noel J. Bremer , Gary V. Goeden , David R. Woodbury
发明人： Noel J. Bremer , Gary V. Goeden , David R. Woodbury
IPC分类号： A62D3/00 , A62D3/34 , A62D3/37 , A62D3/38 , A62D101/20 , A62D101/22 , A62D101/26 , A62D101/28 , B01D3/38 , B01D53/86 , B09B3/00 , B09C1/06 , C01B3/32 , C01B3/38 , C02F1/20 , C02F1/70
CPC分类号： A62D3/37 , B01D3/38 , B01D53/8668 , B09B3/00 , B09C1/06 , C01B3/323 , C01B3/38 , C02F1/20 , A62D2101/20 , A62D2101/22 , A62D2101/26 , A62D2101/28 , Y02P70/34 , Y02W30/20
摘要： A process for the destruction of organic contaminants from wastewater streams and solid surfaces, including soil. The process comprises removing volatile organic compounds from the wastewater stream or surface by steam stripping and then contacting a stream comprising steam and the stripped organic compounds with a catalyst at an elevated temperature so as to convert the hydrocarbon portion of the organic compounds to a mixture of hydrogen and carbon dioxide.
摘要翻译：从废水流和固体表面（包括土壤）中破坏有机污染物的过程。该方法包括通过蒸汽汽提从废水流或表面除去挥发性有机化合物，然后在升高的温度下将包含蒸汽和汽提的有机化合物的物流与催化剂接触，以将有机化合物的烃部分转化为氢气和二氧化碳。

8. 发明授权

US4465846A Preparation of maleic anhydride 失效
标题翻译：马来酸酐的制备
公开(公告)号：US4465846A
公开(公告)日：1984-08-14
申请号：US488902
申请日：1983-04-27
申请人： Noel J. Bremer , Dennis E. Dria
发明人： Noel J. Bremer , Dennis E. Dria
IPC分类号： C07C51/215 , C07D307/60
CPC分类号： C07C51/215
摘要： Vanadium phosphorus mixed oxide containing catalysts are prepared by sequentially forming an alpha-VOPO.sub.4 catalyst precursor in aqueous media, and thereafter partially reducing a portion of the vanadium to a valence state of +4 in an organic liquid reducing media, in the absence of corrosive reducing agents. The catalysts exhibit excellent activity for the production of maleic anhydride from 4 carbon atom hydrocarbons such as n-butane.
摘要翻译：通过在水性介质中依次形成α-VOPO 4催化剂前体，然后在不存在腐蚀性还原的情况下，在有机液体还原介质中部分还原一部分钒至+4的价态来制备含钒磷混合氧化物的催化剂代理商该催化剂对于从4个碳原子烃如正丁烷生产马来酸酐具有优异的活性。

9. 发明授权

US4448893A Preparation of improved mixed vanadium phosphorus oxide catalyst and their use in oxidation processes 失效
标题翻译：改进的混合钒氧化钒催化剂的制备及其在氧化过程中的应用
公开(公告)号：US4448893A
公开(公告)日：1984-05-15
申请号：US411780
申请日：1982-08-26
申请人： Noel J. Bremer , Dennis E. Dria , Andrew M. Weber
发明人： Noel J. Bremer , Dennis E. Dria , Andrew M. Weber
IPC分类号： B01J27/198 , C07C51/215 , C07C51/25 , B01J27/14
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： Vanadium phosphorus mixed oxide containing catalysts are prepared in an organic liquid reaction medium with heating wherein at least 1.5 moles organic liquid are removed from the reaction medium such as by distillation for each mole of vanadium which is reduced or reacted during such reaction and/or reduction. The resulting catalysts are useful for the production of maleic anhydride from 4 carbon atom hydrocarbons.
摘要翻译：在加热的有机液体反应介质中制备含钒磷混合氧化物的催化剂，其中从反应介质中除去至少1.5摩尔有机液体，例如通过蒸馏每一摩尔在此反应和/或还原期间还原或反应的钒。得到的催化剂可用于从4个碳原子烃生产马来酸酐。

10. 发明授权

US4234461A Oxidation catalysts 失效
标题翻译：氧化催化剂
公开(公告)号：US4234461A
公开(公告)日：1980-11-18
申请号：US891786
申请日：1978-03-30
申请人： Dev D. Suresh , Noel J. Bremer , Robert K. Grasselli
发明人： Dev D. Suresh , Noel J. Bremer , Robert K. Grasselli
IPC分类号： B01J23/22 , B01J23/26 , B01J23/34 , B01J23/84 , C07C51/215 , C07C51/25 , C07C51/265 , B01J23/10 , B01J21/00 , B01J21/02 , B01J23/16
CPC分类号： C07C51/252 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/84 , C07C51/215 , C07C51/25 , C07C51/265
摘要： Catalysts comprising the combined oxides of vanadium and at least one element selected from the group consisting of boron, niobium, tantalum, antimony, tungsten and chromium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene, or a mixture thereof with molecular oxygen in the vapor phase to yield maleic anhydride. The catalysts of the present invention may be further promoted with additional elements to enhance activity, stability and selectivity. The reaction with n-butane gives an especially pure product in good yield and selectivity.
摘要翻译：已经发现包含钒的组合氧化物和选自硼，铌，钽，锑，钨和铬中的至少一种元素的催化剂在正丁烷，正丁烯和丁二烯的氧化中是特别有效的，或其与气相中的分子氧的混合物，得到马来酸酐。本发明的催化剂可以通过附加元素进一步促进，以增强活性，稳定性和选择性。与正丁烷的反应以良好的产率和选择性得到特别纯的产物。

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