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1. 发明申请

US20060004129A1 Coating composition, antireflection film, photoresist and pattern formation method using it 失效
标题翻译：涂料组合物，抗反射膜，光致抗蚀剂和使用它的图案形成方法
公开(公告)号：US20060004129A1
公开(公告)日：2006-01-05
申请号：US11190855
申请日：2005-07-28
申请人： Nobuyuki Otozawa , Toyomichi Shimada , Takashige Maekawa , Naoko Sumi
发明人： Nobuyuki Otozawa , Toyomichi Shimada , Takashige Maekawa , Naoko Sumi
IPC分类号： C08F16/24
CPC分类号： C09D127/18 , C08G65/007 , C08K5/09 , C08K5/42 , C09D7/42 , G03F7/0046 , G03F7/091 , Y10T428/31786
摘要： To provide a coating composition useful to form an antireflection film having a refractive index lower than 1.4, excellent in water solubility and long-term stability in the form of a water solution. A coating composition containing a fluoropolymer having ionic functional groups (such as a fluoropolymer having polymer units of —CF2CF[O(CF2)3COOH]—), an acid and an aqueous medium.
摘要翻译：为了提供可用于形成折射率低于1.4的抗反射膜的涂料组合物，水溶性和水溶液形式的长期稳定性优异。含有具有离子性官能团的含氟聚合物的涂料组合物（例如具有-CF 2 O 2 CF 3 O 2 CF 3 O 3的聚合物单元的含氟聚合物 > COOH] - ），酸和水性介质。

2. 发明授权

US07262243B2 Coating composition, antireflection film, photoresist and pattern formation method using it 失效
标题翻译：涂料组合物，抗反射膜，光致抗蚀剂和使用它的图案形成方法
公开(公告)号：US07262243B2
公开(公告)日：2007-08-28
申请号：US11190855
申请日：2005-07-28
申请人： Nobuyuki Otozawa , Toyomichi Shimada , Takashige Maekawa , Naoko Sumi
发明人： Nobuyuki Otozawa , Toyomichi Shimada , Takashige Maekawa , Naoko Sumi
IPC分类号： G03F7/11 , G03F7/004 , H01L21/027 , B05D5/06 , B32B27/08 , B32B27/36
CPC分类号： C09D127/18 , C08G65/007 , C08K5/09 , C08K5/42 , C09D7/42 , G03F7/0046 , G03F7/091 , Y10T428/31786
摘要： To provide a coating composition useful to form an antireflection film having a refractive index lower than 1.4, excellent in water solubility and long-term stability in the form of a water solution. A coating composition containing a fluoropolymer having ionic functional groups (such as a fluoropolymer having polymer units of —CF2CF[O(CF2)3COOH]—), an acid and an aqueous medium.
摘要翻译：为了提供可用于形成折射率低于1.4的抗反射膜的涂料组合物，水溶性和水溶液形式的长期稳定性优异。含有具有离子性官能团的含氟聚合物的涂料组合物（例如具有-CF 2 O 2 CF 3 O 2 CF 3 O 3的聚合物单元的含氟聚合物 > COOH] - ），酸和水性介质。

3. 发明授权

US08017709B2 Fluorinated polymer and fluorinated polymer composition containing it 有权
标题翻译：含氟聚合物和含氟聚合物组合物
公开(公告)号：US08017709B2
公开(公告)日：2011-09-13
申请号：US12168197
申请日：2008-07-07
申请人： Nobuyuki Otozawa , Toyomichi Shimada
发明人： Nobuyuki Otozawa , Toyomichi Shimada
IPC分类号： C08F14/18 , C08F114/18 , C08F214/18
CPC分类号： C08F214/18 , C08F14/18 , C08J3/093 , C08J2329/10 , C08K5/02 , C08K5/06 , C08F2/18 , C08L27/12
摘要： To provide an amorphous fluorinated polymer which is soluble in a fluorinated solvent having a boiling point of at most 70° C., and a fluorinated polymer composition containing it. An amorphous fluorinated polymer characterized by having a fluorine content of at least 50 mass % and an intrinsic viscosity of at least 0.03 g/dL and less than 0.05 dL/g as measured in perfluoro(2-butyltetrahydrofuran) at 30° C.
摘要翻译：提供可溶于沸点至多为70℃的氟化溶剂的无定形氟化聚合物和含有它的含氟聚合物组合物。一种无定形氟化聚合物，其特征在于在30℃下，在全氟（2-丁基四氢呋喃）中测得氟含量为至少50质量％，特性粘度至少为0.03g / dL且小于0.05dL / g。

4. 发明授权

US08901264B2 Copolymer and method for producing the same 有权
标题翻译：共聚物及其制造方法
公开(公告)号：US08901264B2
公开(公告)日：2014-12-02
申请号：US12878045
申请日：2010-09-09
申请人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori , Minako Shimada
发明人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori , Minako Shimada
IPC分类号： C08F214/26 , C08F214/08 , C08F220/24 , C08F214/00 , C08F214/06 , C08F220/18 , C08F220/26
CPC分类号： C08F214/00 , C08F214/06 , C08F214/08 , C08F220/18 , C08F220/24 , C08F220/26 , Y10T428/3154
摘要： To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability. A copolymer which is characterized in that it has structural units based on the following monomer (a) and structural units based on the following monomer (b), wherein the content of structural units based on the monomer (a) is from 5 to 95 mass % in the total structural units (100 mass %), the content of structural units based on the monomer (b) is from 5 to 60 mass % in the total structural units (100 mass %) and the sum of the contents of structural units based on the monomer (a) and structural units based on the monomer (b) is at least 65 mass % in the total structural units (100 mass %), and a water repellent composition which comprises the copolymer: Monomer (a): a (meth)acrylate having no Rf group and having a C20-30 alkyl group; Monomer (b): a halogenated olefin.
摘要翻译：为了提供赋予足够的动态防水性的共聚物，对制品表面的空气干燥防水性和摩擦耐久性，对环境的影响较小的共聚物，其制造方法，防水组合物和具有优异的动态防水性，空气干燥防水性和摩擦耐久性。一种共聚物，其特征在于其具有基于以下单体（a）的结构单元和基于以下单体（b）的结构单元，其中基于单体（a）的结构单元的含量为5至95质量份（100质量％），基于单体（b）的结构单元的含量在总结构单位（100质量％）中为5〜60质量％，结构单元的含量之和基于单体（a）和基于单体（b）的结构单元在总结构单元（100质量％）中为至少65质量％，以及包含共聚物的防水组合物：单体（a）：a （甲基）丙烯酸酯，不具有Rf基且具有C20-30烷基; 单体（b）：卤代烯烃。

5. 发明申请

US20060024613A1 Composition for photoresist protective film, photoresist protective film and photoresist pattern formation process 审中-公开
标题翻译：用于光致抗蚀剂保护膜，光致抗蚀剂保护膜和光致抗蚀剂图案形成工艺的组合物
公开(公告)号：US20060024613A1
公开(公告)日：2006-02-02
申请号：US11192049
申请日：2005-07-29
申请人： Nobuyuki Otozawa , Toyomichi Shimada
发明人： Nobuyuki Otozawa , Toyomichi Shimada
IPC分类号： G03C1/76
CPC分类号： C09D133/16 , C09D127/12 , G03F7/0046 , G03F7/11 , G03F7/2041
摘要： A composition for a photoresist protective film comprising a fluoropolymer having at least one functional group selected from the group consisting of —COOH, —SO3H, —OP(═O)(OH)2, —NR2 and —N+R3Cl− (wherein R represents a C1-4 alkyl group) and having a weight average molecular weight Mw of from 1,000 to 100,000 and a solvent.
摘要翻译：一种用于光致抗蚀剂保护膜的组合物，其包含具有至少一个选自-COOH，-SO 3 H，-OP（-O）（OH）2）的官能团的含氟聚合物 -NR 2和-N + 3 R 3 - （其中R代表C 1〜1-4个烷基），重均分子量Mw为1,000〜100,000的溶剂和溶剂。

6. 发明申请

US20110071248A1 COPOLYMER, METHOD FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION 审中-公开
标题翻译：共聚物，其生产方法和水/油组合物
公开(公告)号：US20110071248A1
公开(公告)日：2011-03-24
申请号：US12958906
申请日：2010-12-02
申请人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori , Minako Shimada
发明人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori , Minako Shimada
IPC分类号： C08F214/18 , C08L27/12 , C08F220/24
CPC分类号： C08F214/18 , C08F214/202 , C08F214/222 , C08F216/1408 , C08F220/26 , C08F220/36 , C08F220/58 , C08F222/10 , C08F2220/1891 , C08F214/08
摘要： To provide a copolymer which is capable of providing an article surface with a dynamic water repellency and which has extremely excellent washing durability of water repellency and oil repellency, while placing little burden on the environment; a method for its production; and a water/oil repellent composition.A copolymer comprising structural units of the monomer (a) and structural units of the monomer (b), wherein the total of the content of structural units based on the monomer (a) and the content of structural units based on the monomer (b) is at least 85 mass % of all structural units (100 mass %), and the molar ratio ((a)/(b)) of the content of structural units based on the monomer (a) to the content of structural units based on the monomer (b) is from 0.12 to 3; and a water/oil repellent composition containing such a copolymer. Monomer (a): a compound represented by (Z—Y)n—X, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and when n is 1, and X is a polymerizable unsaturated group. Monomer (b): a halogenated olefin.
摘要翻译：为了提供一种共聚物，其能够提供具有动态拒水性的物品表面，并且在环境上施加很小的负担的情况下具有非常优异的防水性和拒油性的洗涤耐久性。一种生产方法; 和斥水斥油剂组合物。包含单体（a）的结构单元和单体（b）的结构单元的共聚物，其中基于单体（a）的结构单元的含量和基于单体（b）的结构单元的含量的总和基于单体（a）的结构单元的含量与基于单体（a）的结构单元的含量相比，所有结构单元（100质量％）的至少85质量％和结构单元的含量（（a）/（b）单体（b）为0.12〜3; 和含有这种共聚物的斥水斥油剂组合物。单体（a）：由（Z-Y）n -X表示的化合物，其中Z为C1-6多氟烷基等，Y为二价有机基团或单键，n为1或2，当 n为1，X为可聚合不饱和基团。单体（b）：卤代烯烃。

7. 发明申请

US20100331479A1 COPOLYMER AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：共聚物及其制造方法
公开(公告)号：US20100331479A1
公开(公告)日：2010-12-30
申请号：US12878045
申请日：2010-09-09
申请人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori
发明人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori
IPC分类号： C08F16/24 , C08F214/18 , C08F220/22 , C08L33/12 , C08F214/06 , C08F214/08
CPC分类号： C08F214/00 , C08F214/06 , C08F214/08 , C08F220/18 , C08F220/24 , C08F220/26 , Y10T428/3154
摘要： To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability.A copolymer which is characterized in that it has structural units based on the following monomer (a) and structural units based on the following monomer (b), wherein the content of structural units based on the monomer (a) is from 5 to 95 mass % in the total structural units (100 mass %), the content of structural units based on the monomer (b) is from 5 to 60 mass % in the total structural units (100 mass %) and the sum of the contents of structural units based on the monomer (a) and structural units based on the monomer (b) is at least 65 mass % in the total structural units (100 mass %), and a water repellent composition which comprises the copolymer: Monomer (a): a (meth)acrylate having no Rf group and having a C20-30 alkyl group; Monomer (b): a halogenated olefin.
摘要翻译：为了提供赋予足够的动态防水性的共聚物，对制品表面的空气干燥防水性和摩擦耐久性，对环境的影响较小的共聚物，其制造方法，防水组合物和具有优异的动态防水性，空气干燥防水性和摩擦耐久性。一种共聚物，其特征在于其具有基于以下单体（a）的结构单元和基于以下单体（b）的结构单元，其中基于单体（a）的结构单元的含量为5至95质量份（100质量％），基于单体（b）的结构单元的含量在总结构单位（100质量％）中为5〜60质量％，结构单元的含量之和基于单体（a）和基于单体（b）的结构单元在总结构单元（100质量％）中为至少65质量％，以及包含共聚物的防水组合物：单体（a）：a （甲基）丙烯酸酯，不具有Rf基且具有C20-30烷基; 单体（b）：卤代烯烃。

8. 发明授权

US08338529B2 Oil repellent copolymer, method for its production and oil repellent treatment solution 失效
标题翻译：防油共聚物，其制备方法和拒油处理溶液
公开(公告)号：US08338529B2
公开(公告)日：2012-12-25
申请号：US12499321
申请日：2009-07-08
申请人： Taiki Hoshino , Naoko Shirota , Nobuyuki Otozawa , Akihiko Asakawa
发明人： Taiki Hoshino , Naoko Shirota , Nobuyuki Otozawa , Akihiko Asakawa
IPC分类号： C08L75/00
CPC分类号： C09D133/066 , C08G18/807 , C08G18/8116 , C09D133/14
摘要： To provide an oil repellent copolymer capable of forming an oil repellent film which is excellent in durability. An oil repellent copolymer characterized by comprising a repeating unit (A) having a polyfluoroalkyl group, a repeating unit (B) having a fluorescent functional group, and a repeating unit (C) having an ester bond other than an ester bond derived from acrylic acid, and/or a hydroxyl group.
摘要翻译：提供能够形成耐久性优异的防油膜的防油性共聚物。一种斥油剂共聚物，其特征在于包含具有多氟烷基的重复单元（A），具有荧光官能团的重复单元（B）和具有除丙烯酸酯键之外的酯键的重复单元（C），和/或羟基。

9. 发明授权

US07964659B2 Antireflection coating composition 有权
标题翻译：防反射涂料组合物
公开(公告)号：US07964659B2
公开(公告)日：2011-06-21
申请号：US12544723
申请日：2009-08-20
申请人： Nobuyuki Otozawa
发明人： Nobuyuki Otozawa
IPC分类号： C08K5/095
CPC分类号： G03F7/091 , G03F7/0048
摘要： To provide an antireflection coating composition having a low surface tension and excellent coating properties and capable of forming an antireflection film with a low refractive index, without use of PFOS nor PFOA having 7 or more carbon atoms.An antireflection coating composition which contains a fluorinated surfactant (A) containing a compound (A1) represented by the following formula (I), a water-soluble polymer (B) and an aqueous medium (C): R1—O—(R2—O)n—R3—X1 (I) wherein R1 is a linear or branched perfluoroalkyl group of which the terminal fluorine atom may be substituted by a hydrogen atom or a chlorine atom, each of R2 and R3 which are independent of each other, is a linear or branched perfluoroalkylene group, provided that the total number of carbon atoms in R1, R2 and R3 is at most 5, n is 0 or an integer of at least 1, X1 is —COOH or —C(CF2Z1)(CF2Z2)OH, which may form a salt, and each of Z1 and Z2 is a hydrogen atom, a fluorine atom, a chlorine atom or a trifluoromethyl group.
摘要翻译：为了提供具有低表面张力和优异的涂布性能并且能够形成具有低折射率的抗反射膜的抗反射涂料组合物，而不使用具有7个或更多个碳原子的PFOS或PFOA。含有下式（I）表示的化合物（A1），水溶性聚合物（B）和水性介质（C）的含氟表面活性剂（A））的反射防止涂料组合物：R1-O-（R2- O）n -R 3 -X 1（I）其中R 1是末端氟原子可以被氢原子或氯原子取代的直链或支链全氟烷基，R2和R3彼此独立地是直链或支链全氟亚烷基，条件是R1，R2和R3中的碳原子总数最多为5，n为0或至少为1的整数，X 1为-COOH或-C（CF 2 Z 1）（CF 2 Z 2） OH，其可以形成盐，Z1和Z2各自为氢原子，氟原子，氯原子或三氟甲基。

10. 发明授权

US08193277B2 Water/oil repellent composition, method for its production and method for treating article 有权
标题翻译：斥水斥油剂组合物，其制造方法和制品的处理方法
公开(公告)号：US08193277B2
公开(公告)日：2012-06-05
申请号：US13278292
申请日：2011-10-21
申请人： Nobuyuki Otozawa , Kazunori Sugiyama , Minako Shimada , Yuuichi Oomori
发明人： Nobuyuki Otozawa , Kazunori Sugiyama , Minako Shimada , Yuuichi Oomori
IPC分类号： C08L27/12
CPC分类号： D06M15/277 , C08F220/20 , C08F220/22 , C08F220/24 , C08K5/34922 , C09K3/18 , D06M15/227 , D06M15/248 , C08K5/17 , C08L33/16 , C08F214/08 , C08F214/06
摘要： To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency and post-air-drying water repellency to the surface of an article and which presents a low environmental impact, a method for its production and a method for treating an article.A water/oil repellent composition which comprises a copolymer having structural units based on the following monomer (a) and structural units based on the following monomer (b) and having a mass average molecular weight of at least 40,000, and a medium, is used. Monomer (a): a compound represented by (Z—Y)nX, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or the like, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): an olefin, a homopolymer of which has a glass transition temperature of from −50° C. to 50° C.
摘要翻译：本发明提供一种斥水斥油剂组合物，其能够赋予制品表面足够的动态拒水性和空气后干燥性，并且对环境的影响较小，其制备方法及其制备方法文章。包含具有基于以下单体（a）的结构单元和基于以下单体（b）的结构单元并且具有至少40,000的质均分子量和介质的共聚物的斥水斥油剂组合物被使用。单体（a）：由（Z-Y）nX表示的化合物，其中Z为C1-6多氟烷基等，Y为二价有机基团等，n为1或2，X为可聚合的不饱和基团。单体（b）：烯烃，其均聚物的玻璃化转变温度为-50℃至50℃。

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