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1. 发明授权

US4218263A Process for preparing oxygen-containing waxes 失效
标题翻译：含氧蜡制备方法
公开(公告)号：US4218263A
公开(公告)日：1980-08-19
申请号：US961783
申请日：1978-11-17
申请人： Nobuaki Kawabata , Nobuo Yokoyama
发明人： Nobuaki Kawabata , Nobuo Yokoyama
IPC分类号： C10G73/38 , C07D307/60 , C08F8/46 , C08F255/00 , C08F289/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/02 , C08L91/00 , C08L91/06 , C08L91/08 , C08L101/00 , C10G73/42 , C10M109/02
CPC分类号： C10M109/02 , C08F255/00 , C08L23/02 , C08L91/08 , C10M7/00
摘要： A process for preparing an oxygen-containing wax obtained by reacting a mixture of saturated and unsaturated hydrocarbon waxes with an unsaturated polycarboxylic acid thereby to prepare the oxygen-containing wax. In one embodiment, this invention relates to the oxygen-containing waxes so prepared.
摘要翻译：通过将饱和和不饱和烃蜡的混合物与不饱和多元羧酸反应制得含氧蜡的方法，由此制备含氧蜡。在一个实施方案中，本发明涉及如此制备的含氧蜡。

2. 发明授权

US4442140A Aqueous composition for the protection of paint surfaces 失效
标题翻译：用于保护油漆表面的水性组合物
公开(公告)号：US4442140A
公开(公告)日：1984-04-10
申请号：US371829
申请日：1982-04-26
申请人： Nobuaki Kawabata , Nobuo Yokoyama , Yoshihiko Araki
发明人： Nobuaki Kawabata , Nobuo Yokoyama , Yoshihiko Araki
IPC分类号： C09D5/20 , C08L91/00 , C08L91/06 , C09D191/06 , C09G1/08 , B65B33/00
CPC分类号： C09G1/08
摘要： An aqueous composition for the protection of paint surfaces comprises an aqueous emulsion containing as essential components (a) an oxygen-containing wax, (b) an emulsifying agent, (c) a fine powder of an inorganic material having a silicon content of not less than 23%, and (d) a fine powder of an inorganic or organic material substantially free of silicon.
摘要翻译：用于保护油漆表面的水性组合物包含含有以下成分的水乳液：（a）含氧蜡，（b）乳化剂，（c）硅含量不少于无机材料的细粉末超过23％，和（d）基本上不含硅的无机或有机材料的细粉末。

3. 发明授权

US4339276A Wax emulsion 失效
标题翻译：蜡乳液
公开(公告)号：US4339276A
公开(公告)日：1982-07-13
申请号：US212916
申请日：1980-12-03
申请人： Nobuo Yokoyama , Nobuaki Kawabata
发明人： Nobuo Yokoyama , Nobuaki Kawabata
IPC分类号： C08L91/00 , C08K5/09 , C08L7/00 , C08L21/00 , C08L23/00 , C08L91/08 , C08L101/00 , C08L91/06
CPC分类号： C08L91/08 , Y10T428/31804
摘要： A wax emulsion is provided which comprises as essential ingredients (A) 100 parts by weight of a petroleum fraction wax having a melting point ranging within 40.degree. to 90.degree. C.; and (B) 3 to 20 parts by weight of an oxygen containing wax; said oxygen-containing wax being prepared by mixing 10 to 80 parts by weight of a petroleum fraction wax (I) having a melting point ranging within 50.degree. to 85.degree. C. with 90 to 20 parts by weight of a polyolefin wax (II) having a melting point ranging within 36.degree. to 120.degree. C., a number average molecular weight of from 310 to 1,000 and 5 to 50 double bonds per 1,000 carbon atoms to obtain a mixture, and then reacting 100 parts by weight of said mixture with 3 to 25 parts by weight of an unsaturated polycarboxylic acid or an anhydride thereof under a condition for forming free radicals.
摘要翻译：提供了一种蜡乳液，其包含作为必要成分（A）100重量份的熔点在40℃至90℃范围内的石油馏分蜡; 和（B）3〜20重量份的含氧蜡; 所述含氧蜡通过将10至80重量份的熔点在50至85℃范围内的石油馏分蜡（I）与90至20重量份的聚烯烃蜡（II）混合来制备，熔点在36〜120℃，数均分子量为310〜1000，每1000个碳原子为5〜50个双键，得到混合物，然后将100重量份所述混合物与 3〜25重量份的不饱和多元羧酸或其酸酐，形成自由基。

4. 发明授权

US4594109A Aqueous composition for the protection of paint surfaces 失效
标题翻译：用于保护油漆表面的水性组合物
公开(公告)号：US4594109A
公开(公告)日：1986-06-10
申请号：US766345
申请日：1985-08-16
申请人： Nobuaki Kawabata
发明人： Nobuaki Kawabata
IPC分类号： C09D5/20 , C09D5/00 , C09D183/00 , C09D183/04 , C09D191/06 , C08J3/02
CPC分类号： C09D5/008
摘要： An aqueous composition for the protection of paint surfaces comprises [A] a solid emulsion component composed of (a) an oxygen-containing wax, (b) a polybutene and (c) a silicone oil; [B] a powdery emulsion component composed of (d) substantially white-colored fine powder of a silicon-containing inorganic material and (e) white-colored fine powder of a silicon-free inorganic or organic material; and [C] an emulsifier component.
摘要翻译：用于保护油漆表面的水性组合物包含[A]由（a）含氧蜡，（b）聚丁烯和（c）硅油组成的固体乳液组分; [B]由（d）含硅无机材料的基本上白色的细粉末和（e）无硅无机或有机材料的白色细粉末组成的粉末状乳液组分; 和[C]乳化剂组分。

5. 发明授权

US5049186A Water-based protective compositions for coating films 失效
标题翻译：用于涂膜的水性保护组合物
公开(公告)号：US5049186A
公开(公告)日：1991-09-17
申请号：US494303
申请日：1990-03-16
申请人： Nobuaki Kawabata
发明人： Nobuaki Kawabata
IPC分类号： C08L23/08 , C08L89/00 , C09D5/00 , C09D5/20 , C09D123/02 , C09D123/08 , C09D191/06 , C09D191/08
CPC分类号： C09D5/008 , Y10S106/901
摘要： Water-based compositions of the water-based wax emulsion type for protecting coating films are provided by emulsifying and dispersing, as essential components, [A] a disperse phase component and [B] an emulsifier component in water. The disperse phase component [A] is formed of (a) a petroleum fraction wax having a melting point of 50.degree.-90.degree. C., (b) an oxygen-containing wax having an oxygen content of at least 3.0 wt. % and a melting point of 50.degree.-85.degree. C., (c) an ethylene/.alpha.-olefin copolymer having a number average molecular weight of 2,000-20,000, and (d) a higher fatty acid metal salt and/or a metal-modified hard wax. The compositions can form, without the need for a solvent, strong barrier coats which are resistant to rain, moisture, sunlight and air pollutants even under severe environmental conditions. After these barrier coats are used, they can be easily removed with warm water containing a small amount of a solvent or steam.
摘要翻译：通过以分散相成分和[B]乳化剂成分在水中乳化分散为基本成分，提供水性蜡乳液型水性成分。分散相成分[A]由（a）熔点为50〜90℃的石油馏分蜡形成，（b）氧含量为3.0重量％以上的含氧蜡。％，熔点为50〜-85℃，（c）数均分子量为2,000〜20,000的乙烯/α-烯烃共聚物，（d）高级脂肪酸金属盐和/或金属改性硬蜡。即使在恶劣的环境条件下，组合物可以形成即使在苛刻的环境条件下也能耐雨水，水分，阳光和空气污染物的强力阻隔层，而不需要溶剂。在使用这些阻挡涂层之后，可以用含有少量溶剂或蒸汽的温水容易地除去它们。

6. 发明授权

US5194483A Water-based protective compositions for coating films and preparation processes thereof 失效
标题翻译：涂膜用水性保护组合物及其制备方法
公开(公告)号：US5194483A
公开(公告)日：1993-03-16
申请号：US794972
申请日：1991-11-20
申请人： Nobuaki Kawabata
发明人： Nobuaki Kawabata
IPC分类号： C08J7/04 , C08L5/00 , C08L33/02 , C08L93/00 , C09D133/06
CPC分类号： C08J7/047 , C09D133/064 , C08J2433/00 , C08L33/02 , C08L5/00 , C08L93/00
摘要： Disclosed herein are water-based protective composition for coating films. The compositions contain (a) a water-based dispersion of copolymer particles having a number average molecular weight of from 2,000 to 20,000 and a glass transition point of from -10.degree. C. to +40.degree. C. and obtained by emulsion-polymerizing 100 parts by weight of a monomer mixture consisting substantially of (X) 7-12 parts by weight of an .alpha.,.beta.-monoethylenically-unsaturated carboxylic acid and (Y) 88-93 parts by weight of at least one ester selected from the group consisting of C.sub.1-4 -alkyl acrylates and C.sub.1-4 -alkyl methacrylates; as well as specific amounts of (b) an ultraviolet absorber, (c) an antioxidant, (d) a thickening agent and (e) a surface active agent. They can form barrier coats having excellent removability, weatherability, water-proofness, heat resistance and coating-film-protecting property. Their preparation processes are also disclosed.
摘要翻译：本文公开了用于涂膜的水基保护组合物。组合物含有（a）数均分子量为2,000〜20,000，玻璃化转变温度为-10℃〜+ 40℃的共聚物颗粒的水性分散体，通过乳液聚合100 基于（X）7-12重量份的α，β-单烯属不饱和羧酸和（Y）88-93重量份的至少一种选自以下的酯的单体混合物的重量份：丙烯酸C 1-4烷基酯和甲基丙烯酸C 1-4烷基酯; （b）紫外线吸收剂，（c）抗氧化剂，（d）增稠剂和（e）表面活性剂的具体量。它们可以形成具有优异的可除去性，耐候性，防水性，耐热性和涂膜保护性的阻挡涂层。还公开了它们的制备方法。

7. 发明授权

US6159254A Wax composition for forming candles 失效
标题翻译：用于形成蜡烛的蜡组成
公开(公告)号：US6159254A
公开(公告)日：2000-12-12
申请号：US222756
申请日：1998-12-30
申请人： Eiji Akiyama , Masao Isobe , Nobuaki Kawabata
发明人： Eiji Akiyama , Masao Isobe , Nobuaki Kawabata
IPC分类号： C08K5/01 , C08L91/06 , C08L91/08 , C11C5/00 , C10L5/00
CPC分类号： C11C5/002 , C08K5/01 , C08L91/06 , C08L91/08
摘要： An object is to provide a wax composition for candles which is excellent in moldability in the production of the candles, enables the candles produced therefrom to be reduced in the bending and blocking, and which can be improved in releasability. A wax composition for forming candles, which comprises 100 parts by weight of petroleum paraffin wax and 0.1 to 0.3 parts by weight of a mineral oil, with said petroleum paraffin wax containing 97% by weight and above of a fraction which has 24 and above carbon atoms, having normal paraffin wax/non-normal paraffin wax ratios of at least 9 and having a melting point of 45 to 65.degree. C.
摘要翻译：本发明的目的是提供一种蜡烛用蜡组合物，其蜡烛的制造成型性优异，能够使由其制造的蜡烛的弯曲和阻断性降低，并且可以提高脱模性。用于形成蜡烛的蜡组合物，其包含100重量份的石油石蜡和0.1至0.3重量份的矿物油，所述石油石蜡包含97重量％以上的具有24及以上碳的馏分原子，具有正常石蜡/非正常石蜡比率为至少9且熔点为45至65℃。

8. 发明授权

US5098948A Water-based protective compositions for coating films and preparation processes thereof 失效
标题翻译：用于涂膜的水基保护组合物及其制备方法
公开(公告)号：US5098948A
公开(公告)日：1992-03-24
申请号：US533398
申请日：1990-06-05
申请人： Nobuaki Kawabata
发明人： Nobuaki Kawabata
IPC分类号： C08J3/03 , C08J7/04 , C08K5/07 , C08K5/13 , C08K5/34 , C08L5/00 , C08L33/02 , C08L33/04 , C08L33/06 , C08L93/00 , C09D133/04 , C09D133/06
CPC分类号： C08J7/047 , C09D133/064 , C08J2433/00 , C08L33/02 , C08L5/00 , C08L93/00
摘要： Disclosed herein are water-based protective composition for coating films. The compositions contain (a) a water-based dispersion of copolymer particles having a number average molecular weight of from 2,000 to 20,000 and a glass transition point of from -10.degree. C. to +40.degree. C. and obtained by emulsion-polymerizing 100 parts by weight of a monomer mixture consisting substantially of (X) 7-12 parts by weight of an .alpha.,.beta.-monoethylenically-unsaturated carboxylic acid and (Y) 88-93 parts by weight of at least one ester selected from the group consisting of C.sub.1-4 -alkyl acrylates and C.sub.1-4 -alkyl methacrylates; as well as specific amounts of (b) an ultraviolet absorber, (c) an antioxidant, (d) a thickening agent and (e) a surface active agent. They can form barrier coats having excellent removability, weatherability, waterproofness, heat resistance and coating-film-protecting property. Their preparation processes are also disclosed.

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