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1. 发明授权

US07443651B2 Organic electrolyte capacitor 有权
标题翻译：有机电解电容器
公开(公告)号：US07443651B2
公开(公告)日：2008-10-28
申请号：US10573943
申请日：2004-09-27
申请人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fujii , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fujii , Yukinori Hato , Chisato Marumo
IPC分类号： H01G9/00
CPC分类号： H01G11/06 , H01G11/50 , H01G11/70 , H01M10/0525 , H01M2010/4292 , Y02E60/13
摘要： An organic electrolyte capacitor. The organic capacitor is made up of a positive electrode, a negative electrode, and an electrolyte capable of transporting lithium ions. The organic capacitor exhibits a small change in internal resistance during charge and discharge, a high energy and a high output power, and allows lithium ions to move with ease. This is achieved by having a positive electrode that is able to support lithium ions and anions reversibly, a negative electrode that is able to support lithium ions reversibly, and controlling the ratio of positive electrode active material to negative electrode active material within an optimized range.
摘要翻译：有机电解电容器。有机电容器由正极，负极和能够输送锂离子的电解质组成。有机电容器在充电和放电期间内部电阻变化很小，能量高，输出功率高，并且容易使锂离子移动。这是通过具有能够可逆地支持锂离子和阴离子的正极，能够可逆地负载锂离子的负极，并将正极活性物质与负极活性物质的比例控制在优化范围内来实现的。

2. 发明申请

US20070002524A1 Organic electrolyte capacitor 有权
标题翻译：有机电解电容器
公开(公告)号：US20070002524A1
公开(公告)日：2007-01-04
申请号：US10573943
申请日：2004-09-27
申请人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fujii , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fujii , Yukinori Hato , Chisato Marumo
IPC分类号： H01G9/145
CPC分类号： H01G11/06 , H01G11/50 , H01G11/70 , H01M10/0525 , H01M2010/4292 , Y02E60/13
摘要： Discharge at a high current density has been difficult because of problems that an electrolytic solution has low conductivity and absorption and desorption reaction of lithium ions are slow in the negative electrode. However, let a (mAh) be a cell capacity when the organic electrolyte capacitor in a charged state is discharged to half the charging voltage over 1±0.25 hours, and b (mAh) be a negative electrode capacity when the negative electrode in the charged state is discharged to 1.5 V (Li/Li+), then, by controlling a ratio of a positive electrode active material and a negative electrode active material to satisfy 0.05≦a/b≦0.30, it is possible to achieve a high-performance organic electrolyte capacitor having a small internal resistance and a small change in internal resistance during charging and discharging as well a high output density, in which lithium ions are allowed to move with ease.
摘要翻译：由于电解液的导电性低，锂离子的吸附和解吸反应在负极中缓慢的问题，所以难以进行高电流密度的放电。然而，当充电状态下的有机电解电容器在1±0.25小时内放电至充电电压的一半时，使（mAh）为电池容量，当充电状态下的负极为负极时，将（mAh）设为负极容量放电至1.5V（Li / Li +），然后通过控制正极活性物质和负极活性物质的比例满足0.05 <= a /b≤0.30的范围，具有小的内部电阻和充放电期间的内部电阻变化小的高性能的有机电解电容器，以及允许锂离子容易地移动的高输出密度。

3. 发明申请

US20070002523A1 Organic electrolyte capacitor 有权
标题翻译：有机电解电容器
公开(公告)号：US20070002523A1
公开(公告)日：2007-01-04
申请号：US10551875
申请日：2004-03-29
申请人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fujii , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fujii , Yukinori Hato , Chisato Marumo
IPC分类号： H01G9/00
CPC分类号： H01G9/155 , H01G9/016 , H01G9/058 , H01G11/06 , H01G11/12 , H01G11/28 , H01G11/32 , H01G11/60 , H01G11/62 , H01G11/70 , H01M4/133 , H01M4/137 , H01M4/602 , H01M4/667 , H01M4/70 , H01M4/742 , H01M10/052 , H01M10/0525 , H01M10/0585 , H01M10/0587 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： There is provided an organic electrolyte capacitor having electrodes on current collectors that have holes penetrating the front and rear surfaces, in which electrode materials formed an the through-holes of the current collectors seldom fall off and high energy density and high power density can be obtained. The organic electrolyte capacitor includes positive electrodes, negative electrodes and an electrolyte capable of transferring lithium ions, in which the positive electrodes contain a substance capable of carrying lithium ions and/or anions reversibly as a positive electrode active material, the negative electrodes contain a substance capable of carrying lithium ions as a negative electrode active material, the positive and negative electrodes possess the positive or negative electrode active material layers on an electrode substrate that has conductive layers made of conductive materials on current collectors, which have through-holes, and the negative electrodes carry lithium electrochemically.
摘要翻译：提供了一种有机电解电容器，其具有在集电体上具有穿透前后表面的孔的电极，其中形成集电极的通孔很少脱落的电极材料，能够获得高能量密度和高功率密度。有机电解质电容器包括正极，负极和能够转移锂离子的电解质，其中正极含有能够携带锂离子和/或阴离子的物质作为正极活性物质，负极含有物质能够承载锂离子作为负极活性物质的正极和负极具有在具有通孔的集电体上由导电材料制成的导电层的电极基板上具有正极或负极活性物质层，并且负极电化学地携带锂。

4. 发明授权

US07385801B2 Organic electrolyte capacitor 有权
标题翻译：有机电解电容器
公开(公告)号：US07385801B2
公开(公告)日：2008-06-10
申请号：US10551875
申请日：2004-03-29
申请人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fuji , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Kenji Kojima , Shinichi Tasaki , Hiromoto Taguchi , Tsutomu Fuji , Yukinori Hato , Chisato Marumo
IPC分类号： H01G9/00 , H01G9/02 , H01G9/04
CPC分类号： H01G9/155 , H01G9/016 , H01G9/058 , H01G11/06 , H01G11/12 , H01G11/28 , H01G11/32 , H01G11/60 , H01G11/62 , H01G11/70 , H01M4/133 , H01M4/137 , H01M4/602 , H01M4/667 , H01M4/70 , H01M4/742 , H01M10/052 , H01M10/0525 , H01M10/0585 , H01M10/0587 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： There is provided an organic electrolyte capacitor having electrodes on current collectors that have holes penetrating the front and rear surfaces, in which electrode materials formed on the through-holes of the current collectors seldom fall off and high energy density and high power density can be obtained. The organic electrolyte capacitor includes positive electrodes, negative electrodes and an electrolyte capable of transferring lithium ions, in which the positive electrodes contain a substance capable of carrying lithium ions and/or anions reversibly as a positive electrode active material, the negative electrodes contain a substance capable of carrying lithium ions as a negative electrode active material, the positive and negative electrodes possess the positive or negative electrode active material layers on an electrode substrate that has conductive layers made of conductive materials on current collectors, which have through-holes, and the negative electrodes carry lithium electrochemically.
摘要翻译：提供了一种有机电解质电容器，其具有在集电体上具有穿透前后表面的孔的电极，其中形成在集电体的通孔上的电极材料很少脱落，并且能够获得高能量密度和高功率密度。有机电解质电容器包括正极，负极和能够转移锂离子的电解质，其中正极含有能够携带锂离子和/或阴离子的物质作为正极活性物质，负极含有物质能够承载锂离子作为负极活性物质的正极和负极具有在具有通孔的集电体上由导电材料制成的导电层的电极基板上具有正极或负极活性物质层，并且负极电化学地携带锂。

5. 发明申请

US20090023066A1 NEGATIVE ELECTRODE ACTIVE MATERIAL FOR CHARGING DEVICE 有权
标题翻译：用于充电装置的负极电极活性材料
公开(公告)号：US20090023066A1
公开(公告)日：2009-01-22
申请号：US11911630
申请日：2006-04-25
申请人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
发明人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M4/00 , H01M4/58
CPC分类号： H01M10/0525 , C01B32/00 , H01G9/038 , H01G9/155 , H01G11/24 , H01G11/42 , H01G11/50 , H01M4/587 , H01M10/0566 , H01M2004/021 , H01M2004/027 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： To present a carbon material which provides an electrical storage device not only ensuring a high energy density but also realizing a high output and an excellent low temperature performance.A negative electrode active material for an electrical storage device employing an aprotic organic solvent electrolyte solution containing a lithium salt as an electrolytes characterized in that it is made of a carbon material having a specific surface area of from 0.01 to 50 m2/g and a total mesopore volume of from 0.005 to 1.0 cc/g, wherein volumes of mesopores having pore diameters of from 100 to 400 Å occupy at least 25% of the total mesopore volume.
摘要翻译：提供一种提供蓄电装置的碳材料，不仅确保高能量密度，而且实现高输出和优异的低温性能。一种使用含有锂盐作为电解质的非质子性有机溶剂电解质溶液的蓄电装置用负极活性物质，其特征在于，其比表面积为0.01〜50m2 / g，总计为介孔体积为0.005至1.0cc / g，其中孔径为100至400的介孔的体积占总介孔体积的至少25％。

6. 发明授权

US08142930B2 Negative electrode active material for charging device 有权
标题翻译：负极活性物质用于充电装置
公开(公告)号：US08142930B2
公开(公告)日：2012-03-27
申请号：US11911630
申请日：2006-04-25
申请人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
发明人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M4/13 , C01B31/04
CPC分类号： H01M10/0525 , C01B32/00 , H01G9/038 , H01G9/155 , H01G11/24 , H01G11/42 , H01G11/50 , H01M4/587 , H01M10/0566 , H01M2004/021 , H01M2004/027 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： To present a carbon material which provides an electrical storage device not only ensuring a high energy density but also realizing a high output and an excellent low temperature performance.A negative electrode active material for an electrical storage device employing an aprotic organic solvent electrolyte solution containing a lithium salt as an electrolytes characterized in that it is made of a carbon material having a specific surface area of from 0.01 to 50 m2/g and a total mesopore volume of from 0.005 to 1.0 cc/g, wherein volumes of mesopores having pore diameters of from 100 to 400 Å occupy at least 25% of the total mesopore volume.
摘要翻译：提供一种提供蓄电装置的碳材料，不仅确保高能量密度，而且实现高输出和优异的低温性能。一种使用含有锂盐作为电解质的非质子性有机溶剂电解质溶液的蓄电装置用负极活性物质，其特征在于，其比表面积为0.01〜50m2 / g，总计为介孔体积为0.005至1.0cc / g，其中孔径为100至400的介孔的体积占总介孔体积的至少25％。

7. 发明申请

US20060057433A1 Electrical storage device and manufacturing electrical storage device 审中-公开
标题翻译：蓄电装置及制造蓄电装置
公开(公告)号：US20060057433A1
公开(公告)日：2006-03-16
申请号：US10540907
申请日：2003-12-25
申请人： Nobuo Ando , Shinichi Tasaki , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Shinichi Tasaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M14/00 , H01M4/58 , H01M10/04
CPC分类号： H01G9/155 , H01M4/13 , H01M4/382 , H01M4/587 , H01M6/5005 , H01M6/5044 , H01M10/0431 , H01M10/0436 , H01M10/052 , H01M10/058 , H01M10/0587 , H01M10/4242 , H01M10/44 , H01M10/446 , H01M10/48 , H01M2010/4292 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108 , Y10T29/4911
摘要： An electrical storage device of the present invention is characterized in that a positive electrode, a negative electrode, a lithium electrode, and an electrolyte capable of transferring lithium ion is included, the lithium electrode is arranged to be out of direct contact with the negative electrode, and lithium ion can be supplied to the negative electrode by flowing a current between the lithium electrode and the negative electrode through an external circuit. With the above characteristic, problems such as non-uniform carrying of lithium ion to the negative electrode, shape-change of a cell, and temperature increase of an electrolytic solution under incomplete sealing of a cell and the like can be easily solved. A using method of the electrical storage device is characterized in that, by using the lithium electrode as a reference electrode, the positive electrode potential and negative electrode potential can be measured, and the potential of the positive or negative electrode can be controlled when the electrical storage device is charged or discharged. Therefore, the potentials of the positive electrode and negative electrode can be monitored, thereby it can be easily determined whether deterioration of the electrical storage device is caused by the positive electrode or the negative electrode. Also, it is possible to control the device with the potential difference between the negative electrode and reference electrode, that is, the negative potential. In addition, when characteristics deteriorate such as the internal resistance increase, an appropriate amount of lithium ion can be supplied to the negative electrode and/or positive electrode by the lithium electrode.
摘要翻译：本发明的蓄电装置的特征在于，包括正极，负极，锂电极和能够转移锂离子的电解质，所述锂电极配置为与所述负极直接接触可以通过外部电路在锂电极和负极之间流动电流而向负极供给锂离子。利用上述特征，可以容易地解决诸如锂离子对负极的不均匀携带，电池形状变化以及电池不完全密封等下的电解液温度升高等问题。电气存储装置的使用方法的特征在于，通过使用锂电极作为参考电极，可以测量正极电位和负极电位，并且可以在电气存储设备充电或放电。因此，可以监视正极和负极的电位，从而可以容易地确定是否由正极或负极引起蓄电装置的劣化。此外，可以用负电极和参考电极之间的电位差来控制器件，即负电位。此外，当诸如内阻增加之类的特性劣化时，可以通过锂电极向负极和/或正极供应适量的锂离子。

8. 发明授权

US08152865B2 Electrical storage device and manufacturing method of the same 有权
标题翻译：蓄电装置及其制造方法相同
公开(公告)号：US08152865B2
公开(公告)日：2012-04-10
申请号：US12862155
申请日：2010-08-24
申请人： Nobuo Ando , Shinichi Tasaki , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Shinichi Tasaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M10/04 , H01M10/052 , H01M10/058
CPC分类号： H01G9/155 , H01M4/13 , H01M4/382 , H01M4/587 , H01M6/5005 , H01M6/5044 , H01M10/0431 , H01M10/0436 , H01M10/052 , H01M10/058 , H01M10/0587 , H01M10/4242 , H01M10/44 , H01M10/446 , H01M10/48 , H01M2010/4292 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108 , Y10T29/4911
摘要： An electrical storage device having a positive electrode, a negative electrode, a lithium electrode, and an electrolyte capable of transferring lithium ion, the lithium electrode is out of direct contact with the negative electrode, and lithium ion is supplied to the negative electrode by flowing a current between the lithium and negative electrode through an external circuit. A method of using the electrical storage device includes using the lithium electrode as a reference electrode, the positive electrode potential and negative electrode potential is measured, and the potential of the positive or negative electrode is controlled during charging or discharging. The potentials of the positive electrode and negative electrode are monitored to easily determine whether deterioration of the electrical storage device is caused by the positive or negative electrode. It is possible to control the device with the potential difference between the negative electrode and reference electrode, using the negative potential.
摘要翻译：具有正极，负极，锂电极和能够转移锂离子的电解质的蓄电装置，锂电极不与负极直接接触，并且通过流动将锂离子供给到负极通过外部电路在锂和负极之间的电流。使用蓄电装置的方法包括使用锂电极作为参比电极，测定正极电位和负极电位，并且在充电或放电期间控制正极或负极的电位。监测正极和负极的电位，以容易地确定蓄电装置的劣化是由正极还是由负极引起。使用负电位可以用负电极和参考电极之间的电位差来控制器件。

9. 发明申请

US20110041324A1 ELECTRICAL STORAGE DEVICE AND MANUFACTURING METHOD OF THE SAME 有权
标题翻译：电气存储装置及其制造方法
公开(公告)号：US20110041324A1
公开(公告)日：2011-02-24
申请号：US12862155
申请日：2010-08-24
申请人： Nobuo Ando , Shinichi Tasaki , Yukinori Hato , Chisato Marumo
发明人： Nobuo Ando , Shinichi Tasaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M4/04
CPC分类号： H01G9/155 , H01M4/13 , H01M4/382 , H01M4/587 , H01M6/5005 , H01M6/5044 , H01M10/0431 , H01M10/0436 , H01M10/052 , H01M10/058 , H01M10/0587 , H01M10/4242 , H01M10/44 , H01M10/446 , H01M10/48 , H01M2010/4292 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108 , Y10T29/4911
摘要： An electrical storage device having a positive electrode, a negative electrode, a lithium electrode, and an electrolyte capable of transferring lithium ion, the lithium electrode is out of direct contact with the negative electrode, and lithium ion is supplied to the negative electrode by flowing a current between the lithium and negative electrode through an external circuit. A method of using the electrical storage device includes using the lithium electrode as a reference electrode, the positive electrode potential and negative electrode potential is measured, and the potential of the positive or negative electrode is controlled during charging or discharging. The potentials of the positive electrode and negative electrode are monitored to easily determine whether deterioration of the electrical storage device is caused by the positive or negative electrode. It is possible to control the device with the potential difference between the negative electrode and reference electrode, using the negative potential.
摘要翻译：具有正极，负极，锂电极和能够转移锂离子的电解质的蓄电装置，锂电极不与负极直接接触，并且通过流动将锂离子供给到负极通过外部电路在锂和负极之间的电流。使用蓄电装置的方法包括使用锂电极作为参比电极，测定正极电位和负极电位，并且在充电或放电期间控制正极或负极的电位。监测正极和负极的电位，以容易地确定蓄电装置的劣化是由正极还是由负极引起。使用负电位可以用负电极和参考电极之间的电位差来控制器件。

10. 发明授权

US07548409B2 Organic electrolyte capacitor using a mesopore carbon material as a negative electrode 有权
标题翻译：使用中孔碳材料作为负极的有机电解电容器
公开(公告)号：US07548409B2
公开(公告)日：2009-06-16
申请号：US10599383
申请日：2005-03-31
申请人： Kenji Kojima , Satoshi Nagura , Nobuo Ando , Yukinori Hato , Chisato Marumo
发明人： Kenji Kojima , Satoshi Nagura , Nobuo Ando , Yukinori Hato , Chisato Marumo
IPC分类号： H01G9/00
CPC分类号： H01G11/50 , H01G11/26 , H01G11/32 , Y02E60/13
摘要： An organic electrolyte capacitor is provided with a high energy density, a high power and a high capacitance even at −20°. The organic electrolyte capacitor has a high discharge capacity even at a temperature as low as −20° C., while having a high voltage and a high energy density. The structure of the organic electrolyte capacitor includes a positive electrode, a negative electrode, and an electrolyte capable of transporting lithium ions. The positive electrode can reversibly support lithium ions and anions, and the negative electrode can reversibly support the lithium ions by using a mesopored carbon material having a pore volume of 0.10 ml/g or more for a pore diameter of 3 nm or larger.
摘要翻译：有机电解质电容器即使在-20°也具有高能量密度，高功率和高电容。有机电解质电容器即使在低至-20℃的温度下也具有高放电容量，同时具有高电压和高能量密度。有机电解质电容器的结构包括正极，负极和能够输送锂离子的电解质。正极可以可逆地支持锂离子和阴离子，负极可以通过使用孔径为3nm以上的孔体积为0.10ml / g以上的中孔碳材料来可逆地负载锂离子。

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