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    • 7. 发明授权
    • Acetylene compound, liquid crystal composition and liquid crystal element
    • 乙炔化合物,液晶组合物和液晶元素
    • US06217793B1
    • 2001-04-17
    • US09312698
    • 1999-05-17
    • Yoshiyuki TotaniHiroe KayashimaTsutomu IshidaMasakatsu Nakatsuka
    • Yoshiyuki TotaniHiroe KayashimaTsutomu IshidaMasakatsu Nakatsuka
    • C09K1932
    • C09K19/2007C09K19/32
    • Provided are novel acetylene compounds which are useful as a component for a liquid crystal composition used for a liquid crystal element, a liquid crystal composition containing said compounds and a liquid crystal element using said liquid crystal composition. The acetylene compound is represented by Formula (1): n-CmH2m+1—C≡C—A—Z1—B—Y1—R1  (1) wherein m represents an integer of 2 to 24; R1 represents a linear or branched alkyl group, a linear or branched alkoxyalkyl group, a linear or branched alkenyl group, or a linear or branched alkenyloxyalkyl group each of which may be substituted with a halogen atom; R1 may have an asymmetric carbon atom, and the asymmetric carbon atom may be optically active; A and B represents a cyclic group such as a phenylene group, a biphenylene group, a naphthylene group and the like each of which may be substituted with a halogen atom.
    • 提供了可用作用于液晶元件的液晶组合物的组分,含有所述化合物的液晶组合物和使用所述液晶组合物的液晶元件的新型乙炔化合物。 乙炔化合物由式(1)表示:其中m表示2〜24的整数; R1表示直链或支链烷基,直链或支链烷氧基烷基,直链或支链烯基,或每个可被卤素原子取代的直链或支链烯氧基烷基; R1可以具有不对称碳原子,并且不对称碳原子可以是光学活性的; A和B表示可以被卤素原子取代的亚苯基,亚联苯基,亚萘基等环状基团。
    • 9. 发明授权
    • Method for preparing an aromatic polycarbonate
    • 芳族聚碳酸酯的制备方法
    • US5426170A
    • 1995-06-20
    • US158518
    • 1993-11-29
    • Motokazu HiraoYoshiyuki TotaniTomonori ItoMasakatsu NakatsukaAkihiro Yamaguchi
    • Motokazu HiraoYoshiyuki TotaniTomonori ItoMasakatsu NakatsukaAkihiro Yamaguchi
    • C08G64/14C08G64/24C08G64/28C08G64/00
    • C08G64/28C08G64/14C08G64/24
    • 1. A method for preparing an aromatic polycarbonate having less content of a low molecular weight oligomer which comprises the steps of:(A) conducting an interfacial polymerization reaction in a reaction system comprising at least one aromatic dihydroxy compound, a carbonate precursor, an alkali metal or alkaline earth metal base, water and an organic solvent in the absence of an endcapping agent, and(B) conducting an interfacial polymerization reaction with the addition of an endcapping agent after at least one of the following parameters reaches a predetermined value:(1) a weight-average molecular weight of a prepolymer obtained in step A,(2) a residual amount of the aromatic dihydroxy compound which is contained in the reaction mixture obtained in step A,(3) an amount ratio of a bishaloformate compound to a prepolymer wherein the bishaloformate compound is a bishaloformate derivative of a dihydroxy compound and is contained in the reaction mixture obtained in step A.
    • 1.一种制备低分子量低聚物含量较低的芳族聚碳酸酯的方法,其包括以下步骤:(A)在包含至少一种芳族二羟基化合物,碳酸酯前体,碱的反应体系中进行界面聚合反应 金属或碱土金属碱,水和有机溶剂,和(B)在至少一个以下参数达到预定值后,加入封端剂进行界面聚合反应:( 1)步骤A中获得的预聚物的重均分子量,(2)步骤A中获得的反应混合物中所含的芳族二羟基化合物的残留量,(3)双卤代甲酸酯化合物与 预聚物,其中双卤代甲酸酯化合物是二羟基化合物的双卤代甲酸酯衍生物,并且包含在步骤A中获得的反应混合物中。