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    • 3. 发明授权
    • Homogeneously surface-fluorinated metal oxide particulates, process for manufacturing the same, and use of the same
    • 均匀的表面氟化金属氧化物颗粒,其制造方法及其用途
    • US06281277B1
    • 2001-08-28
    • US09296667
    • 1999-04-22
    • Nobuaki IshiiKoichi WadaKazuo SekiguchiHiroyuki Takahashi
    • Nobuaki IshiiKoichi WadaKazuo SekiguchiHiroyuki Takahashi
    • C08K300
    • B82Y30/00C01B13/145C01B33/18C01F7/021C01P2004/62C01P2004/64C01P2004/80C01P2006/12C01P2006/80C08K9/02C09C1/3045C09C1/3653C09C3/06
    • The present invention provides homogeneously surface-fluorinated metal oxide particulates, characterized in that a metal oxide particulate such as Ti, Al, Si, Ag, Cu, Fe, Zr, Ce, Mn, Sn, Ge and Ta is surface reacted with fluorine gas while allowing the metal oxide particulate to flow, and also provides a process for manufacturing the metal oxide particulates. The homogeneously surface-fluorinated metal oxide particulates according to the present invention are useful as an additive for a weatherproof coating material, a weatherproof resin or a cosmetic material. Furthermore, according to the process of the present invention, the surface of a metal oxide particulate can be homogeneously fluorinated at any ratio in a very simple and efficient manner. Even when the homogeneously surface-fluorinated titanium oxide is incorporated as a white pigment into a thermoplastic resin in a high concentration, the resin coated substrate can maintain the surface smoothness without causing any partial defect and troubles can be greatly prevented from occurring at the melt extrusion coating for obtaining the resin coated substrate.
    • 本发明提供均匀的表面氟化金属氧化物微粒,其特征在于,诸如Ti,Al,Si,Ag,Cu,Fe,Zr,Ce,Mn,Sn,Ge和Ta的金属氧化物颗粒与氟气表面反应 同时允许金属氧化物颗粒流动,并且还提供用于制造金属氧化物颗粒的方法。根据本发明的均匀的表面氟化的金属氧化物颗粒可用作耐候性涂料,防风雨树脂或 化妆品材料。 此外,根据本发明的方法,金属氧化物颗粒的表面可以以非常简单和有效的方式以任何比例均匀地氟化。 即使将均匀的表面氟化的氧化钛作为白色颜料以高浓度结合到热塑性树脂中,树脂涂布的基材也可以保持表面光滑度而不会产生任何部分缺陷,并且可以极大地防止在熔融挤出时发生麻烦 用于获得树脂涂覆的基底的涂层。
    • 4. 发明授权
    • Cosmetic composition
    • 化妆品组成
    • US06500415B2
    • 2002-12-31
    • US09873398
    • 2001-06-05
    • Nobuaki IshiiJunko FutamiKouichi WadaMichihiro Takama
    • Nobuaki IshiiJunko FutamiKouichi WadaMichihiro Takama
    • A61K3174
    • B82Y30/00A61K8/29A61K8/731A61K8/732A61K8/733A61K8/8147A61Q1/02A61Q17/04C01P2002/82C01P2002/84C01P2004/04C01P2004/62C01P2004/64C01P2004/82C01P2004/86C01P2006/60C09C1/043C09C1/3661Y10S514/972
    • A cosmetic composition comprising titanium oxide coated with one or both of silica and alumina or zinc oxide coated with one or both of silica and alumina, and a thickening polymer having a carboxyl group in the side chain, preferably a carboxyvinyl polymer, wherein when 10% by mass of silica- and/or alumina-coated titanium oxide or silica- and/or alumina-coated zinc oxide is dispersed in an aqueous solution containing 0.133% by mass of a carboxyvinyl polymer, the viscosity after the passing of 100 hours is 50% or more of the initial viscosity. A cosmetic composition comprising titanium oxide coated with one or both silica and alumina or zinc oxide coated with one or both of silica and alumina, and a thickening polymer having a carboxyl group in the side chain of the invention, can maintain emulsion stability by thickening of polymer for a long period of time and can be widely and suitably used for ultraviolet shielding cosmetic materials or the like having preparation form stability.
    • 一种化妆品组合物,其包含用二氧化硅和氧化铝中的一种或二者涂覆的二氧化钛或涂覆有二氧化硅和氧化铝中的一种或两种的氧化锌,以及在侧链中具有羧基的增稠聚合物,优选羧基乙烯基聚合物,其中当10% 的二氧化硅和/或氧化铝涂覆的氧化钛或二氧化硅和/或氧化铝涂覆的氧化锌分散在含有0.133质量%羧基乙烯基聚合物的水溶液中,100小时后的粘度为50 %以上的初始粘度。 包含二氧化硅和氧化铝或二氧化硅或二氧化硅和氧化铝中的一种或二者涂覆的二氧化钛的化妆品组合物和本发明侧链具有羧基的增稠聚合物可以通过增稠而保持乳液的稳定性 聚合物长时间并且可广泛适用于具有制备形式稳定性的紫外线屏蔽化妆品等。
    • 5. 发明授权
    • Cosmetic composition
    • 化妆品组成
    • US06942878B2
    • 2005-09-13
    • US10363664
    • 2001-09-10
    • Nobuaki IshiiKouichi WadaJunko FutamiMichihiro Takama
    • Nobuaki IshiiKouichi WadaJunko FutamiMichihiro Takama
    • A61K8/11A61K8/25A61K8/27A61K8/29A61K8/35A61K8/37A61Q17/04A61K9/14
    • A61K8/11A61K8/25A61K8/27A61K8/29A61K8/35A61K8/37A61K2800/412A61K2800/413A61Q17/04
    • To provide a cosmetic composition having excellent ultraviolet protection against both UVB and UVA, causing neither unpleasant whitening to the applied skin nor skin irritation, and ensuring good feeling on use and high safety and high stability without causing decomposition of the ingredients blended in the cosmetic material, such as organic ultraviolet absorber. A cosmetic composition obtained by using fine particulate titanium oxide and fine particulate zinc oxide each surface-treated with silica, alumina or alumina/silica and having a primary particle size of 0.01 to 0.2 μm in combination and blending titanium oxide and zinc oxide at a mass ratio of 1:4 to 2:3, wherein SPF is maintained as compared with the case where the mass ratio of titanium oxide to zinc oxide is 1:0, and when applied to a thickness of 10 μm, the whiteness W value measured using the CIE color specification system is 20 or less.
    • 为了提供对UVB和UVA均具有优异的紫外线防护性的化妆品组合物,不会对所施用的皮肤造成令人不愉快的美白,也不引起皮肤刺激,并且确保良好的使用感和高安全性和高稳定性,而不会引起混合在化妆品材料中的成分的分解 ,如有机紫外线吸收剂。 通过使用二氧化硅,氧化铝或氧化铝/二氧化硅进行表面处理的细颗粒氧化钛和细粒状氧化锌并且一次粒径为0.01〜0.2μm的组合并以氧化钛和氧化锌的质量混合而获得的化妆品组合物 比例为1:4〜2:3,与氧化钛与氧化锌的质量比为1:0的情况相比,维持SPF,当施加到10μm的厚度时,使用 CIE颜色规格系统为20以下。