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1. 发明授权

US07150861B2 Catalyst for purification of exhaust gases and process for purification of exhaust gases 失效
标题翻译：用于净化废气的催化剂和废气净化方法
公开(公告)号：US07150861B2
公开(公告)日：2006-12-19
申请号：US10247376
申请日：2002-09-20
申请人： Atsushi Morita , Junji Okamura , Shinyuki Masaki , Noboru Sugishima , Motonobu Kobayashi
发明人： Atsushi Morita , Junji Okamura , Shinyuki Masaki , Noboru Sugishima , Motonobu Kobayashi
IPC分类号： B01J23/58 , B01J23/64 , B01J21/06 , B01J27/55 , B01D53/56 , B01D53/62 , B01D53/94
CPC分类号： B01D53/945 , B01D2255/102 , B01D2255/106 , B01D2255/207 , B01D2255/9207 , Y02T10/22
摘要： A catalyst for purification of CO-containing exhaust gases, includes a metal oxide as a support and a catalytic component A being supported thereon as a catalytic component and including a specific noble metal element; wherein the support includes a titanium-containing oxide as the metal oxide and is a monolithically molded type porous honeycomb support obtained by a process including the steps of extrusion-molding and then calcining materials of the support; and wherein the catalytic component A is distributed with a quantitatively great inclination toward surfaces of the catalyst. A process for purification of exhaust gases to remove CO therefrom, includes the step of bringing the exhaust gases into contact with the catalyst.
摘要翻译：用于净化含CO废气的催化剂包括作为载体的金属氧化物和作为催化剂组分负载并包括特定贵金属元素的催化组分A，其中所述载体包括含钛氧化物作为所述金属氧化物，并且是通过包括以下步骤的方法得到的整体模制型多孔蜂窝载体，所述方法包括挤出成型然后煅烧所述载体的材料; 并且其中催化组分A以定量大的倾斜分布在催化剂的表面上。净化废气以从其中除去CO的方法包括使废气与催化剂接触的步骤。

2. 发明授权

US07740819B2 Process for purification of exhaust gases and catalyst used for purification of exhaust gases in this process 失效
标题翻译：在此过程中净化废气和用于净化废气的催化剂的方法
公开(公告)号：US07740819B2
公开(公告)日：2010-06-22
申请号：US10354201
申请日：2003-01-30
申请人： Atsushi Morita , Junji Okamura , Shinyuki Masaki , Noboru Sugishima , Motonobu Kobayashi
发明人： Atsushi Morita , Junji Okamura , Shinyuki Masaki , Noboru Sugishima , Motonobu Kobayashi
IPC分类号： B01D53/56
CPC分类号： B01D53/944 , B01D53/864
摘要： The present invention has an object to more enhance the efficiency of the purification of the CO-containing exhaust gases with a catalytic-component-supporting type catalyst, particularly, to enable both achievement of high purification efficiency and long-term stable maintenance of high purification efficiency without increasing the quantity of the catalytic component as supported. As a means of achieving this object, a process for purification of exhaust gases, according to the present invention, is a process for purification of exhaust gases to remove CO therefrom, and is characterized by comprising the step of bringing the exhaust gases into contact with a catalyst layer at a temperature of 250 to 600° C., a pressure drop of not more than 100 mmH2O, and a linear velocity of 0.5 to 10 m/s, wherein the catalyst layer includes a honeycomb-structural catalyst having an opening size of 1.0 to 3.0 mm, an opening ratio of 60 to 80%, and an inner wall thickness of less than 2 mm.
摘要翻译：本发明的目的是通过催化组分负载型催化剂来更有效地提高含CO废气的净化效率，特别是能够实现高纯化效率和高纯度的长期稳定的维持效率而不增加所支持的催化组分的量。作为实现该目的的手段，根据本发明的废气净化方法是净化废气以从其中除去CO的方法，其特征在于包括使废气与催化剂层，其温度为250〜600℃，压降为100mmH2O以下，线速度为0.5〜10m / s，其中，催化剂层包含蜂窝结构催化剂，其具有开口尺寸为1.0〜3.0mm，开口率为60〜80％，内壁厚度为2mm以下。

3. 发明授权

US6120747A Catalyst for removing organic halogen compounds, preparation method therefor and method for removing organic halogen compounds 失效
标题翻译：用于除去有机卤素化合物的催化剂，其制备方法和除去有机卤素化合物的方法
公开(公告)号：US6120747A
公开(公告)日：2000-09-19
申请号：US995099
申请日：1997-12-19
申请人： Noboru Sugishima , Atsushi Morita , Motonobu Kobayashi
发明人： Noboru Sugishima , Atsushi Morita , Motonobu Kobayashi
IPC分类号： B01D53/86 , B01J21/06 , B01J35/10 , C01B7/00 , A62D3/00 , B01J23/00
CPC分类号： B01J21/063 , B01D53/8659 , B01J23/30 , B01J35/002 , B01J35/023 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/031 , B01J2523/00
摘要： The present invention provides a catalyst having excellent capability of removing organic halogen compounds such as dioxins, a method for preparing the catalyst, and a method for removing organic halogen compounds using the catalyst. A catalyst for removing organic halogen compounds comprises titanium oxide as a catalyst component and has pores including a group of pores having a pore diameter distribution peak in a range of 0.01 to 0.05 gm and another group of pores having a pore diameter distribution peak in a range of 0.1 to 0.8 .mu.m. Another catalyst for removing organic halogen compounds comprises titanium oxide and a titanium-silicon composite oxide as catalyst components and has pores including a group of pores having a pore diameter distribution peak in a range of 0.01 to 0.05 .mu.m and another group of pores having a pore diameter distribution peak in a range of 0.8 to 4 .mu.m.
摘要翻译：本发明提供了除去有机卤素化合物如二恶英的能力优异的催化剂，催化剂的制备方法和使用该催化剂除去有机卤素化合物的方法。用于除去有机卤素化合物的催化剂包括氧化钛作为催化剂组分，并且具有包含具有在0.01至0.05gm范围内的孔径分布峰的一组孔的孔，另一组孔径分布峰在一定范围内为0.1〜0.8μm。用于除去有机卤素化合物的另一种催化剂包括钛氧化物和钛 - 硅复合氧化物作为催化剂组分，并且具有包含具有0.01至0.05μm范围内的孔径分布峰的一组孔的孔，另一组具有孔径分布峰值在0.8〜4μm的范围内。

4. 发明授权

US5658546A Denitration catalyst 失效
标题翻译：脱硝催化剂
公开(公告)号：US5658546A
公开(公告)日：1997-08-19
申请号：US522536
申请日：1995-09-01
申请人： Motonobu Kobayashi , Noboru Sugishima , Katsunori Miyoshi
发明人： Motonobu Kobayashi , Noboru Sugishima , Katsunori Miyoshi
IPC分类号： B01D53/86 , B01D53/94 , B01J23/30 , B01J23/888 , B01J21/06 , C01B21/00
CPC分类号： B01J23/888 , B01D53/8628 , B01D53/9418 , B01J23/30 , B01D2251/2062 , B01D2255/20707 , B01D2255/20776 , B01D2258/012
摘要： There is provided a denitration catalyst excellent in denitration activity and durability in a high temperature region, for catalytically reducing NOx in an exhaust gas using a reducing agent such as ammonia. This denitration catalyst is (1) one containing a titanium-tungsten oxide obtained by coprecipitating a soluble titanium compound and a soluble tungsten compound from an aqueous medium under the conditions of a temperature of 60.degree. C. or less and a pH of the range of 5 to 8, and drying and calcining to coprecipitate formed; or (2) one comprising said titanium-tungsten oxide (component A), and an oxide of at least one element (component B) selected from the group consisting of cerium (Ce), lanthanum (La), praseodymium (Pr), neodymium (Nd), nickel (Ni) and tin (Sn).
摘要翻译：提供了一种脱硝催化剂，其在高温区域的脱硝活性和耐久性优异，使用氨等还原剂催化还原废气中的NOx。该脱硝催化剂为（1）在温度60℃以下，pH范围为0.1以下的条件下，将含有钛 - 氧化钨的水溶性钛化合物和可溶性钨化合物从水性介质中共沉淀而成的 5〜8，干燥煅烧成共沉淀物; 或者（2）包含所述钛 - 氧化钨（A成分）和选自由铈（Ce），镧（La），镨（Pr），钕（镨），镨（Nd），镍（Ni）和锡（Sn）。

5. 发明授权

US08173098B2 Titanium oxide, catalyst for treating exhaust gas and method for purifying exhaust gas 有权
标题翻译：氧化钛，废气处理催化剂和净化废气的方法
公开(公告)号：US08173098B2
公开(公告)日：2012-05-08
申请号：US11886462
申请日：2006-05-26
申请人： Atsushi Morita , Ryoji Kuma , Shinyuki Masaki , Motonobu Kobayashi
发明人： Atsushi Morita , Ryoji Kuma , Shinyuki Masaki , Motonobu Kobayashi
IPC分类号： C01G23/047 , C01G28/00 , C01G30/00 , C01B33/20 , C01B21/00 , C01B23/00 , C01B25/00 , C01B31/00 , C01B33/00 , C01B35/00 , B01J21/00 , B01J23/00 , B01J8/02 , B01D53/56 , B01D53/94
CPC分类号： C01G23/047 , B01D53/8628 , B01D53/8662 , B01D2255/20707 , B01J21/06 , B01J21/063 , B01J23/002 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/002 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J2523/00 , C01G23/002 , C01G23/0536 , C01P2002/72 , C01P2006/12 , B01J2523/41 , B01J2523/47 , B01J2523/68 , B01J2523/55 , B01J2523/69
摘要： A catalyst for treating exhaust gases having excellent durability and performance for removing nitrogen oxides and organic halogen compounds and a low SO2 oxidation rate, a titanium oxide suitable for preparing the catalyst and a method for treating exhaust gases containing nitrogen oxides and/or organic halogen compounds using the catalyst are provided.The BET specific surface areas of the titanium oxide and the catalyst for treating exhaust gases are in the range of 85 to 250 m2/g and in the range of 50 to 200 m2/g respectively. The titanium oxide and the catalyst for treating exhaust gases have each a ratio in the range of 15 to 145%, the ratio of the intensity of the peak indicating an anatase crystal present in the range of 2θ=24.7° to 2θ=25.7° of powder X-ray diffraction thereof (Ia) to the intensity of the peak indicating an anatase crystal present in the range of 2θ=24.7° to 2θ=25.7° of powder X-ray diffraction of the standard sample comprising a mixture composed of 15% by mass of pure anatase-type titanium dioxide and 85% by mass of pure rutile-type titanium dioxide (Ib).
摘要翻译：一种处理废气的催化剂，其具有优异的耐久性和性能，用于除去氮氧化物和有机卤素化合物和低SO 2氧化速率，适用于制备催化剂的氧化钛和用于处理含有氮氧化物和/或有机卤素化合物的废气的方法使用催化剂。氧化钛和废气处理用催化剂的BET比表面积分别为85〜250m2 / g，范围为50〜200m2 / g。用于处理废气的氧化钛和催化剂各自具有在15至145％的范围内的比率，表示锐钛矿晶体的峰的强度的比率在2θ= 24.7°至2θ的范围内= 25.7 °的粉末X射线衍射（Ia）与表示锐钛矿晶体的强度呈现在2θ的范围内; = 24.7°至2θ= 25.7°的包含混合物的标准样品的粉末X射线衍射由15质量％的纯锐钛矿型二氧化钛和85质量％的纯金红石型二氧化钛（Ib）构成。

6. 发明申请

US20080152560A1 Titanium Oxide, Catalyst For Treating Exhaust Gas and Method For Purifying Exhaust Gas 有权
标题翻译：氧化钛，用于处理废气的催化剂和用于净化废气的方法
公开(公告)号：US20080152560A1
公开(公告)日：2008-06-26
申请号：US11886462
申请日：2006-05-26
申请人： Atsushi Morita , Ryoji Kuma , Shinyuki Masaki , Motonobu Kobayashi
发明人： Atsushi Morita , Ryoji Kuma , Shinyuki Masaki , Motonobu Kobayashi
IPC分类号： B01J21/06 , C01G23/047 , C01B33/20 , B01D53/38
CPC分类号： C01G23/047 , B01D53/8628 , B01D53/8662 , B01D2255/20707 , B01J21/06 , B01J21/063 , B01J23/002 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/002 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J2523/00 , C01G23/002 , C01G23/0536 , C01P2002/72 , C01P2006/12 , B01J2523/41 , B01J2523/47 , B01J2523/68 , B01J2523/55 , B01J2523/69
摘要： A catalyst for treating exhaust gases having excellent durability and performance for removing nitrogen oxides and organic halogen compounds and a low SO2 oxidation rate, a titanium oxide suitable for preparing the catalyst and a method for treating exhaust gases containing nitrogen oxides and/or organic halogen compounds using the catalyst are provided.The BET specific surface areas of the titanium oxide and the catalyst for treating exhaust gases are in the range of 85 to 250 m2/g and in the range of 50 to 200 m2/g respectively. The titanium oxide and the catalyst for treating exhaust gases have each a ratio in the range of 15 to 145%, the ratio of the intensity of the peak indicating an anatase crystal present in the range of 2θ=24.7° to 2θ=25.7° of powder X-ray diffraction thereof (Ia) to the intensity of the peak indicating an anatase crystal present in the range of 2θ=24.7° to 2θ=25.7° of powder X-ray diffraction of the standard sample comprising a mixture composed of 15% by mass of pure anatase-type titanium dioxide and 85% by mass of pure rutile-type titanium dioxide (Ib).
摘要翻译：一种用于处理废气的催化剂，其具有优异的耐久性和性能，用于除去氮氧化物和有机卤素化合物和低SO 2氧化速率，适用于制备催化剂的氧化钛和用于处理废气的方法提供了使用该催化剂的氮氧化物和/或有机卤素化合物。氧化钛和用于处理废气的催化剂的BET比表面积在85至250m 2 / g的范围内，在50至200m 2 / SUP> / g。用于处理废气的氧化钛和催化剂各自具有15至145％的范围，表示锐钛矿晶体的峰的强度在2θ= 24.7°至2θ= 25.7°的范围内其粉末X射线衍射（Ia）与表示锐钛矿晶体的峰强度呈现在标准样品的粉末X射线衍射的2θ= 24.7°至2θ= 25.7°的范围内，该标准样品包含由15％的纯锐钛矿型二氧化钛和85质量％的纯金红石型二氧化钛（Ib）。

7. 发明授权

US5523150A Metal-impregnated refractory product 失效
$Metal-impregnated refractory product$
标题翻译：金属浸渍耐火产品
公开(公告)号：US5523150A
公开(公告)日：1996-06-04
申请号：US134473
申请日：1993-10-08
申请人： Noriji Numata , Makoto Iiyama , Noboru Murakami , Motonobu Kobayashi , Haruyoshi Tanabe
发明人： Noriji Numata , Makoto Iiyama , Noboru Murakami , Motonobu Kobayashi , Haruyoshi Tanabe
IPC分类号： C04B38/06 , C04B41/51 , C04B41/88 , B32B5/00
CPC分类号： C04B41/009 , C04B38/065 , C04B41/5133 , C04B41/5144 , C04B41/88 , C04B2111/0087 , Y10T428/12486 , Y10T428/249957 , Y10T428/24997
摘要： A metal-impregnated refractory product of this invention has high slag attack, gas attack, and spalling resistances and is used in various types of molten metal treatment vessels. A material of refractory particles mainly consisting of MgO or Al.sub.2 O.sub.3 is formed and heated by a suitable method to obtain a porous material body containing at least 4 vol % of open pores. A metal or an alloy mainly consisting of at least one type of a metal selected from the group consisting of iron, chromium, and nickel is impregnated in the porous material body at a ratio of 25 vol % or more of the open pores. The metal is filled in pores present in a region from the surface to at least a predetermined depth. The metal-impregnated refractory product can withstand various high-temperature damages and can be stably used over a long time period.
摘要翻译：本发明的金属浸渍耐火产品具有高的炉渣侵蚀，气体侵蚀和抗剥落性能，并用于各种类型的熔融金属处理容器。通过合适的方法形成主要由MgO或Al 2 O 3组成的耐火材料的材料并加热，得到含有至少4体积％的开孔的多孔体。主要由至少一种选自铁，铬和镍的金属组成的金属或合金以比例为25体积％以上的开孔浸渍在多孔材料体中。金属填充在从表面到至少预定深度的区域中存在的孔中。金属浸渍的耐火产品可以承受各种高温损坏，并可长期稳定使用。

8. 发明授权

US5021227A Method of removing nitrogen oxides in exhaust gases from a diesel engine 失效
标题翻译：从柴油机排出废气中的氮氧化物的方法
公开(公告)号：US5021227A
公开(公告)日：1991-06-04
申请号：US474274
申请日：1990-02-02
申请人： Motonobu Kobayashi , Futoru Kinoshita , Mitsuharu Hagi , Akira Inoue , Terushige Uno
发明人： Motonobu Kobayashi , Futoru Kinoshita , Mitsuharu Hagi , Akira Inoue , Terushige Uno
IPC分类号： B01D53/94 , F01N3/08 , F01N3/20 , F01N9/00 , F01N13/02 , F02B3/06 , F02B37/02
CPC分类号： F02B37/02 , B01D53/9409 , B01D53/9431 , B01D53/9495 , F01N13/0097 , F01N3/08 , F01N3/208 , F01N2610/02 , F01N2900/08 , F02B3/06 , Y02T10/144 , Y02T10/24
摘要： The present invention concerns a method of removing nitrogen oxides in exhaust gases from a diesel engine by using a catalyst in a reacter under the presence of ammonia, wherein a humidity of in-take air as a specific factor and one or more of engine power, fuel consumption amount of engine, temperature of engine in-take air and exhaust gas temperature as selective factors are measured respectively as the measuring factors and the flow rate of ammonia is controlled based on measured values and ammonia is supplied to an exhaust gas flow channel from the engine to the reactor.

9. 发明授权

US6068824A Adsorbent for nitrogen oxides and method for removal of nitrogen oxides by use thereof 失效
标题翻译：用于氮氧化物的吸附剂和使用它们去除氮氧化物的方法
公开(公告)号：US6068824A
公开(公告)日：2000-05-30
申请号：US738422
申请日：1996-10-25
申请人： Futoru Kinoshita , Shinyuki Masaki , Hisao Kondo , Motonobu Kobayashi
发明人： Futoru Kinoshita , Shinyuki Masaki , Hisao Kondo , Motonobu Kobayashi
IPC分类号： B01D53/02 , B01D53/86 , B01D53/94 , B01J20/02 , B01J23/38 , B01J23/54 , B01J37/03 , B01D59/26
CPC分类号： B01D53/9481 , B01D53/02 , B01D53/8628 , B01J20/02 , B01J20/0225 , B01J20/0233 , B01J20/0277 , B01J20/0281 , B01J20/0288 , B01J20/0296 , B01J20/06 , B01J20/10 , B01J20/18 , B01J20/223 , B01J23/38 , B01J23/54 , B01J37/031 , B01J37/033
摘要： This invention discloses an adsorbent ideal or the removal of nitrogen oxides (NO.sub.x : nitrogen monoxide and nitrogen dioxide), particularly nitrogen dioxide, from an exhaust gas containing the nitrogen oxides at low concentrations and a method for efficient removal of nitrogen oxides, particularly nitrogen dioxide, from an exhaust gas containing the nitrogen oxides at low concentrations by the use of the adsorbent. The adsorbent either comprises at least one noble metal selected from the group consisting of Pt, Au, Ru, Rh, and Pd and/or a compound thereof supported on a carrier or comprises the noble metal component and an oxide of at least one heavy metal selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and Pb, which may be supported on the carrier, if necessary.
摘要翻译：本发明公开了一种从含有低浓度氮氧化物的废气中理想或去除氮氧化物（NOx：一氧化氮和二氧化氮），特别是二氧化氮的吸附剂，以及有效去除氮氧化物，特别是二氧化氮的方法，通过使用吸附剂从含有低浓度的氮氧化物的排气中排出。所述吸附剂包含至少一种选自Pt，Au，Ru，Rh和Pd的贵金属和/或其负载在载体上的化合物，或包含贵金属组分和至少一种重金属的氧化物选自Mn，Fe，Co，Ni，Cu，Zn和Pb，如果需要，其可以负载在载体上。

10. 发明授权

US5550096A Catalyst for purifying nitrogen oxides from exhaust and waste gases 失效
标题翻译：从废气和废气中净化氮氧化物的催化剂
公开(公告)号：US5550096A
公开(公告)日：1996-08-27
申请号：US385896
申请日：1995-02-09
申请人： Akira Inoue , Motonobu Kobayashi , Tetsuji Ono
发明人： Akira Inoue , Motonobu Kobayashi , Tetsuji Ono
IPC分类号： B01D53/94 , B01J27/02 , B01J27/053
CPC分类号： B01J27/02 , B01D53/9418 , B01D2251/2062 , B01D2255/2065 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2255/30 , B01D2255/9207
摘要： A catalyst for the purification of an exhaust gas by the removal, through selective reduction, of nitrogen oxides present in the exhaust gas, which comprises (A) 80 to 95% by weight of a sulfur oxide-containing catalytic oxide obtained by thermally treating at least one hydrous oxide compound selected from the group consisting of binary hydrous oxide compound of titanium and silicon, binary hydrous oxide compound of titanium and zirconium and ternary hydrous oxide compound of titanium, zirconium and silicon in the presence of at least one sulfur compound selected from the group consisting of sulfuric acid and ammonium sulfate, (B) 0 to 5% by weight of a catalytic oxide comprising vanadium oxide, (C) 1 to 15% by weight of a catlytic oxide comprising the oxide of at least one metal selected form the group consisitng of tungsten, molybdenum, tin and cerium.
摘要翻译：通过选择性还原除去存在于废气中的氮氧化物来净化废气的催化剂，其包含（A）80至95重量％的通过在至少一种选自钛和硅的二元水合氧化物化合物，钛和锆的二元水合氧化物化合物和钛，锆和硅的三元含水氧化物化合物的水合氧化物化合物在至少一种硫化合物的存在下，选自由硫酸和硫酸铵组成的组，（B）0至5重量％的包含氧化钒的催化氧化物，（C）1至15重量％的包含至少一种金属选择形式的氧化物的电解氧化物该组由钨，钼，锡和铈组成。

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