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1. 发明授权

US06544478B1 QCM sensor 失效
标题翻译： QCM传感器
公开(公告)号：US06544478B1
公开(公告)日：2003-04-08
申请号：US09341465
申请日：1999-07-12
申请人： Noboru Oyama , Tetsu Tatsuma , Yoshihito Watanabe , Osamu Hatozaki , Kaoru Kitakizaki , Masanori Haba , Takayuki Noguchi
发明人： Noboru Oyama , Tetsu Tatsuma , Yoshihito Watanabe , Osamu Hatozaki , Kaoru Kitakizaki , Masanori Haba , Takayuki Noguchi
IPC分类号： G01N2700
CPC分类号： G01N29/036 , G01G3/13 , G01N5/02 , G01N29/022 , G01N2291/014 , G01N2291/018 , G01N2291/0215 , G01N2291/0224 , G01N2291/0256 , G01N2291/0426 , G01N2291/106
摘要： A QCM sensor including a sensor device, the sensor device having a crystal substrate, on both of front and rear surfaces of which a pair of electrodes are disposed so as to oppose with each other and the QCM sensor detecting and quantitatively analyzing components of a sample from either a variation in a fundamental resonant frequency or a variation in an impedance when a surface of one of the pair of electrodes is immersed into either a sample gas or a sample solution. The sensor device is arranged in a multi-channel structure such that four mutually opposing electrodes (11A through 14A, 12B through 14B) are disposed on both front and rear surfaces of the crystal substrate 10, each electrode being arranged to enable a fixation of a receptor which is different for each component of a sample to be detected and quantitatively analyzed, whereby the QCM sensor detects and quantitatively analyzes once the components of one sample different for different electrodes.
摘要翻译：一种QCM传感器，包括传感器装置，传感器装置具有晶体基板，其前表面和后表面上设置有一对电极以彼此相对，并且QCM传感器检测和定量分析样品的组分从基本共振频率的变化或当一对电极中的一个的表面浸入样品气体或样品溶液中时的阻抗变化。传感器装置布置成多通道结构，使得四个相互对置的电极（11A至14A，12B至14B）设置在晶体基板10的前表面和后表面上，每个电极被布置成能够固定受体，其对于待检测和定量分析的样品的每个组分不同，由此QCM传感器检测并定量分析一次样品的不同电极的组分。

2. 发明申请

US20100027195A1 LITHIUM ION CAPACITOR 有权
标题翻译：锂离子电容器
公开(公告)号：US20100027195A1
公开(公告)日：2010-02-04
申请号：US12093528
申请日：2006-11-13
申请人： Hiromoto Taguchi , Nobuo Ando , Hideki Shibuya , Shinichi Tasaki , Risa Miyagawa , Yukinori Hato , Osamu Hatozaki
发明人： Hiromoto Taguchi , Nobuo Ando , Hideki Shibuya , Shinichi Tasaki , Risa Miyagawa , Yukinori Hato , Osamu Hatozaki
IPC分类号： H01G9/028
CPC分类号： H01M10/0525 , H01G11/06 , H01G11/12 , H01G11/20 , H01G11/32 , H01G11/50 , H01G11/62 , H01G11/70 , H01M4/13 , H01M4/661 , H01M4/70 , H01M10/0413 , H01M10/0445 , H01M10/0585 , H01M12/005 , H01M2010/4292 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A lithium ion capacitor includes a positive electrode made of a material capable of reversibly doping and dedoping lithium ions and/or anions; a negative electrode made of a material capable of reversibly doping and dedoping lithium ions; and an electrolytic solution made of an aprotonic organic solvent electrolyte solution of a lithium salt. When the negative electrode and/or positive electrode and a lithium ion supply source are electrochemically brought into contact, lithium ions are doped in a negative electrode and/or positive electrode. A positive electrode potential after the positive electrode and negative electrode are short-circuited is 2.0 V (vs. Li/Li+) or less. The positive electrode and/or negative electrode has a current collector made of a metal foil that has many holes that penetrate through both sides and have an average diameter of inscribed circles of the through-holes of 100 μm or less.
摘要翻译：锂离子电容器包括由能够可逆地掺杂和去掺杂锂离子和/或阴离子的材料制成的正极; 由能够可逆地掺杂和去掺杂锂离子的材料制成的负极; 以及由锂盐的非质子有机溶剂电解质溶液制成的电解液。当负电极和/或正电极和锂离子供应源电化学接触时，锂离子被掺杂在负电极和/或正电极中。正极和负极短路后的正极电位为2.0V（相对于Li / Li +）以下。正极和/或负极具有由金属箔构成的集电体，该集电体具有穿过两侧的许多孔，并且通孔的内接圆的平均直径为100μm以下。

3. 发明申请

US20090023066A1 NEGATIVE ELECTRODE ACTIVE MATERIAL FOR CHARGING DEVICE 有权
标题翻译：用于充电装置的负极电极活性材料
公开(公告)号：US20090023066A1
公开(公告)日：2009-01-22
申请号：US11911630
申请日：2006-04-25
申请人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
发明人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M4/00 , H01M4/58
CPC分类号： H01M10/0525 , C01B32/00 , H01G9/038 , H01G9/155 , H01G11/24 , H01G11/42 , H01G11/50 , H01M4/587 , H01M10/0566 , H01M2004/021 , H01M2004/027 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： To present a carbon material which provides an electrical storage device not only ensuring a high energy density but also realizing a high output and an excellent low temperature performance.A negative electrode active material for an electrical storage device employing an aprotic organic solvent electrolyte solution containing a lithium salt as an electrolytes characterized in that it is made of a carbon material having a specific surface area of from 0.01 to 50 m2/g and a total mesopore volume of from 0.005 to 1.0 cc/g, wherein volumes of mesopores having pore diameters of from 100 to 400 Å occupy at least 25% of the total mesopore volume.
摘要翻译：提供一种提供蓄电装置的碳材料，不仅确保高能量密度，而且实现高输出和优异的低温性能。一种使用含有锂盐作为电解质的非质子性有机溶剂电解质溶液的蓄电装置用负极活性物质，其特征在于，其比表面积为0.01〜50m2 / g，总计为介孔体积为0.005至1.0cc / g，其中孔径为100至400的介孔的体积占总介孔体积的至少25％。

4. 发明授权

US08310811B2 Positive electrode active material for lithium ion electric storage device, and lithium ion electric storage device using the same 有权
标题翻译：锂离子蓄电装置用正极活性物质及使用其的锂离子蓄电装置
公开(公告)号：US08310811B2
公开(公告)日：2012-11-13
申请号：US12623106
申请日：2009-11-20
申请人： Tsutomu Fujii , Osamu Hatozaki
发明人： Tsutomu Fujii , Osamu Hatozaki
IPC分类号： H01G9/00 , H01M4/88
CPC分类号： H01M4/587 , H01M10/052 , H01M10/0569
摘要： [Problem] The present invention aims to enhance a characteristic of a lithium ion electric storage device upon charging or discharging with high load, and increasing a working temperature range thereof.[Means for Solving Problem] In a positive electrode active material used for a lithium ion electric storage device, the BET specific surface area is 1500 m2/g or more and 3000 m2/g or less, the ratio A of the pore volume within the range of the pore diameter of 0.6 nm or more and less than 1 nm to the pore volume within the range of the pore diameter of 0.6 nm or more and 200 nm or less in the active material satisfies 0≦A≦0.80, and the ratio B of the active material of the pore volume within the range of the pore diameter of 1 nm or more and 6 nm or less to the pore volume within the range of the pore diameter of 0.6 nm or more and 200 nm or less in the active material satisfies 0.20≦B≦1.0. By virtue of this structure, the lithium ion electric storage device can be provided that is excellent in the charging/discharging characteristic when it is given a high load, and that can satisfactorily operate even under an environment of −30° C.
摘要翻译：本发明旨在提高锂离子蓄电装置在高负荷充放电时的特性，提高其工作温度范围。解决问题的手段在锂离子蓄电装置的正极活性物质中，BET比表面积为1500m 2 / g以上3000m 2 / g以下，在活性物质的孔径为0.6nm以上且200nm以下的范围内的孔径为0.6nm以上且小于1nm的孔径的范围满足0＆lt; nlE; A＆nlE; 0.80， B的孔体积的活性物质在孔径为1nm以上且6nm以下的范围内的孔体积在活性物质的孔径为0.6nm以上且200nm以下的范围内材料满足0.20＆nlE; B＆nlE; 1.0。通过这样的结构，能够提供充电/放电特性优异的锂离子蓄电装置，即使在-30℃的环境下也能令人满意地进行充电。

5. 发明授权

US08203826B2 Lithium ion capacitor 有权
标题翻译：锂离子电容器
公开(公告)号：US08203826B2
公开(公告)日：2012-06-19
申请号：US12090461
申请日：2006-12-07
申请人： Kohei Matsui , Atsuro Shirakami , Nobuo Ando , Shinichi Tasaki , Risa Miyagawa , Osamu Hatozaki , Yukinori Hato
发明人： Kohei Matsui , Atsuro Shirakami , Nobuo Ando , Shinichi Tasaki , Risa Miyagawa , Osamu Hatozaki , Yukinori Hato
IPC分类号： H01G9/00
CPC分类号： H01G9/058 , H01G9/038 , H01G9/155 , H01G11/06 , Y02E60/13 , Y02T10/7022
摘要： A lithium ion capacitor includes a positive electrode, a negative electrode, and a non-protonic organic solvent electrolytic solution of a lithium salt. A positive electrode active material is a material capable of reversibly doping a lithium ion and/or an anion. A negative electrode active material is a material capable of reversibly doping a lithium ion. The lithium ion is doped in advance to either one or both of the negative electrode and the positive electrode so that a positive electrode potential after the positive electrode and the negative electrode are short-circuited is 2.0 V (relative to Li/Li+) or less when capacitance per unit weight of the positive electrode is C+(F/g), weight of the positive electrode active material is W+(g), capacitance per unit weight of negative electrode is C−(F/g), and weight of the negative electrode active material is W−(g), a value of (C−×W−)/(C+×W+) is 5 or more.
摘要翻译：锂离子电容器包括正极，负极和锂盐的非质子有机溶剂电解液。正极活性物质是能够可逆地掺杂锂离子和/或阴离子的材料。负极活性物质是能够可逆地掺杂锂离子的材料。锂离子预先掺杂到负极和正极中的一个或两个，使正极和负极短路后的正极电位为2.0V（相对于Li / Li +）以下当正极单位重量的电容为C +（F / g）时，正极活性物质的重量为W +（g），负极单位重量的电容为C-（F / g），重量为负极活性物质为W-（g），（C-×W-）/（C +×W +）的值为5以上。

6. 发明授权

US07817403B2 Lithium ion capacitor 有权
标题翻译：锂离子电容器
公开(公告)号：US07817403B2
公开(公告)日：2010-10-19
申请号：US12063696
申请日：2006-07-28
申请人： Shinichi Tasaki , Mitsuru Nagai , Hiromoto Taguchi , Kohei Matsui , Risa Takahata , Kenji Kojima , Nobuo Ando , Yukinori Hato , Osamu Hatozaki
发明人： Shinichi Tasaki , Mitsuru Nagai , Hiromoto Taguchi , Kohei Matsui , Risa Takahata , Kenji Kojima , Nobuo Ando , Yukinori Hato , Osamu Hatozaki
IPC分类号： H01G9/02
CPC分类号： H01G11/70 , H01G11/06 , H01G11/12 , H01G11/24 , H01G11/26 , H01G11/34 , H01G11/52 , Y02E60/13 , Y02T10/7022
摘要： A lithium ion capacitor having high energy density, high output density, high capacity and high safety includes a positive electrode made of a material capable of being reversibly doped with lithium ions and/or anions, a negative electrode made of a material capable of being reversively doped with lithium ions, and an aprotic organic solution of a lithium salt as an electrolytic solution. Wherein, the positive electrode and the negative electrode are laminated or wound with a separator interposed between them, the area of the positive electrode is smaller than the area of the negative electrode. The face of the positive electrode is substantially covered by the face of the negative electrode when they are laminated or wound.
摘要翻译：具有高能量密度，高输出密度，高容量和高安全性的锂离子电容器包括由能够可逆地掺杂锂离子和/或阴离子的材料制成的正极，由能够逆变的材料制成的负极掺杂锂离子，以及作为电解液的锂盐的非质子有机溶液。其中，正极和负极通过夹在它们之间的隔膜层叠或缠绕，正极的面积小于负极的面积。当正极的表面层压或缠绕时，正极的表面基本上被负极的表面覆盖。

7. 发明申请

US20100255356A1 Electric storage device and its production method 有权
标题翻译：蓄电装置及其制作方法
公开(公告)号：US20100255356A1
公开(公告)日：2010-10-07
申请号：US12662007
申请日：2010-03-26
申请人： Tsutomu Fujii , Osamu Hatozaki
发明人： Tsutomu Fujii , Osamu Hatozaki
IPC分类号： H01M6/10 , H01M6/00 , H01G9/00
CPC分类号： H01M10/0525 , H01G9/016 , H01G9/038 , H01G9/058 , H01G9/155 , H01G11/06 , H01G11/12 , H01G11/24 , H01G11/62 , H01G11/70 , H01M4/133 , H01M4/742 , H01M4/745 , H01M12/005 , H01M2004/021 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108
摘要： When an electrode material having a weight-average mesopore/macropore specific surface area within a specific range is used, there arises an expansion of a cell caused by the generation of decomposed gas from a component of electrolyte solution during the pre-doping process of lithium ions. A potential drop upon the pre-doping process is adjusted so as to reduce or suppress the expansion of the cell. Specifically, since the pre-doping speed is increased, the negative electrode can speedily reach the potential by which an SEI component made of lithium alkyl carbonate can be produced on the surface of the negative electrode. Consequently, the absolute amount of the gas produced by the decomposition of the electrolyte solution can be reduced, whereby the expansion of the electric storage device can be reduced.
摘要翻译：当使用具有在特定范围内的重均分子中孔/大孔比表面积的电极材料时，在锂的预掺杂过程中会产生由电解质溶液的分解产生分解气体引起的电池的膨胀离子。调整预掺杂工艺的电位降低，以便减小或抑制电池的膨胀。具体地说，由于预掺杂速度增加，所以负极可以快速地达到在负极表面上可以产生由碳酸烷基酯制成的SEI组分的电位。因此，可以降低由电解液分解产生的气体的绝对量，从而可以减少蓄电装置的膨胀。

8. 发明授权

US08974947B2 Electric storage device and its production method 有权
标题翻译：蓄电装置及其制作方法
公开(公告)号：US08974947B2
公开(公告)日：2015-03-10
申请号：US12662007
申请日：2010-03-26
申请人： Tsutomu Fujii , Osamu Hatozaki
发明人： Tsutomu Fujii , Osamu Hatozaki
IPC分类号： H01M6/10 , H01M6/00 , H01G9/00 , H01M10/0525 , H01G9/008 , H01G9/022 , H01G9/04 , H01G11/06 , H01G11/12 , H01G11/24 , H01G11/62 , H01G11/70 , H01M4/133 , H01M4/74 , H01M12/00 , H01M4/02
CPC分类号： H01M10/0525 , H01G9/016 , H01G9/038 , H01G9/058 , H01G9/155 , H01G11/06 , H01G11/12 , H01G11/24 , H01G11/62 , H01G11/70 , H01M4/133 , H01M4/742 , H01M4/745 , H01M12/005 , H01M2004/021 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10T29/49108
摘要： When an electrode material having a weight-average mesopore/macropore specific surface area within a specific range is used, there arises an expansion of a cell caused by the generation of decomposed gas from a component of electrolyte solution during the pre-doping process of lithium ions. A potential drop upon the pre-doping process is adjusted so as to reduce or suppress the expansion of the cell. Specifically, since the pre-doping speed is increased, the negative electrode can speedily reach the potential by which an SEI component made of lithium alkyl carbonate can be produced on the surface of the negative electrode. Consequently, the absolute amount of the gas produced by the decomposition of the electrolyte solution can be reduced, whereby the expansion of the electric storage device can be reduced.
摘要翻译：当使用具有在特定范围内的重均分子中孔/大孔比表面积的电极材料时，在锂的预掺杂过程中会产生由电解质溶液的分解产生分解气体引起的电池的膨胀离子。调整预掺杂工艺的电位降低，以便减小或抑制电池的膨胀。具体地说，由于预掺杂速度增加，所以负极可以快速地达到在负极表面上可以产生由碳酸烷基酯制成的SEI组分的电位。因此，可以降低由电解液分解产生的气体的绝对量，从而可以减少蓄电装置的膨胀。

9. 发明申请

US20090097189A1 LITHIUM ION CAPACITOR 有权
标题翻译：锂离子电容器
公开(公告)号：US20090097189A1
公开(公告)日：2009-04-16
申请号：US12063696
申请日：2006-07-28
申请人： Shinichi Tasaki , Mitsuru Nagai , Hiromoto Taguchi , Kohei Matsui , Risa Takahata , Kenji Kojima , Nobuo Ando , Yukinori Hato , Osamu Hatozaki
发明人： Shinichi Tasaki , Mitsuru Nagai , Hiromoto Taguchi , Kohei Matsui , Risa Takahata , Kenji Kojima , Nobuo Ando , Yukinori Hato , Osamu Hatozaki
IPC分类号： H01G9/048
CPC分类号： H01G11/70 , H01G11/06 , H01G11/12 , H01G11/24 , H01G11/26 , H01G11/34 , H01G11/52 , Y02E60/13 , Y02T10/7022
摘要： A lithium ion capacitor having high energy density, high output density, high capacity and high safety is provided.A lithium ion capacitor comprising a positive electrode 1 made of a material capable of being reversibly doped with lithium ions and/or anions, a negative electrode 2 made of a material capable of being reversively doped with lithium ions, and an aprotic organic solution of a lithium salt as an electrolytic solution, wherein the positive electrode 1 and the negative electrode 2 are laminated or wound with a separator interposed between them, the area of the positive electrode 1 is smaller than the area of the negative electrode 2, and the face of the positive electrode 1 is substantially covered by the face of the negative electrode 2 when they are laminated or wound.
摘要翻译：提供了具有高能量密度，高输出密度，高容量和高安全性的锂离子电容器。一种锂离子电容器，其包括由能够可逆地掺杂锂离子和/或阴离子的材料制成的正极1，由能够被锂离子反向掺杂的材料制成的负极2和非极性有机溶液锂盐作为电解液，其中正极1和负极2以介于它们之间的隔膜层叠或缠绕，正极1的面积小于负极2的面积，面积正极1在层叠或卷绕时基本上被负极2的表面覆盖。

10. 发明授权

US08142930B2 Negative electrode active material for charging device 有权
标题翻译：负极活性物质用于充电装置
公开(公告)号：US08142930B2
公开(公告)日：2012-03-27
申请号：US11911630
申请日：2006-04-25
申请人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
发明人： Kenji Kojima , Nobuo Ando , Tsutomu Fujii , Hiromoto Taguchi , Osamu Hatozaki , Yukinori Hato , Chisato Marumo
IPC分类号： H01M4/13 , C01B31/04
CPC分类号： H01M10/0525 , C01B32/00 , H01G9/038 , H01G9/155 , H01G11/24 , H01G11/42 , H01G11/50 , H01M4/587 , H01M10/0566 , H01M2004/021 , H01M2004/027 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： To present a carbon material which provides an electrical storage device not only ensuring a high energy density but also realizing a high output and an excellent low temperature performance.A negative electrode active material for an electrical storage device employing an aprotic organic solvent electrolyte solution containing a lithium salt as an electrolytes characterized in that it is made of a carbon material having a specific surface area of from 0.01 to 50 m2/g and a total mesopore volume of from 0.005 to 1.0 cc/g, wherein volumes of mesopores having pore diameters of from 100 to 400 Å occupy at least 25% of the total mesopore volume.
摘要翻译：提供一种提供蓄电装置的碳材料，不仅确保高能量密度，而且实现高输出和优异的低温性能。一种使用含有锂盐作为电解质的非质子性有机溶剂电解质溶液的蓄电装置用负极活性物质，其特征在于，其比表面积为0.01〜50m2 / g，总计为介孔体积为0.005至1.0cc / g，其中孔径为100至400的介孔的体积占总介孔体积的至少25％。

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