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1. 发明专利

JPS618854A Cell and its manufacturing method 失效
标题翻译：细胞及其制造方法
公开(公告)号：JPS618854A
公开(公告)日：1986-01-16
申请号：JP12884384
申请日：1984-06-22
申请人： Nippon Telegr & Teleph Corp
发明人： EBISAWA FUMIHIRO , NIWA OSAMU , TABEI HISAO
IPC分类号： H01M2/16 , H01M6/18 , H01M10/05 , H01M10/058
CPC分类号： H01M10/05 , H01M6/181
摘要： PURPOSE:To make it possible to obtain the thin membrane type solid cell of its easy maintenance by making the separator of composite electrolytic polymer membrane formed on the organic conductive film of at least one electrode of the cell. CONSTITUTION:At least one electrode of a cell is made of organic conductive film 2, and the separator of the cell is made of composite electrolyte polymer membrane 3. And, forming the electrode composed of the organic conductive film 2 on the substrate 1, and further, laminating the general purpose high molecular membrane on the organic conductive film electrode and also, performing its electrolytic oxidation, the cell is manufactured by forming the separator 3 of composite electrolytic polymer membrane which is made of general purpose high molecular membrane of composite hetrocyclic group conductive high molecule. The materisl of said organic conductive film and hetrocyclic group high molecule, for example, pyrrole group high molecule such as n-methyl polypyrrole and polypyrrole etc., thiophene group high molecule such as polythiophene etc., furan group high molecule etc. such as polyfuran, or copolymer of these materials are used.
摘要翻译：目的：通过在电池的至少一个电极的有机导电膜上形成复合电解聚合物膜的隔膜，可以获得容易维护的薄膜型固体电池。结构：电池的至少一个电极由有机导电膜2制成，电池的隔膜由复合电解质聚合物膜3制成。并且，在基板1上形成由有机导电膜2构成的电极和另外，将通用高分子膜层叠在有机导电膜电极上，并进行电解氧化，由复合电解质聚合物膜形成隔膜3制成复合电解聚合物膜，复合电解聚合物膜是由复合环状基团的通用高分子膜导电高分子。所述有机导电膜和hetrocyclic组高分子的材料，例如吡咯基高分子如正甲基聚吡咯和聚吡咯等，噻吩基高分子如聚噻吩等，呋喃基高分子等，如呋喃，或这些材料的共聚物。

2. 发明专利

JPS6143149A Polymerizable diacetylene compound and its polymer 失效
标题翻译：可聚合的二乙烯基化合物及其聚合物
公开(公告)号：JPS6143149A
公开(公告)日：1986-03-01
申请号：JP16439484
申请日：1984-08-06
申请人： Nippon Telegr & Teleph Corp
发明人： KURIHARA TAKASHI , FUJIKI MICHIYA , EBISAWA FUMIHIRO , TABEI HISAO
IPC分类号： C07D221/12 , C07C67/00 , C07C231/00 , C07C233/05 , C07C233/11 , C07C233/45 , C07C239/00 , C07C271/08 , C07C301/00 , C07C307/02 , C07C309/63 , C07D213/26 , C07D213/28 , C07D213/30 , C08F38/00 , C08F38/02
摘要： NEW MATERIAL:A compound shown by the formula I (A is aromatic ring, or heterocyclic ring; H is hydrogen bond-forming atom group or polar atom group, for example, -NHCOO-, -CONH-, OSO
2 -, etc.; Z is substituted benzene, or substituted alkyl; n is 1W4, or ≥12).
EXAMPLE: 1,3-Pentadiin-1-(p-methoxyphenyl)-5-(phenylurethane).
USE: Since strong mutual action between a side-chain aromatic ring and a conjugated main chain may exist, high mobility change in electrical conductivity, improvement in doping characteristics, third-order and second-order nonlinear type optical effect are expected, and the titled compound is useful as an organic electronic material stock.
PREPARATION: p-Iodoanisole is reacted with trimethylsilylacetylene, and treated with an alkali to give a compound shown by the formula II, which is brominated, and reacted with propargyl alcohol to give a compound shown by the formula III, which is reacted with phenyl isocyanate, to give the example compound shown by the formula IV.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：式Ⅰ化合物（A为芳香环或杂环; H为氢键形成原子团或极性原子团，例如-NHCOO - ， - CONH - ，OSO2-等） Z是取代的苯或取代的烷基; n是1-4或= 12）。实施例：1,3-戊二-1-（对甲氧基苯基）-5-（苯基氨基甲酸酯）。用途：由于可能存在侧链芳族环和共轭主链之间的强相互作用，预期导电性的高迁移率变化，掺杂特性的改善，三阶和二阶非线性型光学效应，标题化合物可用作有机电子材料原料。制备：将对碘苯甲醚与三甲基甲硅烷基乙炔反应，并用碱处理，得到式II化合物，其被溴化，并与炔丙醇反应，得到式III所示的化合物，其与苯基异氰酸酯，得到式IV所示的实例化合物。

3. 发明专利

JPS618855A Cell and its manufacture 失效
标题翻译：细胞及其制造
公开(公告)号：JPS618855A
公开(公告)日：1986-01-16
申请号：JP12884484
申请日：1984-06-22
申请人： Nippon Telegr & Teleph Corp
发明人： TABEI HISAO , EBISAWA FUMIHIRO , KURIHARA TAKASHI
IPC分类号： H01M2/16 , H01M4/60 , H01M10/05 , H01M10/058
CPC分类号： H01M4/137 , H01M4/60 , H01M10/05
摘要： PURPOSE:To obtain a thin film solid cell easy and convenient for maintenance, by utilizing the difference of charge carrier holding ability caused by lamination of conductive films. CONSTITUTION:Electrode 1 and 5 interpose an organic conductive film between themselves, which is made of a laminate forming the density gradient of charge carrier by lamination of multiple organic conductive films 2 and 3 having different charge carrier density. Furthermore, a heterocyclic macromolecular organic conductive film is laminated on said organic conductive film by electrolytic oxidation and the charge carrier density gradient is formed by impressing backward voltage and thus, a cell is formed. Or, a polymer coating film is formed on said organic conductive film and furthermore, a heterocyclic macromolecular organic conductive film is laminated on this polymer coating film by electrolytic oxidation and the charge carrier density gradient is formed by impressing backward voltage and thus, a cell is formed. As said organic conductive film material, for example, pyrrole system polymer such as polypyrrole, n-methylpolypyrrole, etc., thiophene system polymer such as polythiophene or the like, and furan system polymer such as polyfuran or the like, and so on are used.
摘要翻译：目的：通过利用导电膜层压引起的载流子保持能力的差异，获得便于维护的薄膜固体电池。构成：电极1和5通过层叠具有不同电荷载流子密度的多个有机导电膜2和3，在它们之间插入有机导电膜，该有机导电膜由层压形成电荷载流子密度梯度的层压体构成。此外，通过电解氧化将杂环高分子有机导电膜层叠在所述有机导电膜上，并通过施加反向电压形成电荷载流子密度梯度，从而形成电池。或者，在所述有机导电膜上形成聚合物涂膜，此外，通过电解氧化在该聚合物涂膜上层叠杂环高分子有机导电膜，通过施加反向电压形成电荷载流子浓度梯度，因此，电池为形成。作为所述有机导电膜材料，可以使用例如聚吡咯，正甲基聚吡咯等吡咯系聚合物，聚噻吩等噻吩系聚合物，聚呋喃等呋喃系聚合物等。。

4. 发明专利

JPS59176301A Organic semiconductive polymer and its production 失效
标题翻译：有机半导体聚合物及其生产
公开(公告)号：JPS59176301A
公开(公告)日：1984-10-05
申请号：JP5051683
申请日：1983-03-28
申请人： Nippon Telegr & Teleph Corp
发明人： KURIHARA TAKASHI , EBISAWA FUMIHIRO , TABEI HISAO , FUJIKI MICHIYA
IPC分类号： C08F8/00 , C08F8/04 , C08F36/00 , C08F36/22 , C08F38/00 , H01B1/12
摘要： PURPOSE: To obtain an organic semiconductive polymer having a polyene structure and being excellent in electric conductivity, photoconductive properties, etc., and suitable for use in photo-electric conversion elements, by hydrogeneting the main chain of a specified polydiacetylene with a hydrogenative reducing agent.
CONSTITUTION: The purpose organic semiconductive polymer having repeating units of formula V is obtained by hydrogenating a polymer having repeating units of formula I or II (wherein R is a group of formula III or IV) with a hydrogenative reducing agent. The hydrogenative reducing agents which can be suitably used include, for example, (n-C
4 H
9 )
3 SnH, Raney nickel, AlH(i-C
4 H
9 )
2 , Lindlar catalyst and Ti(CO)
2 (C
2 H
5 )
2 . In this way, the main chain of the polydiacetylene can be converted into a polyene structure, which results in increased electric conductivity and improved photoconductive properties of the polymer.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了获得具有多烯结构并具有优异导电性，光电导性等的有机半导体聚合物，并且适用于光电转换元件，通过将氢化还原剂氢化特定聚二乙炔的主链。构成：具有式V重复单元的有机半导体聚合物的目的是通过用氢还原剂氢化具有式I或II重复单元的聚合物（其中R是式III或IV的基团）。可适当使用的还原剂包括（例如）（n-C 4 H 9）3 Sn，阮内镍，AlH（i-C 4 H 9）2，Lindlar催化剂和Ti（CO）2（C 2 H 5）2）。以这种方式，聚二乙炔的主链可以转化为多烯结构，这导致聚合物的电导率增加和光导电性能的改善。

5. 发明专利

JPS61138624A Production of electrically conductive electrolytic polymer 失效
标题翻译：电导电聚合物的生产
公开(公告)号：JPS61138624A
公开(公告)日：1986-06-26
申请号：JP26133884
申请日：1984-12-10
申请人： Nippon Telegr & Teleph Corp
发明人： EBISAWA FUMIHIRO , TABEI HISAO
IPC分类号： C08G61/00 , C08G61/10
摘要： PURPOSE: To produce an electrolytic polymer thin film having high electrical conductivity and suitable as an antistatic film, etc. easily and economically, by the electrolytic oxidation of a polynucleus aromatic hydrocarbon compound in an electrolytic liquid containing a supporting electrolyte.
CONSTITUTION: The objective electrolytic polymer is produced by the electrolytic oxidation of a polynucleus aromatic hydrocarbon compound (e.g. biphenyl) in an electrolytic liquid (e.g. acetonitrile) containing preferably ≤0.5M/l of a supporting electrolyte (e.g. BF
4 N.BF
4 , etc.).
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过在含有支持电解质的电解液中电解氧化多核芳烃化合物，可以容易且经济地制造导电性高，适合作为抗静电膜等的电解质聚合物薄膜。构成：目标电解质聚合物通过在优选<= 0.5M / l的支持电解质（例如BF4N.BF4等）的电解液（例如乙腈）中电解氧化多核芳烃化合物（例如联苯）来生产。）。

6. 发明专利

JPS6160638A Organic nonlinear optical material 失效
标题翻译：有机非线性光学材料
公开(公告)号：JPS6160638A
公开(公告)日：1986-03-28
申请号：JP18331884
申请日：1984-08-31
申请人： Nippon Telegr & Teleph Corp
发明人： KURIHARA TAKASHI , FUJIKI MICHIYA , EBISAWA FUMIHIRO , TABEI HISAO
IPC分类号： C07D213/73 , C07C67/00 , C07C231/00 , C07C233/43 , C07D213/75 , G02F1/35 , G02F1/355 , G02F1/361
CPC分类号： G02F1/361
摘要： NEW MATERIAL:The compound of formula I (D is electron-donative aromatic or heterocyclic group; A is electron-accepting aromatic or heterocyclic group; Hb is atomic group forming hydrogen bond; R is alkyl; n is 0-4). EXAMPLE:1-[2-(N-stearoylamico)-4-(N,N-dimethylamino)phynyl]-2 [3-(Nsteraroy lamino)-4-(N,N-dimethylamino)phenyl]-2 (3-N-stearoyl-amino)-4-nitropheyl)ethyne. USE:An organic nonlinear optical material. It has high nonlinear optical constant, and excellent strength, chemical stability and processability. PREPARATION:The compound of formula I can be prepared by reacting the compound of formula II in dehydrated tetrahydrofuran containing triethylamine, in the presence of stearoyl chloride at room temperature.
摘要翻译：新材料：式Ⅰ化合物（D为给电子芳族或杂环基; A为受电子芳族或杂环基; Hb为原子团形成氢键; R为烷基; n为0-4）。实施例：1- [2-（N-硬脂酰基氨基）-4-（N，N-二甲基氨基）吩炔基] -2 [3-（Nsteraroy lamino）-4-（N，N-二甲基氨基）苯基] N-硬脂酰氨基）-4-硝基苯基）乙炔。使用：有机非线性光学材料。具有高非线性光学常数，优异的强度，化学稳定性和加工性。制备：式I化合物可以通过在室温下在硬脂酰氯存在下使式II化合物在含有三乙胺的脱水四氢呋喃中反应来制备。

7. 发明专利

JPS6127934A Polymerizable diacetylene compound and its polymer 失效
标题翻译：可聚合的二乙烯基化合物及其聚合物
公开(公告)号：JPS6127934A
公开(公告)日：1986-02-07
申请号：JP14608284
申请日：1984-07-16
申请人： Nippon Telegr & Teleph Corp
发明人： KURIHARA TAKASHI , FUJIKI MICHIYA , TABEI HISAO
IPC分类号： C07C33/30 , C07C27/00 , C07C67/00 , C07C231/00 , C07C233/01 , C07C233/07 , C07C233/09 , C07C233/15 , C07C233/43 , C07C233/65 , C07C239/00 , C07C271/28 , C07C271/44 , C07C275/48 , C07C275/54 , C07C301/00 , C07C307/02 , C07D213/04 , C08F38/00 , C08F38/02 , C09K9/02
摘要： NEW MATERIAL:The polymerizable diacetylene compound of formula (A is aromatic or heterocyclic group; H is atomic group forming hydrogen bond; L is ≥7C long-chain alkyl or liquid crystal group).
EXAMPLE: 1,3-Butadiyne-1,4-bis(o-stearoylanilide).
USE: Raw material of polymer for electronic material. A polymerizable diacetylene compound containing aromatic ring having arbitrary structure as the conjugated side chain substituent group can be synthesized, and its polymer is expected to exhibit unique electro-optical characteristics originated from the charge transfer action between main chains or between main chain and side chain.
PREPARATION: The exemplified compound can be prepared via 2-(o-aminophenyl) trimethylsilylacetylene (obtained by the reaction of o-iodoaniline with trimethylsilylacetylene), o-aminophenol acetylene, and 1,3-butadiyne-1,4-bis(o-aniline).
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：式（A为芳族或杂环基的可聚合乙炔基化合物; H为原子团形成氢键; L为> = 7C长链烷基或液晶基）。实施例：1,3-丁二炔-1,4-双（邻 - 硬脂酰苯胺）。用途：电子材料用聚合物原料。可以合成含有作为共轭侧链取代基的具有任意结构的芳环的可聚合的乙炔基化合物，其聚合物预期具有源自主链之间或主链和侧链之间的电荷转移作用的独特的电光特性。制备：示例性化合物可以通过2-（邻氨基苯基）三甲基甲硅烷基乙炔（通过邻碘苯胺与三甲基甲硅烷基乙炔的反应获得），邻氨基苯酚乙炔和1,3-丁二炔-1,4-双（邻 - 苯胺）。

8. 发明专利

JPS59126201A Manufacture of refractive index distribution type plastic light transmission body 失效
$Manufacture of refractive index distribution type plastic light transmission body$
标题翻译：折射率分布型塑料光传输体的制造
公开(公告)号：JPS59126201A
公开(公告)日：1984-07-20
申请号：JP104883
申请日：1983-01-10
申请人： Nippon Telegr & Teleph Corp
发明人： FUJIKI MICHIYA , TABEI HISAO
IPC分类号： G01B5/14 , G02B1/04
CPC分类号： G02B1/04
摘要： PURPOSE:To obtain a light transmission body with limited transmission loss by supplying a vinyl monomer to provide a low refractive index polymer and a vinyl monomer to provide a high refractive index polymer into a transparent reaction tube varying the vapor pressure ratio therebetween to be photopolymerized with ultraviolet rays irradiated from outside. CONSTITUTION:After a photopolymerization initiator and a thermal polymerization inhibitor are added thereto, for example, methyl methacrylate to provide a low refractive index polymer and stylene to provide a high refractive index polymer are put into a monomer container 3 in a polymerizer 9, fed to an ultraviolet ray tranmisivity reaction tube 1 from a pipe 5 passing through a hole of a light shield plate 7 and then, an ultraviolet rays 8 are irradiated thereinto outside the tube 1. As containers 3 and 1 are being rotated with a motor 6, the temperature within the apparatus 9 is raised gradually from the initial value of 40 deg.C to accomplish a polymerization. Initially, the methyl methacrylate with a low boiling point is evaporated dominantly and a steam rich in stylene with a high boiling point done later to perform a photopolymerization in the tube 1. After the completion of the polymerization, a polymerized rod is taken out, melted and drawn to obtain a small focusing element with a limited light loss.
摘要翻译：目的：为了通过供应乙烯基单体以提供低折射率聚合物和乙烯基单体来获得具有有限的传输损耗的透光体，以将高折射率聚合物提供到透明反应管中，改变其之间的蒸汽压比，以使其与从外部照射的紫外线。构成：在加入光聚合引发剂和热聚合抑制剂之后，例如将甲基丙烯酸甲酯提供低折射率聚合物和苯乙烯以提供高折射率聚合物放入聚合反应器9中的单体容器3中，来自通过遮光板7的孔的管5的紫外线透射性反应管1，然后将紫外线8照射到管1的外部。随着容器3和1与电动机6一起旋转，装置9内的温度从初始值40℃逐渐升高以完成聚合。最初，具有低沸点的甲基丙烯酸甲酯主要被蒸发，并且稍后进行富含高沸点的蒸汽的蒸汽在管1中进行光聚合。聚合完成后，取出聚合的棒，熔化并绘制以获得具有有限光损失的小聚焦元件。

9. 发明专利

JP2004219325A Electrochemical online type biosensor and its manufacturing method 有权
标题翻译：电化学在线型生物传感器及其制造方法
公开(公告)号：JP2004219325A
公开(公告)日：2004-08-05
申请号：JP2003008622
申请日：2003-01-16
申请人： Nippon Telegr & Teleph Corp , Ntt Advanced Technology Corp , エヌ・ティ・ティ・アドバンステクノロジ株式会社 , 日本電信電話株式会社
发明人： KURITA RIYOUJI , TABEI HISAO , NIWA OSAMU , HAYASHI KATSUYOSHI
IPC分类号： G01N33/483 , G01N27/28 , G01N27/327 , G01N27/416 , G01N37/00
摘要： PROBLEM TO BE SOLVED: To safely form a flow cell with satisfactory productivity without having to form thin-layer channels by etching or the like. SOLUTION: By joining an insulating substrate 1, in which thin-film electrodes are formed, to a polymer substrate 3 connected to both a tube 4 for introducing a sample and a tube 5 for discharging the sample with a perforated adhesive double-coated sheet 2, the flow cell having the thin-layer channels is constituted. By a capillary for sampling connected to the insulating substrate 1 or a microdialysis probe, a sample solution is introduced. The adhesive double-coated sheet 2 is perforated in the form of the desired channels at the formation of the flow cell. By sandwiching the perforated adhesive double coated sheet 2 between the insulating substrate 1 having the thin-film electrodes and the polymer substrate 3 for the formation of the flow cell, the flow cell is formed. COPYRIGHT: (C)2004,JPO&NCIPI
摘要翻译：要解决的问题：为了安全地形成具有令人满意的生产率的流动池，而不必通过蚀刻等形成薄层通道。解决方案：通过将形成有薄膜电极的绝缘基板1连接到与用于引入样品的管4连接的聚合物基板3和用于将穿孔粘合剂双重剥离的样品排出的管5，涂布片2构成具有薄层通道的流通池。通过连接到绝缘基板1或微透析探针的采样毛细管，引入样品溶液。在形成流动池时，粘合剂双层纸2以所需通道的形式穿孔。通过在具有薄膜电极的绝缘基板1和用于形成流动池的聚合物基板3之间夹持多孔粘合剂双面涂布片2，形成流动池。版权所有（C）2004，JPO＆NCIPI

10. 发明专利

JPS61141443A Pattern forming material and formation of pattern 失效
标题翻译：图案形成与形成
公开(公告)号：JPS61141443A
公开(公告)日：1986-06-28
申请号：JP26501684
申请日：1984-12-14
申请人： Nippon Telegr & Teleph Corp
发明人： FUJIKI MICHIYA , TABEI HISAO , IMAMURA SABURO , KURIHARA TAKASHI
IPC分类号： G03F7/20 , G03C1/00 , G03C1/72 , G03C1/735 , G03C5/00 , G03C5/08 , G03F7/038
CPC分类号： G03C1/735
摘要： PURPOSE:To obtain a pattern forming material capable of forming a conductive pattern good in dry etching resistance and high in resolution by using a specified phthalocyanine deriv. CONSTITUTION:The pattern forming material is a phthalocyanine deriv. represented by the formula, each of R1-R8 being a side chain or H, and M being H or metal ion. A pattern is formed by patternwise exposing it with electron beams, X-rays, UV rays, or the like and developing it to leave the exposed parts. Since the pattern is formed by utilizing that the chemical structure is changed by irradiation of radiation and the solubility is changed, swelling at the time of development can be avoided, resolution can be enhanced remarkably, and a submicron pattern can be formed even when a film is thick.
摘要翻译：目的：通过使用特定的酞菁衍生物，可获得能够形成耐干蚀刻性和分辨率高的导电图案的图案形成材料。构成：图案形成材料是酞菁衍生物。由式表示，R1-R8各自为侧链或H，M为H或金属离子。通过用电子束，X射线，紫外线等图案曝光形成图案，并将其显影以留下暴露部分。由于通过利用通过照射辐射改变化学结构并且改变溶解度来形成图案，因此可以避免显影时的溶胀，甚至可以形成亚微米图案，即使当膜很厚

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