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1. 发明专利

JP2011034055A Optical device and method for manufacturing the same 有权
标题翻译：光学装置及其制造方法
公开(公告)号：JP2011034055A
公开(公告)日：2011-02-17
申请号：JP2010069286
申请日：2010-03-25
申请人： Nippon Shokubai Co Ltd , Toyoda Gosei Co Ltd , Toyota Central R&D Labs Inc , 株式会社日本触媒 , 株式会社豊田中央研究所 , 豊田合成株式会社
发明人： OKITA AKIKO , INUI YUKITOSHI , TERADA KAZUHIRO , HAGA KENJI , TAJIRI KOZO , MAKINO TOMOMI , TAKAHASHI KUNIO , TSUCHIMORI MASAAKI , NAKAO JURI
IPC分类号： G02B6/12 , C08L63/00 , C08L83/06 , G02B6/13
摘要： PROBLEM TO BE SOLVED: To provide an optical device which does not deteriorate in an accelerated degradation test in which repetition is made between a high temperature and high humidity state and a low temperature state. SOLUTION: The optical device includes in the inside of a light transmittable housing 10: a shaft shaped core 30 which is obtained by self convergently photocuring a photosetting resin; and a clad 40 including an organosilsesquioxane, an epoxy resin and an oxetane resin. The epoxy resin and the oxetane resin are increasingly smaller in a curing shrinkage rate than an acryl resin when they are cured, and consequently a tensile stress hardly remains in the inside of the clad 40 which is a formed cured product. The epoxy resin, the oxetane resin and the organosilsesquioxane are high in heat resistance and small in hygroscopicity compared with the acryl resin having an ester bond and are not consequently swollen due to moisture even at a high temperature and high humidity. Furthermore, the light transmittable housing 10 is preferably formed from the epoxy resin and the oxetane resin. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种在高温高湿状态和低温状态之间重复的加速劣化试验中不劣化的光学装置。解决方案：光学装置包括在透光壳体10的内部：轴形芯30，其通过自会聚地光固化光固化树脂而获得; 以及包含有机倍半硅氧烷，环氧树脂和氧杂环丁烷树脂的包层40。当环氧树脂和氧杂环丁烷树脂固化时，其固化收缩率比丙烯酸树脂固化收缩率越来越小，因此在作为形成的固化产物的包层40的内部几乎不残留拉伸应力。环氧树脂，氧杂环丁烷树脂和有机倍半硅氧烷与具有酯键的丙烯酸树脂相比，耐热性高，吸湿性小，因此即使在高温高湿下也不会由于水分而膨胀。此外，透光壳体10优选由环氧树脂和氧杂环丁烷树脂形成。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2013184933A Metal oxide particle 审中-公开
标题翻译：金属氧化物颗粒
公开(公告)号：JP2013184933A
公开(公告)日：2013-09-19
申请号：JP2012051975
申请日：2012-03-08
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： OKADA ATSUSHI , TAKAHASHI KUNIO , HIROTA KOITSU
IPC分类号： C07C53/128 , C01G25/00 , C07F7/00
摘要： PROBLEM TO BE SOLVED: To obtain metal oxide particles that can be well dispersible in a substrate and have a crystal system mainly composed of a monoclinic crystal.SOLUTION: A metal oxide particle is coated with a carboxylate compound represented by formula (1):-OC(=O)-R and the ratio of the monoclinic crystal in the metal oxide particle is at least 90% relative to the total of all of the crystal systems. In formula (1), R is a hydrocarbon group. Preferably, the metal oxide particle is at least one oxide selected from the group consisting of Ti, Al, Zr, Zn and Sn.
摘要翻译：要解决的问题：获得可以良好地分散在基材中并具有主要由单斜晶体构成的晶体体系的金属氧化物颗粒。溶液：用式（1）表示的羧酸盐化合物涂覆金属氧化物颗粒： - OC（= O）-R，并且金属氧化物颗粒中的单斜晶体的比例相对于所有晶体体系的总和至少为90％。式（1）中，R为烃基。优选地，金属氧化物颗粒是选自Ti，Al，Zr，Zn和Sn中的至少一种氧化物。

3. 发明专利

JP2010085937A Composition containing inorganic oxide fine particle, and cured composition containing inorganic oxide fine particle obtained by curing the composition 有权
标题翻译：含有无机氧化物微粒的组合物和包含无机氧化物微粒的固化组合物通过固化而获得
公开(公告)号：JP2010085937A
公开(公告)日：2010-04-15
申请号：JP2008257915
申请日：2008-10-03
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： TAKAHASHI KUNIO , HIROTA KOITSU
IPC分类号： G02B1/11 , B82Y20/00 , B82Y30/00 , C08K3/22 , C08K9/04 , C08L101/00 , C08L101/08 , G02B1/111 , G02B1/14
摘要： PROBLEM TO BE SOLVED: To provide a composition containing inorganic oxide fine particles containing inorganic oxide fine particles and a polymerizable monomer exhibiting (I) antireflection property, (II) excellent adhesiveness to a substrate, (III) a function as a hard coat layer and (IV) excellent total luminous transmittance, particularly on a glass surface, as well as sufficiently achieving the above functions in a single layer. SOLUTION: The composition containing inorganic oxide fine particles contains (α) inorganic oxide fine particles coated with a coating material containing at least a (meth)acryl group, (β) a cyclic monofunctional compound having a cyclic structure and one polymerizable unsaturated group, and (γ) a polyfunctional compound having at least two polymerizable unsaturated groups. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决问题的方法为了提供含有无机氧化物微粒的无机氧化物微粒和可显示（I）抗反射性的聚合性单体的组合物，（II）对基材的密合性优异，（III）作为硬涂层，（IV），特别是玻璃表面的全透光性，以及在单层中充分实现上述功能。解决方案：含有无机氧化物微粒的组合物含有（α）无机氧化物微粒，其涂覆有至少含有（甲基）丙烯酰基的涂料，（β）具有环状结构的环状单官能化合物和一个可聚合不饱和基团和（γ）具有至少两个可聚合不饱和基团的多官能化合物。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2010070640A Hydrolyzable silicon compound, method for producing hydrolyzable silicon compound, condensate of hydrolyzable silicon compound, resin additive, inorganic surface modifier, film forming agent, and resin composition 审中-公开
标题翻译：可水解硅化合物，生产可水解硅化合物的方法，可水解硅化合物的冷凝剂，树脂添加剂，无机表面改性剂，膜形成剂和树脂组合物
公开(公告)号：JP2010070640A
公开(公告)日：2010-04-02
申请号：JP2008239385
申请日：2008-09-18
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： TAKAHASHI KUNIO
IPC分类号： C08G77/14 , C08K9/06 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To provide a hydrolyzable silicon compound excellent in dispersibility in an organic medium, affinity for inorganic materials, and properties imparted upon surface treatment of the inorganic materials, preferably used for various applications, and forming members excellent in transparency, refractive index and so on; a condensate of the hydrolyzable silicon compound; and a method for producing the hydrolyzable silicon compound; and to provide, as use thereof, a resin additive, an inorganic surface modifier, a film forming agent, and a resin composition essentially containing the hydrolyzable silicon compound and/or a condensate of the hydrolyzable silicon compound. SOLUTION: The hydrolyzable silicon compound comprises a structure having a row of a conjugated aromatic backbone, containing 7 or more carbon atoms, and 3 or more atoms. A condensate of the hydrolyzable silicon compound and a method for producing the hydrolyzable silicon compound are also disclosed. As its use, a resin additive, an inorganic surface modifier, a film forming agent essentially containing the hydrolyzable silicon compound and/or a condensate of the hydrolyzable silicon compound, as well as a resin composition essentially containing a hydrolyzable silicon compound and/or its condensate and a resin component is disclosed. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种在有机介质中分散性优异的可水解硅化合物，对无机材料的亲和性以及优选用于各种用途的无机材料的表面处理赋予的性能以及透明性优异的成型构件，折射率等; 可水解硅化合物的缩合物; 和可水解硅化合物的制造方法; 并且提供一种树脂添加剂，无机表面改性剂，成膜剂和基本上含有可水解硅化合物和/或可水解硅化合物的缩合物的树脂组合物的用途。解决方案：可水解硅化合物包括具有一行含有7个或更多个碳原子和3个或更多原子的共轭芳族主链的结构。还公开了可水解硅化合物的缩合物和可水解硅化合物的制备方法。作为其使用，树脂添加剂，无机表面改性剂，基本上含有可水解硅化合物和/或可水解硅化合物的缩合物的成膜剂以及基本上含有可水解硅化合物和/或其可水解硅化合物的树脂组合物公开了冷凝物和树脂组分。版权所有（C）2010，JPO＆INPIT

5. 发明专利

JP2009249467A Resin composition, optical material, and optical member 有权
标题翻译：树脂组合物，光学材料和光学成员
公开(公告)号：JP2009249467A
公开(公告)日：2009-10-29
申请号：JP2008097494
申请日：2008-04-03
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： TAKAHASHI KUNIO , MAKINO TOMOMI , TAJIRI KOZO
IPC分类号： C08L101/02 , C08G59/18 , C08L83/04 , G02B1/04
摘要： PROBLEM TO BE SOLVED: To provide a resin composition which has various excellent performance of transparency, a low curing contraction rate, a low refractive index, adhesion properties and the like, and is suitably used for optical uses (especially optical transparency uses) such as an optical waveguide, a lens, an optical disk, an optical fiber and a casing, a machine component material, electric and electronic component materials, civil engineering and construction materials, a molding material, and electric/electronic component materials, and to provide an optical material and an optical member. SOLUTION: This invention relates to the resin composition containing a cationically polymerizable group-containing organic compound as an organic resin component, wherein the cured body of the resin composition has a refractive index of 1.49 or below in 850 nm wavelength. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供具有各种优异的透明性，低固化收缩率，低折射率，粘合性等的树脂组合物，并且适合用于光学用途（特别是光学透明性用途），光波导，透镜，光盘，光纤和壳体，机器部件材料，电气和电子部件材料，土木工程和建筑材料，成型材料和电气/电子部件材料，以及以提供光学材料和光学构件。本发明涉及含有含有阳离子聚合性基团的有机化合物作为有机树脂成分的树脂组合物，其中树脂组合物的固化体在850nm波长下的折射率为1.49以下。版权所有（C）2010，JPO＆INPIT

6. 发明专利

JP2007186707A Resin composition for coating and curable coating composition 有权
标题翻译：用于涂料和可固化涂料组合物的树脂组合物
公开(公告)号：JP2007186707A
公开(公告)日：2007-07-26
申请号：JP2007038389
申请日：2007-02-19
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： TAKAHASHI KUNIO , KODAMA NAOKI , YOSHIDA MASAYA
IPC分类号： C09D175/04 , C09D7/12 , C09D175/08
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for a coating and a curable coating composition, wherein a cured coating film has excellent fundamental performance such as high gloss and high weatherability, high hardness and excellent flexibility, and at the same time, a high-solid composition thereof can meet resource saving and environmental protection requirements. SOLUTION: The curable coating composition comprises a resin composition for coatings comprising a polyol (A1) or (A2), a polyether polyol (B) and a solvent (C), a crosslinking agent comprising a (block) polyisocyanate compound, as an essential component, an organometallic compound and an acidic substance, wherein the polyol (A1) comprises a hydroxy group-containing polymerizable unsaturated monomer and a ring structure-containing polymerizable unsaturated monomer as essential components and the polyol (A2) comprises a hydroxy group-containing polymerizable unsaturated monomer and a specific linear branched structure-containing polymerizable unsaturated monomer as essential components. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种涂料用树脂组合物和固化性涂料组合物，其中固化涂膜具有优异的基础性能，例如高光泽度和高耐候性，高硬度和优异的柔韧性，并且同时，其高固体组成可以满足资源节约和环保要求。解决方案：可固化涂料组合物包含用于包含多元醇（A1）或（A2），聚醚多元醇（B）和溶剂（C））的涂料用树脂组合物，包含（嵌段）多异氰酸酯化合物的交联剂，作为必要成分的有机金属化合物和酸性物质，其中多元醇（A1）含有含羟基的可聚合不饱和单体和含环结构的可聚合不饱和单体作为必要成分，多元醇（A2）包括羟基的可聚合不饱和单体和特定的含直链支链的可聚合不饱和单体作为必要成分。版权所有（C）2007，JPO＆INPIT

7. 发明专利

JP2010116301A Composition comprising microparticle containing titania-silica sol and inorganic oxide other than titania and silica, and hardened material from the same 审中-公开
标题翻译：包含含有钛白粉和不含钛的无机氧化物的微晶的组合物及其相似的硬化材料
公开(公告)号：JP2010116301A
公开(公告)日：2010-05-27
申请号：JP2008291356
申请日：2008-11-13
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： TAKAHASHI KUNIO
IPC分类号： C01B33/141 , C01G25/02 , C08J7/04 , G02B1/04
摘要： PROBLEM TO BE SOLVED: To provide a composition satisfying a high refractive index and a high hardness, and providing a hardened material improved in ultraviolet resistance and heat resistance, and to provide a hardened material containing the composition and improved in various physical properties. SOLUTION: The composition comprises a titania-silica sol having a polymerizable organic group, and an inorganic oxide microparticle, wherein the inorganic oxide microparticle is a microparticle in which a polymerizable organic group is bonded to an inorganic oxide other than titania. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供满足高折射率和高硬度的组合物，并且提供耐紫外线性和耐热性提高的硬化材料，并提供含有该组合物的硬化材料并改善各种物理性能。解决方案：该组合物包含具有可聚合有机基团的二氧化钛 - 硅溶胶和无机氧化物微粒，其中无机氧化物微粒是可聚合有机基团与除二氧化钛之外的无机氧化物结合的微粒。版权所有（C）2010，JPO＆INPIT

8. 发明专利

JP2009235196A Curable resin composition, cured product thereof, optical member, and optical unit 审中-公开
标题翻译：可固化树脂组合物，其固化产品，光学部件和光学单元
公开(公告)号：JP2009235196A
公开(公告)日：2009-10-15
申请号：JP2008081573
申请日：2008-03-26
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： TAKAHASHI KUNIO
IPC分类号： C08G65/26 , G02B1/00
摘要： PROBLEM TO BE SOLVED: To provide a curable resin composition capable of keeping a refractive index of a cured product produced by curing the curable resin composition and capable of improving a curing rate, reducing curing shrinkage, and lowering viscosity for efficiently producing the cured product such as an optical member. SOLUTION: The curable resin composition includes a (meth)acrylate having a conjugate structure consisting of 7 or more carbon atoms and a radical polymerization initiator. The curable resin composition also includes a cationic polymerizable liquid compound having an aromatic structure as an essential component. The cured product produced by curing the curable resin composition, the optical member containing the cured product, and an optical unit having the optical member are also provided. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决问题的方案：提供一种固化树脂组合物，其能够保持通过固化该固化性树脂组合物而制备的固化物的折射率，并且能够提高固化速度，降低固化收缩率和降低粘度以有效地制备固化产物如光学构件。解决方案：可固化树脂组合物包括具有由7个或更多个碳原子组成的共轭结构的（甲基）丙烯酸酯和自由基聚合引发剂。可固化树脂组合物还包括具有芳族结构作为必要组分的阳离子可聚合液体化合物。还提供了通过固化固化性树脂组合物，含有固化物的光学构件和具有光学构件的光学单元固化的固化物。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2005272727A Aqueous resin dispersion and method for producing the same 审中-公开
标题翻译：水性树脂分散体及其制造方法
公开(公告)号：JP2005272727A
公开(公告)日：2005-10-06
申请号：JP2004090257
申请日：2004-03-25
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： SHIRAISHI SATOHIRO , TAKAHASHI KUNIO , YAMAZAWA SHIZUKA , NAKAO KANJI
IPC分类号： C08F2/24 , C08F220/18 , C08F246/00 , C08F265/00 , C09D5/02 , C09D7/12 , C09D157/00
摘要： PROBLEM TO BE SOLVED: To prepare an aqueous resin dispersion improved in its water resistance, also excellent in weather resistance and further environmentally advantageous.
SOLUTION: The aqueous resin dispersion containing a polymer containing an aromatic monomer unit indispensably and an emulsifying agent is provided with that the polymer contains 0.1-10 mass % aromatic monomer unit based on the total monomer units constituted with a polymerizable unsaturated bond group-containing compound, the emulsifying agent is a non-nonylphenyl-based emulsifying agent, and the aqueous resin dispersion has ≤5 ΔE in a water resistance whitening testing.
COPYRIGHT: (C)2006,JPO&NCIPI

10. 发明专利

JP2005272726A Aqueous resin dispersion and method for producing the same 有权
标题翻译：水性树脂分散体及其生产方法
公开(公告)号：JP2005272726A
公开(公告)日：2005-10-06
申请号：JP2004090256
申请日：2004-03-25
申请人： Nippon Shokubai Co Ltd , 株式会社日本触媒
发明人： SHIRAISHI SATOHIRO , TAKAHASHI KUNIO
IPC分类号： C08L25/08 , C08F2/24 , C08F257/00 , C08F265/00 , C09D5/02 , C09D151/00 , C09D157/00
摘要： PROBLEM TO BE SOLVED: To prepare an aqueous resin dispersion capable of exhibiting an excellent weather resistance by preventing the invasion of water for suppressing the deterioration of a coated film so as to be able to sufficiently exhibit basic property required for the uses in various under coating, middle coating, final coating, etc.
SOLUTION: This aqueous resin dispersion is provided by containing a polymer having 15-40 mass % aromatic monomer unit based on the total monomer unit constituted with a polymerizable unsaturated bonding group-containing compound, and has 60°mirror surface luster-maintaining rate GR (%) after passing 2,500 hr of the accelerated weathering testing of its coated film by a sunshine weatherometer satisfying the following formula (1): GR>(100-S)x(1+Y)+5 [wherein, S is the content of the aromatic monomer unit; and Y =-0.25+0.5Z when the content Z of a monomer unit constituted with an ultraviolet light-absorbable polymerizable monomer and ultraviolet light-stable monomer is 0 mass %≤Z≤0.5 mass %, and Y=0 when Z>0.5 mass %].
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：为了制备能够通过防止用于抑制涂膜的劣化的水的侵入而显示出优异的耐候性的水性树脂分散体，以便能够充分地显示用于各种底涂，中涂，最终涂层等。解决方案：该水性树脂分散体是通过含有基于由聚合性不饱和键合基团构成的总单体单元的具有15-40质量％芳族单体单元的聚合物，通过满足下列公式（1）的阳光恒温器通过其涂膜的加速耐候试验2500小时后，具有60°镜面光泽保持率GR（％）：GR>（100-S）× （1 + Y）+5 [其中，S为芳族单体单元的含量; 当紫外线吸收聚合性单体和紫外线稳定性单体构成的单体单元的含量Z为0质量％≤Z≤0.5质量％时，Y = -0.25 + 0.5Z，当Z> 0.5时Y = 0 质量％]。版权所有（C）2006，JPO＆NCIPI

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