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1. 发明专利

JP2007146050A Method for desulfurizing hydrocarbon-based fuel 有权
标题翻译：用于将基于油气的燃料进行除油的方法
公开(公告)号：JP2007146050A
公开(公告)日：2007-06-14
申请号：JP2005344374
申请日：2005-11-29
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： KOBORI YOSHIHIRO , ENOMOTO TOSHIYUKI , SEGAWA ATSUSHI , ADACHI TOMOAKI
IPC分类号： C10L3/10 , B01J23/46 , B01J23/80 , B01J23/86 , B01J29/12 , B01J37/30 , C01B3/38 , C01B3/48 , C10G25/05 , C10L3/12 , H01M8/06
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a desulfurizing method by using a desulfurizing agent capable of maintaining the desulfurizing effects over a long period in a state in which a trace of methanol is mixed in a hydrocarbon-based fuel containing sulfur, or in a state in which a trace of water is mixed therein. SOLUTION: The method for desulfurizing the hydrocarbon-based fuel containing the methanol uses a zeolite-based desulfurizing agent at least containing silver as the desulfurizing agent, wherein the ratio of SiO 2 /Al 2 O 3 in the zeolite is within the range of 2-3. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：为了提供一种脱硫方法，该脱硫方法是在含有微量甲醇的烃类燃料中含有硫的情况下，使用能够长时间保持脱硫效果的脱硫剂，或其中混合有痕量水的状态。解决方案：含有甲醇的烃类燃料的脱硫方法使用至少含有银的沸石型脱硫剂作为脱硫剂，其中SiO 2 / Al 2 O 3 在2-3范围内。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2004075474A Water gas shift reaction method, apparatus for producing hydrogen using the method and fuel cell system 有权
公开(公告)号：JP2004075474A
公开(公告)日：2004-03-11
申请号：JP2002239782
申请日：2002-08-20
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： ADACHI TOMOAKI , SATO YASUSHI , MIYAMA TADAO
IPC分类号： C01B3/16 , C01B3/48 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a method for suppressing the reduction of the service life of a catalyst caused by sintering while maintaining sufficient activity äGHSV (Gas Hourly Space Velocity)} as total in a water gas shift reaction. SOLUTION: In the water gas shift reaction method for a carbon monoxide-containing reformed gas comprising a two stage reaction process consisting of a high temperature shift reaction stage and a low temperature shift reaction stage, a noble metal-based catalyst comprising metal selected from ruthenium, rhodium, palladium, rhenium, osmium, iridium, platinum and gold is used in the first high temperature shift reaction stage, and a base metal based catalyst comprising copper and zinc as the main element components is used in the second low temperature shift reaction stage. In particular, the concentration of CO is made lower, or the treatment is performed so as to generate ≥70% of heating value in the first high temperature shift reaction stage. COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2003284950A Catalyst for selectively oxidizing carbon monoxide, method for reducing concentration of carbon monoxide, and fuel battery system 审中-公开
标题翻译：用于选择性氧化一氧化碳的催化剂，一氧化碳浓度降低的方法和燃料电池系统
公开(公告)号：JP2003284950A
公开(公告)日：2003-10-07
申请号：JP2002092274
申请日：2002-03-28
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： ADACHI TOMOAKI , ISHIZUKI KIBIKO , SATO YASUSHI , MATSUMOTO TAKANARI
IPC分类号： C01B3/32 , B01J23/42 , B01J23/46 , C01B3/48 , C10K3/04 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To obtain a catalyst for selectively oxidizing carbon monoxide from a raw gas containing carbon monoxide and hydrogen; a method for reducing a concentration of carbon monoxide using the catalyst; and a fuel battery system using the method. SOLUTION: In the catalyst, an inorganic oxide carrier is carried with at least one kind of a metal selected from the group consisting of Pt, Pd, Ru, Au, Rh and Ir, and after carried, a content of chlorine before drying is 100 mass ppm or lower against the carrier. By using such the catalyst, the concentration of carbon monoxide can be reduced by selectively oxidizing carbon monoxide in the raw gas containing carbon monoxide and hydrogen. COPYRIGHT: (C)2004,JPO
摘要翻译：待解决的问题：获得用于从含有一氧化碳和氢气的原料气体中选择性氧化一氧化碳的催化剂; 使用该催化剂降低一氧化碳浓度的方法; 以及使用该方法的燃料电池系统。解决方案：在催化剂中，无机氧化物载体携带有选自Pt，Pd，Ru，Au，Rh和Ir中的至少一种金属，并且在运送之后，将氯含量相对于载体干燥为100质量ppm以下。通过使用这种催化剂，可以通过选择性地氧化含有一氧化碳和氢气的原料气体中的一氧化碳来降低一氧化碳的浓度。版权所有（C）2004，JPO

4. 发明专利

JP2008031306A Desulfurization process for hydrocarbon fuel 审中-公开
标题翻译：石油燃料的脱硫工艺
公开(公告)号：JP2008031306A
公开(公告)日：2008-02-14
申请号：JP2006206498
申请日：2006-07-28
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： NIITSUMA TAKUYA , MIYAZAWA KAZUNORI , KOBORI YOSHIHIRO , ADACHI TOMOAKI , SEGAWA ATSUSHI
IPC分类号： C10L3/10 , B01J20/18 , C10G29/04 , H01M8/06 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a desulfurization process using a desulfurization agent capable of keeping a desulfurization effect for a long period of time on desulfurization of a hydrocarbon fuel containing carbonyl sulfide in a state mixed with a minute amount of methanol or further with moisture of a minute amount. SOLUTION: On desulfurizing the hydrocarbon fuel containing carbonyl sulfide and methanol, the desulfurization process of the hydrocarbon fuel comprises using a zeolite family desulfurizing agent which contains silver at least and also a ratio of SiO 2 /Al 2 O 3 in the zeolite being 2-3, and the desulfurizing agent whose surface area of the desulfurizing agent being more than 300 m 2 /g. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种脱硫工艺，其使用能够在与少量甲醇混合的状态下含有硫化羰的烃燃料脱硫长时间地保持脱硫效果的脱硫剂含有微量的水分。解决方案：在含有羰基硫化物和甲醇的烃燃料脱硫中，烃燃料的脱硫过程包括使用至少含有银的沸石族脱硫剂，并且SiO 2的比例< 沸石中的Al 2 3 为3〜3，脱硫剂的表面积大于300μm /G。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2004319401A Fuel for fuel cell system, its manufacturing method, and fuel cell system 有权
公开(公告)号：JP2004319401A
公开(公告)日：2004-11-11
申请号：JP2003114941
申请日：2003-04-18
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： SAITO KENICHIRO , ADACHI TOMOAKI , SEGAWA ATSUSHI , SADAKANE OSAMU
IPC分类号： H01M8/06
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide fuel suitable for a fuel cell system, capable of high efficient hydrogen generation and power generation, while minimizing deterioration in system durability due to degraded reforming catalyst, and to provide a fuel cell system capable of high efficient power generation for a long period of time.
SOLUTION: The fuel for a fuel cell system is a hydrocarbon mixture having a boiling range of 100-320°C, and containing a naphthene-based hydrocarbon of 20vol% or higher.
COPYRIGHT: (C)2005,JPO&NCIPI

6. 发明专利

JP2004319400A Fuel for fuel cell system and fuel cell system 有权
公开(公告)号：JP2004319400A
公开(公告)日：2004-11-11
申请号：JP2003114940
申请日：2003-04-18
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： SAITO KENICHIRO , ADACHI TOMOAKI , SEGAWA ATSUSHI , SADAKANE OSAMU
IPC分类号： H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide fuel suitable for a fuel cell system, capable of high efficient hydrogen generation and power generation, while minimizing deterioration in system durability due to degraded reforming catalyst, and to provide a fuel cell system capable of high efficient power generation for a long period of time.
SOLUTION: The fuel for a fuel cell system is a hydrocarbon mixture having a boiling range of 100-320°C, and an alykyl benzothiophene content of 7 mass ppm or lower.
COPYRIGHT: (C)2005,JPO&NCIPI

7. 发明专利

JP2010120784A Method for producing molded article of sulfonic acid group-containing carbonaceous material and application of the same 审中-公开
标题翻译：制备含硫酸基团的碳素材料的成型方法及其应用
公开(公告)号：JP2010120784A
公开(公告)日：2010-06-03
申请号：JP2008293472
申请日：2008-11-17
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： YANAGAWA SHINICHIRO , KONDO HIDESATO , ADACHI TOMOAKI
IPC分类号： C01B31/02 , B01J27/053 , C07B61/00 , C07C27/02 , C07C29/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C37/08 , C07C39/04 , C07C41/06 , C07C43/04 , C07C45/29 , C07C49/10 , C07C67/04 , C07C67/08 , C07C69/14
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a molded article of a sulfonic acid group-containing carbonaceous material, which has high catalytic activity and can be applied to a fixed bed flow reaction system. SOLUTION: The molded article of the sulfonic acid group-containing carbonaceous material containing sulfonic acid groups in a high content and having high solid acid catalytic activity can be obtained by molding and curing a mixture of a powdery carbide and an organic binder and then subjecting the resulting carbide molded article to a sulfonation treatment. The molded article can be used for performing various reactions such as hydration, etherification/esterification of an olefin, esterification of a carboxylic acid and an alcohol, hydrolysis of an ester, or acid hydrolysis of a hydroperoxide in a fixed bed flow reaction system. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供具有高催化活性并可应用于固定床流动反应体系的含磺酸基的碳质材料的模塑制品。解决方案：含有高含量磺酸基并具有高固体酸催化活性的含磺酸基的碳质材料的模塑制品可以通过将碳化二亚胺和有机粘合剂的混合物成型和固化来获得，然后对所得的碳化物模制品进行磺化处理。模塑制品可以用于进行各种反应，例如在固定床流动反应系统中进行水合，烯烃的醚化/酯化，羧酸和醇的酯化，酯的水解或氢过氧化物的酸水解。版权所有（C）2010，JPO＆INPIT

8. 发明专利

JP2008115309A Desulfurizing agent for kerosene, desulfurization process, and fuel cell system using the same 有权
标题翻译：用于凯氏体，脱硫方法和使用该催化剂的燃料电池系统的脱硫剂
公开(公告)号：JP2008115309A
公开(公告)日：2008-05-22
申请号：JP2006301131
申请日：2006-11-07
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： SEGAWA ATSUSHI , ADACHI TOMOAKI , KOMAMI TATSUSABURO , MIYAZAWA KAZUNORI
IPC分类号： C10G25/05 , B01J23/80 , C01B3/38 , C10G29/16 , H01M8/06
CPC分类号： H01M8/0675 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/2803 , B01J20/28061 , B01J2220/56 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/1058 , C01B2203/1064 , C01B2203/1247 , C01B2203/127 , C10G2300/1051 , C10G2300/202 , C10G2400/08 , H01M2008/1095 , Y02P20/128 , Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a desulfurizing agent effectively eliminating the sulfur contained in kerosene at a low pressure, excellent in the effect of suppressing carbon deposition. SOLUTION: The desulfurizing agent for kerosene comprises 45-75%. mass of nickel oxide, 3-40%. mass of zinc oxide, 10-25%. mass of silica and less than 5%. mass of alumina and less than 0.1%. mass of sodium, and has more than 200 m 2 /g of BET specific surface area. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种有效地消除低压煤油中所含的硫的脱硫剂，抑制碳沉积的效果优异。
解决方案：煤油脱硫剂含45-75％。氧化镍质量，3-40％。氧化锌质量10-25％。二氧化硅质量小于5％。氧化铝质量小于0.1％。并且具有超过200m 2 / SP / BET的BET比表面积。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2008039425A Method for evaluating selective oxidation ability of catalyst and method for producing gas containing high concentration hydrogen 有权
标题翻译：用于评价催化剂的选择性氧化能力的方法和用于生产含有高浓度氢气的气体的方法
公开(公告)号：JP2008039425A
公开(公告)日：2008-02-21
申请号：JP2006210158
申请日：2006-08-01
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： IWASA YASUYUKI , MATSUMOTO TAKANARI , ISHIZUKI KIBIKO , ADACHI TOMOAKI , KATO EMI
IPC分类号： G01N31/10 , B01J23/46 , C01B3/38 , G01N31/00 , H01M8/06
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for evaluating the selective oxidation ability of an employed catalyst at high accuracy in the selective oxidation of the carbon monoxide of a raw material gas containing hydrogen and carbon monoxide, and to provide a method of efficiently producing a gas containing high concentration hydrogen.
SOLUTION: When the raw material gas containing hydrogen and carbon monoxide and a gas containing oxygen are caused to flow through a catalyst layer for selectively oxidizing the carbon monoxide of the raw material gas, a correlation between the position in the raw material flowing direction of the catalyst layer and the concentration of carbon monoxide or oxygen at the position of the layer is determined. The gas containing high concentration hydrogen can be produced by selectively oxidizing the carbon monoxide of the raw material gas in such a manner that the consumption peak position of carbon monoxide x
max (CO) and that of oxygen x
max (O
2 ) satisfy the condition represented by formula (1): x
max (CO)≤x
max (O
2 ).
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决问题的方法：提供一种用于在含氢和一氧化碳的原料气体的一氧化碳的选择性氧化中以高精度评价所使用的催化剂的选择氧化能力的方法，并提供一种方法有效地生产含有高浓度氢气的气体。解决方案：当含有氢气和一氧化碳的原料气体和含氧气体通过用于选择性氧化原料气体一氧化碳的催化剂层时，原料流动位置之间的相关性确定催化剂层的方向和层的位置处的一氧化碳或氧气的浓度。含有高浓度氢气的气体可以通过选择性地氧化原料气体的一氧化碳，使得一氧化碳的消耗峰值位置（SB）和氧气x（CO） SB> max （O 2 ）满足由公式（1）表示的条件：x 最大（CO）≤x< （O 2 ）。版权所有（C）2008，JPO＆INPIT

10. 发明专利

JP2007146051A Method for desulfurizing hydrocarbon-based fuel 有权
标题翻译：用于将基于油气的燃料进行除油的方法
公开(公告)号：JP2007146051A
公开(公告)日：2007-06-14
申请号：JP2005344375
申请日：2005-11-29
申请人： Nippon Oil Corp , 新日本石油株式会社
发明人： KOBORI YOSHIHIRO , ENOMOTO TOSHIYUKI , SEGAWA ATSUSHI , ADACHI TOMOAKI
IPC分类号： C10L3/10 , B01J23/46 , B01J23/80 , B01J23/86 , B01J29/14 , B01J37/30 , C01B3/38 , C10G25/05 , C10L3/12 , H01M8/06
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a desulfurizing method by using a desulfurizing agent capable of maintaining the desulfurizing effects over a long period in a state in which a trace of methanol is mixed in a hydrocarbon-based fuel containing sulfur, or in a state in which a trace of water is mixed therein. SOLUTION: The method for desulfurizing the hydrocarbon-based fuel containing the methanol uses a zeolite-based desulfurizing agent at least containing copper as the desulfurizing agent, wherein the ratio of SiO 2 /Al 2 O 3 in the zeolite is within the range of 3-10. COPYRIGHT: (C)2007,JPO&INPIT

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