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    • 2. 发明申请
    • METHODS FOR SPHERICALLY GRANULATING AND AGGLOMERATING METAL PARTICLES AND THE METAL PARTICLES PREPARED THEREBY, ANODES MADE FROM THE METAL PARTICLES
    • 金属颗粒和金属颗粒的制备方法及其制备的金属颗粒,金属颗粒产生的阳离子
    • WO2007036087A1
    • 2007-04-05
    • PCT/CN2006/000184
    • 2006-01-27
    • NINGXIA ORIENT TANTALUM INDUSTRY CO., LTDHE, JilinPAN, LuntaoZHENG, AiguoCHENG, YueweiMA, YuezhongLIU, HongdongYANG, GuoqiWANG, ChunxiangWANG, YanpingZHENG, Shiping
    • HE, JilinPAN, LuntaoZHENG, AiguoCHENG, YueweiMA, YuezhongLIU, HongdongYANG, GuoqiWANG, ChunxiangWANG, YanpingZHENG, Shiping
    • B22F1/00B22F9/00H01G9/042
    • B22F1/0096B22F2998/00B22F2998/10B22F2999/00H01G9/0525B22F9/22B22F9/023B22F1/0014B22F1/0048B22F1/0055B22F1/0085B22F2201/20B22F9/04B22F2009/042
    • A method for spherically granulating and agglomerating metal particles such as tantalum and/or niobium powders is described in the present invention, which includes the steps of: a). comminuting the metal particles to form fine particles having D50 less than 50 µm: b). granulating the comminuted metal particles comprising volatile liquid, for example, tantalum and/or niobium particles comprising volatile liquid, to form wet spherical particles; c). still drying the wet spherical particles and removing volatile liquid to form flowable pre-agglomerated particles with increased bulk density; d). heat treating the pre-agglomerated particles; e). screening the heat treated powder to obtain the flowable agglomerated particles. The present invention provides a flowable spherical agglomerated metal particles, and especially tantalum and/or niobium particles having improved properties. The present agglomerated tantalum powder have a flow rate of at least about 2.0 g/sec, a BET surface area of from about 0.2 to about 6.0 m 2 /g, a FSSS of at least 1.0 µm, a Scott bulk density of from about 1.2 g/cm 3 to about 5.5 g/cm 3 . The present agglomerated niobium powder have a flow rate of at least about 1.0 g/sec, a BET surface area of from about 0.5 to about 8.0 m 2 /g, a FSSS of at least 1.0 µm, a Scott bulk density of from about 0.7 g/cm 3 to about 3.5 g/cm 3 . Said tantalum and/or niobium metal particles have improved pore size distribution of the sintered anodes and increased pellet crush strength. The present invention further provides an electrolytic capacitor anodes made from the tantalum and/or niobium particles according to the present invention having a capacitance of from about 5,000µFV/g to about 300,000µFV/g.
    • 在本发明中描述了一种用于球形造粒和附聚如钽和/或铌粉末的金属颗粒的方法,其包括以下步骤:a)。 粉碎金属颗粒以形成D50小于50μm的细颗粒:b)。 将包含挥发性液体的粉碎金属颗粒,例如包含挥发性液体的钽和​​/或铌颗粒造粒,以形成湿球形颗粒; C)。 仍然干燥湿球形颗粒并除去挥发性液体以形成具有增加堆积密度的可流动的预凝聚颗粒; D)。 热处理预凝聚的颗粒; E)。 筛选热处理粉末以获得可流动的附聚颗粒。 本发明提供了一种可流动的球形附聚金属颗粒,特别是具有改进性能的钽和/或铌颗粒。 本发明的聚集的钽粉末的流速为至少约2.0g / sec,BET表面积为约0.2至约6.0m 2 / g,FSSS为至少1.0μm, 斯托克堆积密度为约1.2g / cm 3至约5.5g / cm 3。 本发明的聚集铌粉末的流速为至少约1.0g / sec,BET表面积为约0.5至约8.0m 2 / g,FSSS为至少1.0μm, 斯科特堆积密度为约0.7g / cm 3至约3.5g / cm 3。 所述钽和/或铌金属颗粒具有改善的烧结阳极的孔径分布和增加的颗粒粉碎强度。 本发明进一步提供一种由根据本发明的钽和/或铌颗粒制成的电解电容器阳极,其电容为约5,000μFV/ g至约300,000μFV/ g。
    • 7. 发明公开
    • METHODS FOR SPHERICALLY GRANULATING AND AGGLOMERATING METAL PARTICLES AND THE METAL PARTICLES PREPARED THEREBY, ANODES MADE FROM THE METAL PARTICLES
    • METHOD FOR球形造粒和金属的团聚和由此制得的金属颗粒掉金属生产的涂层阳极
    • EP1928620A1
    • 2008-06-11
    • EP06705605.1
    • 2006-01-27
    • Ningxia Orient Tantalum Industry Co., Ltd.
    • HE, JilinPAN, LuntaoZHENG, AiguoCHENG, YueweiMA, YuezhongLIU, HongdongYANG, GuoqiWANG, ChunxiangWANG, YanpingZHENG, Shiping
    • B22F1/00B22F9/00H01G9/042
    • A method for spherically granulating and agglomerating metal particles such as tantalum and/or niobium powders is described in the present invention, which includes the steps of: a). comminuting the metal particles to form fine particles having D50 less than 50 μm; b). granulating the comminuted metal particles comprising volatile liquid, for example, tantalum and/or niobium particles comprising volatile liquid, to form wet spherical particles; c). still drying the wet spherical particles and removing volatile liquid to form flowable pre-agglomerated particles with increased bulk density; d). heat treating the pre-agglomerated particles; e). screening the heat treated powder to obtain the flowable agglomerated particles. The present invention provides a flowable spherical agglomerated metal particles, and especially tantalum and/or niobium particles having improved properties. The present agglomerated tantalum powder have a flow rate of at least about 2.0 g/sec, a BET surface area of from about 0.2 to about 6.0 m2/g, a FSSS of at least 1.0 μm, a Scott bulk density of from about 1.2 g/cm3 to about 5.5 g/cm3. The present agglomerated niobium powder have a flow rate of at least about 1.0 g/sec, a BET surface area of from about 0.5 to about 8.0 m2/g, a FSSS of at least 1.0 μm, a Scott bulk density of from about 0.7 g/cm3 to about 3.5 g/cm3. Said tantalum and/or niobium metal particles have improved pore size distribution of the sintered anodes and increased pellet crush strength. The present invention further provides an electrolytic capacitor anodes made from the tantalum and/or niobium particles according to the present invention having a capacitance of from about 5,000 μFV/g to about 300,000 μFV/g.
    • 一种用于球粒化和聚结的金属颗粒的方法:例如钽和/或铌粉中描述了本发明,其包括以下步骤:a)。 粉碎的金属颗粒,以形成具有D50小于50微米的细颗粒; B)。 造粒包括挥发性液体,例如钽和/或铌粒子包含挥发性液体,以形成湿的球形颗粒被粉碎的金属颗粒; C)。 无声干燥该湿的球状颗粒并除去挥发性液体,以形成具有增加的堆积密度可流动的预附聚的颗粒; D)。 热处理所述预附聚的颗粒; E)。 筛选所述经热处理的粉末,以获得可流动的附聚颗粒。 本发明提供了一种可流动的球形附聚的金属颗粒,和具有改进的性能的爱尤其钽和/或铌粒子。 本团聚钽粉末具有至少约2.0克/秒的流速,从约0.2至约6.0平方米/克的BET表面积,一个FSSS至少1.0微米,的斯科特堆积密度从约1.2克 / cm 3至约5.5克/立方厘米。 本团聚铌粉末具有至少约1.0克/秒的流动速率,从大约0.5至大约8.0米2 /克的BET表面积,一个FSSS至少1.0微米,的斯科特堆积密度为约0.7克 / cm 3至约3.5克/立方厘米。 所述钽和/或铌金属颗粒具有改善的烧结阳极的孔径分布和增加的沉淀压碎强度。 本发明进一步提供了从钽和/或铌粒子制成的电解电容器阳极gemäß于具有从约5,000 UFV / g至约300000 UFV / g的电容,本发明。