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    • 3. 发明授权
    • Self-contained imaging assembly
    • 独立成像组件
    • US5783353A
    • 1998-07-21
    • US570658
    • 1995-12-11
    • Joseph C. CamillusMark A. JohnsonJohn M. TaylorDarrell A. TerryWilliam LippkeS. Thomas Brammer
    • Joseph C. CamillusMark A. JohnsonJohn M. TaylorDarrell A. TerryWilliam LippkeS. Thomas Brammer
    • G03F7/004C08K5/09C08L61/06C08L67/02G03F7/00G03F7/26G03C1/73G03C1/76
    • G03F7/002Y10S430/116Y10S430/121Y10S430/122Y10S430/123
    • A sealed self-contained photohardenable imaging assembly comprising: a first transparent polymeric film support; a second polymeric film support which may be opaque or transparent; an imaging layer disposed between said first transparent support and said second support; a subbing layer disposed between said first transparent support and said imaging layer, said subbing including a polymer having chemical moieties which bond to said microcapsules; and an adhesive material disposed between said imaging layer and said second support; said imaging layer comprising a developer material and a plurality of microcapsules, said microcapsules encapsulating a photohardenable composition containing a color precursor, a polyethylenically unsaturated compound, a cyanine dye/borate photoinitiator and a disulfide having the formula: ##STR1## where X is selected from the group consisting of S and O except X is N when the disulfide includes one or more tetrazolyl groups; n represents 0 or 1; A represents the residue of the ring containing the N, C and X atoms, the ring containing five or six members and, in addition, said ring members may be fused to an aromatic ring; and R.sup.5 is an aromatic radical selected from the group consisting of (i) phenyl, (ii) benzothiazolyl, (iii) benzoxazolyl, (iv) tetrazolyl, (v) pyridinyl, (vi) pyrimidinyl, (vii) thiazolyl, (viii) oxazolyl, (ix) quinazolinyl, and (x) thiadiazolyl, wherein the imaging layer exhibits a residual stain of less than about 0.3 density units, wherein said microcapsules are melamine-formaldehyde microcapsules formed in the presence of pectin and said developer material is a phenolic resin essentially free of water soluble acid salts.
    • 一种密封的独立可光硬化成像组件,包括:第一透明聚合物膜载体; 可以是不透明或透明的第二聚合物膜载体; 设置在所述第一透明支撑件和所述第二支撑件之间的成像层; 设置在所述第一透明支撑件和所述成像层之间的底层,所述底板包括具有结合到所述微胶囊的化学部分的聚合物; 以及设置在所述成像层和所述第二支撑件之间的粘合材料; 所述成像层包括显影剂材料和多个微胶囊,所述微胶囊封装包含着色前体,多烯属不饱和化合物,花青染料/硼酸酯光引发剂和具有下式的二硫化物的可光硬化组合物:其中X选自 当二硫化物包括一个或多个四唑基时,除了X之外由S和O组成的组是N; n表示0或1; A表示含有N,C和X原子的环的残基,所述环含有五个或六个成员,此外,所述环成员可以与芳环稠合; (ⅰ)苯基,(ⅱ)苯并噻唑基,(ⅲ)苯并恶唑基,(ⅳ)四唑基,(ⅴ)吡啶基,(vi)嘧啶基,(i)噻唑基,(ii) (ix)喹唑啉基和(x)噻二唑基,其中成像层表现出小于约0.3密度单位的残留污渍,其中所述微胶囊是在果胶存在下形成的三聚氰胺 - 甲醛微胶囊,所述显影剂材料是酚类 树脂基本上不含水溶性酸盐。