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    • 6. 发明授权
    • Magnetic tunnel junction device with improved barrier layer
    • 具有改善阻挡层的磁隧道结器件
    • US07635654B2
    • 2009-12-22
    • US11341986
    • 2006-01-27
    • JiJun SunJohn T. MartinJon M. Slaughter
    • JiJun SunJohn T. MartinJon M. Slaughter
    • H01L21/316H01L27/115
    • H01L43/08H01L43/12
    • Methods and apparatus are provided for magnetic tunnel junction (MTJ) devices and arrays, comprising metal-insulator-metal (M-I-M) structures with opposed first and second ferro-magnetic electrodes with alterable relative magnetization direction. The insulator is formed by depositing an oxidizable material (e.g., Al) on the first electrode, naturally oxidizing it, e.g., at about 0.03 to 10 milli-Torr for up to a few thousand seconds at temperatures below about 35° C., then further rapidly (e.g., plasma) oxidizing at a rate much larger than that of the initial natural oxidation. The second electrode of the M-I-M structure is formed on this oxide. More uniform tunneling properties result. A second oxidizable material layer is optionally provided after the initial natural oxidation and before the rapid oxidation step during which it is substantially entirely converted to insulating oxide. A second natural oxidation cycle may be optionally provided before the second layer is rapidly oxidized.
    • 提供了用于磁性隧道结(MTJ)器件和阵列的方法和装置,其包括金属 - 绝缘体 - 金属(M-I-M)结构,具有相对的具有可变相对磁化方向的第一和第二铁磁电极。 绝缘体通过在第一电极上沉积可氧化材料(例如,Al)而形成,其自然氧化,例如在低于约35℃的温度下在约0.03至10毫乇达数千秒,然后 进一步快速(例如,等离子体)以比初始自然氧化的速率更大的速率氧化。 在该氧化物上形成M-I-M结构的第二电极。 导致更均匀的隧道性质。 任选地,在初始自然氧化之后和快速氧化步骤之间提供第二可氧化材料层,在该氧化步骤期间,其基本上完全转化为绝缘氧化物。 可以任选地在第二层被快速氧化之前提供第二自然氧化循环。
    • 7. 发明申请
    • Magnetic tunnel junction device with improved barrier layer
    • 具有改善阻挡层的磁隧道结器件
    • US20070178608A1
    • 2007-08-02
    • US11341986
    • 2006-01-27
    • JiJun SunJohn MartinJon Slaughter
    • JiJun SunJohn MartinJon Slaughter
    • H01L21/473
    • H01L43/08H01L43/12
    • Methods and apparatus are provided for magnetic tunnel junction (MTJ) devices and arrays, comprising metal-insulator-metal (M-I-M) structures with opposed first and second ferro-magnetic electrodes with alterable relative magnetization direction. The insulator is formed by depositing an oxidizable material (e.g., Al) on the first electrode, naturally oxidizing it, e.g., at about 0.03 to 10 milli-Torr for up to a few thousand seconds at temperatures below about 35° C., then further rapidly (e.g., plasma) oxidizing at a rate much larger than that of the initial natural oxidation. The second electrode of the M-I-M structure is formed on this oxide. More uniform tunneling properties result. A second oxidizable material layer is optionally provided after the initial natural oxidation and before the rapid oxidation step during which it is substantially entirely converted to insulating oxide. A second natural oxidation cycle may be optionally provided before the second layer is rapidly oxidized.
    • 提供了用于磁性隧道结(MTJ)器件和阵列的方法和装置,其包括金属 - 绝缘体 - 金属(M-I-M)结构,具有相对的具有可变相对磁化方向的第一和第二铁磁电极。 绝缘体通过在第一电极上沉积可氧化材料(例如,Al)而形成,其自然氧化,例如在低于约35℃的温度下在约0.03至10毫乇达数千秒,然后 进一步快速(例如,等离子体)以比初始自然氧化的速率更大的速率氧化。 在该氧化物上形成M-I-M结构的第二电极。 导致更均匀的隧道性质。 任选地,在初始自然氧化之后和快速氧化步骤之间提供第二可氧化材料层,在该氧化步骤期间,其基本上完全转化为绝缘氧化物。 可以任选地在第二层被快速氧化之前提供第二自然氧化循环。
    • 10. 发明申请
    • Magnetic tunnel junction element structures and methods for fabricating the same
    • 磁隧道结元件结构及其制造方法
    • US20060017081A1
    • 2006-01-26
    • US10899610
    • 2004-07-26
    • JiJun SunRenu DaveJon SlaughterJohan Akerman
    • JiJun SunRenu DaveJon SlaughterJohan Akerman
    • H01L29/94
    • H01L43/08B82Y25/00B82Y40/00H01F10/132H01F10/3254H01F10/3272H01F41/303H01L43/12
    • Magnetic tunnel junction (“MTJ”) element structures and methods for fabricating MTJ element structures are provided. An MTJ element structure may comprise a crystalline pinned layer, an amorphous fixed layer, and a coupling layer disposed between the crystalline pinned layer and the amorphous fixed layer. The amorphous fixed layer is antiferromagnetically coupled to the crystalline pinned layer. The MTJ element further comprises a free layer and a tunnel barrier layer disposed between the amorphous fixed layer and the free layer. Another MTJ element structure may comprise a pinned layer, a fixed layer and a non-magnetic coupling layer disposed therebetween. A tunnel barrier layer is disposed between the fixed layer and a free layer. An interface layer is disposed adjacent the tunnel barrier layer and a layer of amorphous material. The first interface layer comprises a material having a spin polarization that is higher than that of the amorphous material.
    • 提供磁隧道结(“MTJ”)元件结构和制造MTJ元件结构的方法。 MTJ元件结构可以包括结晶钉扎层,非晶固定层和设置在结晶钉扎层和非晶固定层之间的耦合层。 非晶固定层与结晶钉扎层反铁磁耦合。 MTJ元件还包括设置在非晶固定层和自由层之间的自由层和隧道势垒层。 另一MTJ元件结构可以包括被钉扎层,固定层和设置在它们之间的非磁性耦合层。 隧道势垒层设置在固定层和自由层之间。 界面层邻近隧道势垒层和非晶材料层设置。 第一界面层包括具有比无定形材料高的自旋极化的材料。