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1. 发明申请

US20090240067A1 METHOD OF PRODUCING A BISBENZODITHIOL COMPOUND 审中-公开
标题翻译：生产双苯二酚化合物的方法
公开(公告)号：US20090240067A1
公开(公告)日：2009-09-24
申请号：US12408114
申请日：2009-03-20
申请人： Masuji Motoki , Toshihiko Yawata , Naoyuki Hanaki , Tomoaki Nakamura
发明人： Masuji Motoki , Toshihiko Yawata , Naoyuki Hanaki , Tomoaki Nakamura
IPC分类号： C07D339/06
CPC分类号： C07D339/06
摘要： A method of producing a compound represented by formula (1), including: allowing 1,4-benzoquinone or 1,2-benzoquinone to react with a dithiocarbamate compound represented by formula (2) in a polar solvent: wherein R1 and R2 each independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, R1 and R2 may be the same or different and may be combined with each other to form a ring, X represents an ion necessary to neutralize the charge of the molecule, m represents an integer of 1 to 2, n represents an integer of 1 to 2, M represents a hydrogen atom, a metal atom or a conjugate acid of a base, p represents an integer of 1 to 4, and q represents an integer of 1 to 4.
摘要翻译：一种制备由式（1）表示的化合物的方法，包括：在极性溶剂中使1,4-苯醌或1,2-苯醌与式（2）表示的二硫代氨基甲酸酯化合物反应：其中R1和R2各自独立地表示氢原子，烷基，芳基或杂环基，R 1和R 2可以相同或不同，并且可以相互结合形成环，X表示中和分子电荷所必需的离子 m表示1〜2的整数，n表示1〜2的整数，M表示氢原子，金属原子或碱的共轭酸，p表示1〜4的整数，q表示整数 1到4。

2. 发明申请

US20100210762A1 HETEROCYCLIC COMPOUND, ULTRAVIOLET ABSORBENT AND COMPOSITION CONTAINING THE SAME 有权
标题翻译：杂环化合物，超紫外线吸收剂及其组合物
公开(公告)号：US20100210762A1
公开(公告)日：2010-08-19
申请号：US12669611
申请日：2008-08-15
申请人： Naoyuki Hanaki , Masuji Motoki , Toshihiko Yawata
发明人： Naoyuki Hanaki , Masuji Motoki , Toshihiko Yawata
IPC分类号： C08K5/45 , C07D495/04 , C07F7/10 , C07D487/04 , C07D498/04 , C07D513/04 , C07D471/04 , C08K5/46 , C08K5/3445
CPC分类号： A61Q17/04 , A61K8/49 , A61K8/4986 , C07D495/04 , C08K5/45
摘要： A compound represented by formula (I-1): wherein R21, R22, R23 and R24 each independently represent a hydrogen atom or a monovalent substituent, with the proviso that compounds, in which R21, R22, R23 and R24 each are an alkylthio group, are excluded; R21 and R22 and/or R23 and R24 each may bond to each other to form a ring, with the proviso that compounds, in which the formed ring is a dithiol ring or a dithiolane ring, are excluded; R25 and R26 each independently represent a hydrogen atom or a monovalent substituent; X21, X22, X23 and X24 each independently represent a hetero atom; compounds, wherein R21, R22, R23 and R24 each represent a cyan group; X21, X22, X23 and X24 each represent a sulfur atom; and R25 and R26 each represent a hydroxyl group or a hydrogen atom, are excluded; and compounds, wherein R21 and R23 each represent a hydrogen atom; R22 and R24 each represent an arylcarbonyl group; X21, X22, X23 and X24 each represent a sulfur atom; and R25 and R26 each represent a hydroxyl group, are excluded; and an ultraviolet absorbent, which has molecular weight of 10,000 or less and molar extinction coefficient at the maximum absorption wavelength of the ultraviolet absorbent of 80,000 or more.
摘要翻译：由式（I-1）表示的化合物：其中R 21，R 22，R 23和R 24各自独立地表示氢原子或一价取代基，条件是其中R 21，R 22，R 23和R 24各自为烷硫基，被排除在外; R 21和R 22和/或R 23和R 24各自可以彼此键合形成环，条件是排除其中形成的环是二硫醇环或二硫戊环的化合物; R 25和R 26各自独立地表示氢原子或一价取代基; X21，X22，X23和X24各自独立地表示杂原子; 化合物，其中R 21，R 22，R 23和R 24各自表示青色基团; X21，X22，X23和X24各自表示硫原子; R 25和R 26各自表示羟基或氢原子; 和其中R 21和R 23各自表示氢原子的化合物; R 22和R 24各自表示芳基羰基; X21，X22，X23和X24各自表示硫原子; R 25和R 26各自表示羟基; 和紫外线吸收剂，其分子量为10,000以下，紫外线吸收剂的最大吸收波长的摩尔消光系数为80,000以上。

3. 发明授权

US08039532B2 Heterocyclic compound, ultraviolet absorbent and composition containing the same 有权
标题翻译：杂环化合物，紫外线吸收剂和含有它们的组合物
公开(公告)号：US08039532B2
公开(公告)日：2011-10-18
申请号：US12669611
申请日：2008-08-15
申请人： Naoyuki Hanaki , Masuji Motoki , Toshihiko Yawata
发明人： Naoyuki Hanaki , Masuji Motoki , Toshihiko Yawata
IPC分类号： C08K5/45 , C07D495/04
CPC分类号： A61Q17/04 , A61K8/49 , A61K8/4986 , C07D495/04 , C08K5/45
摘要： A compound represented by formula (I-1): wherein R21, R22, R23 and R24 each independently represent a hydrogen atom or a monovalent substituent, with the proviso that compounds, in which R21, R22, R23 and R24 each are an alkylthio group, are excluded; R21 and R22 and/or R23 and R24 each may bond to each other to form a ring, with the proviso that compounds, in which the formed ring is a dithiol ring or a dithiolane ring, are excluded; R25 and R26 each independently represent a hydrogen atom or a monovalent substituent; X21, X22, X23 and X24 each independently represent a hetero atom; compounds, wherein R21, R22, R23 and R24 each represent a cyan group; X21, X22, X23 and X24 each represent a sulfur atom; and R25 and R26 each represent a hydroxyl group or a hydrogen atom, are excluded; and compounds, wherein R21 and R23 each represent a hydrogen atom; R22 and R24 each represent an arylcarbonyl group; X21, X22, X23 and X24 each represent a sulfur atom; and R25 and R26 each represent a hydroxyl group, are excluded; and an ultraviolet absorbent, which has molecular weight of 10,000 or less and molar extinction coefficient at the maximum absorption wavelength of the ultraviolet absorbent of 80,000 or more.
摘要翻译：由式（I-1）表示的化合物：其中R 21，R 22，R 23和R 24各自独立地表示氢原子或一价取代基，条件是其中R 21，R 22，R 23和R 24各自为烷硫基，被排除在外; R 21和R 22和/或R 23和R 24各自可以彼此键合形成环，条件是排除其中形成的环是二硫醇环或二硫戊环的化合物; R 25和R 26各自独立地表示氢原子或一价取代基; X21，X22，X23和X24各自独立地表示杂原子; 化合物，其中R 21，R 22，R 23和R 24各自表示青色基团; X 21，X 22，X 23和X 24各自表示硫原子; R 25和R 26各自表示羟基或氢原子; 和其中R 21和R 23各自表示氢原子的化合物; R 22和R 24各自表示芳基羰基; X21，X22，X23和X24各自表示硫原子; R 25和R 26各自表示羟基; 和紫外线吸收剂，其分子量为10,000以下，紫外线吸收剂的最大吸收波长的摩尔消光系数为80,000以上。

4. 发明授权

US07884146B2 Polymer material containing ultraviolet absorbent 有权
标题翻译：含紫外线吸收剂的聚合物材料
公开(公告)号：US07884146B2
公开(公告)日：2011-02-08
申请号：US12525590
申请日：2008-02-20
申请人： Toshihiko Yawata , Naoyuki Hanaki , Hisashi Mikoshiba , Akihiro Kaneko
发明人： Toshihiko Yawata , Naoyuki Hanaki , Hisashi Mikoshiba , Akihiro Kaneko
IPC分类号： C08K5/45 , C07D339/06
CPC分类号： C08K5/45 , C07D339/02 , C09K15/12
摘要： A polymer material, containing at least one kind of polymer substance selected from the group consisting of acrylic acid-based polymers, polyester-based polymers, and polycarbonate-based polymers; and a compound represented by formula (2) contained in the polymer substance: wherein A21 and A22 each independently represent an atom other than hydrogen atom and carbon atom; Y21 and Y22 each independently represent a hydrogen atom or a monovalent substituent; at least one of Y21 and Y22 represents a substituent having a Hammett substituent constant σp of 0.2 or more; Y21 and Y22 may bind to each other to form a ring; and (B) represents a group of atoms necessary for forming a five- or six-membered ring with A21, A22 and the carbon atom.
摘要翻译：含有选自丙烯酸系聚合物，聚酯系聚合物，聚碳酸酯类聚合物中的至少一种聚合物的高分子材料，和由式（2）表示的化合物，其中A21和A22各自独立地表示氢原子和碳原子以外的原子; Y 21和Y 22各自独立地表示氢原子或一价取代基; Y21和Y22中的至少一个表示具有Hammett取代基常数＆amp; p的取代基，其0.2以上; Y 21和Y 22可以彼此结合形成环; 和（B）表示与A21，A22和碳原子形成五元或六元环所必需的一组原子。

5. 发明申请

US20100130638A1 ULTRAVIOLET ABSORBENT COMPOSITION 审中-公开
标题翻译： ULTRAVIOLET吸收剂组合物
公开(公告)号：US20100130638A1
公开(公告)日：2010-05-27
申请号：US12593862
申请日：2008-03-31
申请人： Naoyuki Hanaki , Toshihiko Yawata
发明人： Naoyuki Hanaki , Toshihiko Yawata
IPC分类号： G21K1/10 , F21V9/06
CPC分类号： C08K5/45 , C08K5/13 , C08K5/3435 , H01L31/048 , Y02E10/50
摘要： An ultraviolet absorbent composition, containing an ultraviolet absorbent represented by formula (2) or (B-I), and a compound represented by formula (TS-I) or (TS-II): wherein A21, A22 and XB1 to XB4 represent a hetero atom; Y21, Y22, RB1 to RB6, R91 to R96, R101 to R104 and X101 represent a hydrogen atom or a substituent; at least one of Y21 and Y22 represents a substituent having a Hammett substituent constant of 0.2 or more; and (B) represents a group of atoms necessary for forming a five- or six-membered ring; —X91- represents —O—, —S—, or —N(—R100)-, in which R100 has the same meaning as R91; all of R91 to R96 and R100 cannot simultaneously represent a hydrogen atom, respectively, and the total number of carbon atoms is 10 or more; and X102 represents a group of hetero atoms necessary for forming a 5- to 7-membered ring.
摘要翻译：一种含有由式（2）或（BI）表示的紫外线吸收剂和由式（TS-I）或（TS-II）表示的化合物的紫外线吸收剂组合物：其中A21，A22和XB1至XB4表示杂原子 ; Y21，Y22，RB1〜RB6，R91〜R96，R101〜R104，X101表示氢原子或取代基; Y 21和Y 22中的至少一个表示哈米特取代基常数为0.2以上的取代基; 和（B）表示形成五元或六元环所必需的一组原子; -X91-表示-O-，-S-或-N（-R100） - ，其中R100具有与R91相同的含义; R91〜R96，R100全部不能同时表示氢原子，碳原子数为10以上。并且X 102表示形成5-至7-元环所必需的一组杂原子。

6. 发明申请

US20100076124A1 POLYMER MATERIAL CONTAINING ULTRAVIOLET ABSORBENT 有权
标题翻译：含有超紫外线吸收剂的聚合物材料
公开(公告)号：US20100076124A1
公开(公告)日：2010-03-25
申请号：US12525590
申请日：2008-02-20
申请人： Toshihiko Yawata , Naoyuki Hanaki , Hisashi Mikoshiba , Akihiro Kaneko
发明人： Toshihiko Yawata , Naoyuki Hanaki , Hisashi Mikoshiba , Akihiro Kaneko
IPC分类号： C08K5/45 , C07D339/06
CPC分类号： C08K5/45 , C07D339/02 , C09K15/12
摘要： A polymer material, containing at least one kind of polymer substance selected from the group consisting of acrylic acid-based polymers, polyester-based polymers, and polycarbonate-based polymers; and a compound represented by formula (2) contained in the polymer substance: wherein A21 and A22 each independently represent an atom other than hydrogen atom and carbon atom; Y21 and Y22 each independently represent a hydrogen atom or a monovalent substituent; at least one of Y21 and Y22 represents a substituent having a Hammett substituent constant σp of 0.2 or more; Y21 and Y22 may bind to each other to form a ring; and (B) represents a group of atoms necessary for forming a five- or six-membered ring with A21, A22 and the carbon atom.
摘要翻译：含有选自丙烯酸系聚合物，聚酯系聚合物，聚碳酸酯类聚合物中的至少一种聚合物的高分子材料，和由式（2）表示的化合物，其中A21和A22各自独立地表示氢原子和碳原子以外的原子; Y 21和Y 22各自独立地表示氢原子或一价取代基; Y21和Y22中的至少一个表示具有Hammett取代基常数＆amp; p的取代基，其0.2以上; Y 21和Y 22可以彼此结合形成环; 和（B）表示与A21，A22和碳原子形成五元或六元环所必需的一组原子。

7. 发明申请

US20100025642A1 ULTRAVIOLET ABSORBENT COMPOSITION 审中-公开
标题翻译： ULTRAVIOLET吸收剂组合物
公开(公告)号：US20100025642A1
公开(公告)日：2010-02-04
申请号：US12527786
申请日：2008-02-20
申请人： Naoyuki Hanaki , Toshihiko Yawata , Hisashi Mikoshiba
发明人： Naoyuki Hanaki , Toshihiko Yawata , Hisashi Mikoshiba
IPC分类号： F21V9/06
CPC分类号： C08K5/005 , C08K2201/014 , C08L21/00
摘要： An ultraviolet absorbent composition, containing: at least one kind of ultraviolet absorbent A having an absorption maximum wavelength of from 350 nm to 400 nm, a half value width of 55 nm or less and a molar extinction coefficient of 20,000 or more at the absorption maximum wavelength; and at least one kind of ultraviolet absorbent B having an absorption maximum wavelength of 350 nm or less and showing 30% or more of absorbance at 320 nm of the absorbance at the absorption maximum wavelength.
摘要翻译：一种紫外线吸收剂组合物，其含有吸收最大波长为350nm〜400nm，半值宽度为55nm以下，摩尔吸光系数为20000以上的紫外线吸收剂A 波长; 和吸收最大波长为350nm以下的至少一种紫外线吸收剂B，在吸收最大波长处的吸光度在320nm处显示30％以上的吸光度。

8. 发明授权

US09737634B2 Non-woven fabric containing bone prosthetic material 有权
公开(公告)号：US09737634B2
公开(公告)日：2017-08-22
申请号：US14001559
申请日：2012-02-28
申请人： Yusuke Okimura , Kazuyoshi Kita , Naoyuki Hanaki , Yasunori Nemoto
发明人： Yusuke Okimura , Kazuyoshi Kita , Naoyuki Hanaki , Yasunori Nemoto
IPC分类号： A61L27/36 , A61L27/46 , A61F2/28
CPC分类号： A61L27/36 , A61F2/28 , A61L27/46 , A61L2430/02
摘要： An object of the present invention is to provide a bone regeneration material suitable for bone (in particular, alveolar bone) regeneration. The present invention provides a non-woven fabric containing a bone prosthetic material wherein the bone prosthetic material is included between biocompatible fibers that constitute the non-woven fabric. The non-woven fabric may be suitably used as a bone regeneration material (in particular, a dental bone regeneration material).

9. 发明申请

US20110018946A1 AZO COMPOUNDS, AZO PIGMENTS, AND DISPERSION, COLORING COMPOSITION AND INK FOR INKJET RECORDING CONTAINING THE AZO COMPOUNDS OR AZO PIGMENTS, INK TANK FOR INKJET RECORDING, INKJET RECORDING METHOD, AND RECORDED PRODUCTS 有权
标题翻译： AZO化合物，AZO颜料和分散体，着色组合物和用于包含AZO化合物或AZO颜料的墨水记录的墨水，用于喷墨记录的墨盒，记录方法和记录的产品
公开(公告)号：US20110018946A1
公开(公告)日：2011-01-27
申请号：US12921327
申请日：2009-03-05
申请人： Shinya Hayashi , Keiichi Tateishi , Naoyuki Hanaki
发明人： Shinya Hayashi , Keiichi Tateishi , Naoyuki Hanaki
IPC分类号： B41J2/175 , C09B29/52
CPC分类号： C07D487/04 , C09B29/0037 , C09B29/3695 , C09B35/03 , C09D11/322
摘要： An azo pigment represented by the general formula (1), a tautomer, salt, or hydrate thereof: wherein R1, R2, R3, Y, Z, and G each independently represents a hydrogen atom or a substituent, n represents an integer of from 2 to 4 and, when n=2, the general formula (1) represents a dimer formed through R1, R2, R3, Y, Z, or G and, when n=3, the general formula (1) represents a trimer formed through R1, R2, R3, Y, Z, or G and, when n=4, the general formula (1) represents a tetramer formed through R1, R2, R3, Y, Z, or G.
摘要翻译：由通式（1）表示的偶氮颜料，其互变异构体，盐或水合物：其中R1，R2，R3，Y，Z和G各自独立地表示氢原子或取代基，n表示 2〜4，当n = 2时，通式（1）表示通过R 1，R 2，R 3，Y，Z或G形成的二聚体，当n = 3时，通式（1）表示形成的三聚体通过R 1，R 2，R 3，Y，Z或G，并且当n = 4时，通式（1）表示通过R 1，R 2，R 3，Y，Z或G形成的四聚体。

10. 发明申请

US20090239982A1 Ultraviolet Absorbent and Heterocyclic Compound 审中-公开
标题翻译：紫外线吸收剂和杂环化合物
公开(公告)号：US20090239982A1
公开(公告)日：2009-09-24
申请号：US12055969
申请日：2008-03-26
申请人： Ichiro Amasaki , Naoyuki Hanaki
发明人： Ichiro Amasaki , Naoyuki Hanaki
IPC分类号： C08K5/3465 , C07D413/14 , C08K5/357 , C07D403/14
CPC分类号： C07D413/04 , C07D401/04 , C07D403/04 , C07D409/04 , C07D413/14 , C07D417/04 , C07D417/14 , C07D498/04 , C08K5/357
摘要： An ultraviolet absorbent represented by the following Formula (1) or (6): wherein, Het1 represents a monovalent five- or six-membered aromatic heterocyclic residue; Xa and Xb each independently represent a heteroatom; Ya to Yc each independently represent a heteroatom or a carbon atom; the ring formed from carbon atom, Xa, Xb, Ya to Yc may have a double bond at any position and has at least one fused ring; wherein, Het6 represents a monovalent five- or six-membered aromatic heterocyclic residue; X6a and X6b each independently represent a heteroatom; Y6a, Y6b and Y6c each independently represent a heteroatom or a carbon atom; L6 represents a bi- to octa-valent connecting group; n is an integer of 2 or more, and m is an integer of 0 or more.
摘要翻译：由下式（1）或（6）表示的紫外线吸收剂：其中，Het1表示一价五元或六元芳族杂环残基; Xa和Xb各自独立地表示杂原子; Ya至Yc各自独立地表示杂原子或碳原子; 由碳原子Xa，Xb，Ya至Yc形成的环可以在任何位置具有双键并且具有至少一个稠环; 其中Het6表示一价五元或六元芳族杂环残基; X6a和X6b各自独立地表示杂原子; Y6a，Y6b和Y6c各自独立地表示杂原子或碳原子; L6表示二价至八价连接基团; n为2以上的整数，m为0以上的整数。

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