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    • 3. 发明授权
    • Process for producing propylene block copolymers
    • 制备丙烯嵌段共聚物的方法
    • US5623022A
    • 1997-04-22
    • US502141
    • 1995-07-13
    • Toshihiko SuganoTakao Tayano
    • Toshihiko SuganoTakao Tayano
    • C08F4/645C08F4/659C08F4/6592C08F10/00C08F10/06C08F297/08
    • C08F297/083C08F10/00C08F10/06C08F4/65912C08F4/65916C08F4/65927
    • A propylene block copolymer having a high impact resistance is prepared without the generation of finely divided particles or the adhesion to the reactor, which propylene block copolymer having a weight ratio of 5/95-70/30 (process (1)/process (2)) is obtained by carrying out the particular polymerization processes (1) and (2) in this sequence under the action of the catalyst comprising the following A and B.A: particular transition metal compound.B: an alumoxane, the reaction product of an alkylboronic acid with an organoAl, a Lewis acid or ionic compound.Process (1): process for copolymerizing propylene and a specified comonomer in a ratio of 0/100-80/20.Process (2): process for producing a propylene polymer having a specified comonomer in an amount of 10% by weight or less.
    • 制备具有高耐冲击性的丙烯嵌段共聚物,而不产生细碎颗粒或与反应器的粘附性,该丙烯嵌段共聚物的重量比为5 / 95-70 / 30(工艺(1)/工艺(2) ))是通过在包含以下A和B的催化剂的作用下以该顺序进行特定的聚合方法(1)和(2)得到的。A:特定的过渡金属化合物。 B:铝氧烷,烷基硼酸与有机铝的反应产物,路易斯酸或离子化合物。 方法(1):以0 / 100-80 / 20的比例共聚丙烯和特定共聚单体的方法。 方法(2):制备具有10重量%以下的特定共聚单体的丙烯聚合物的方法。