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1. 发明申请

US20080090985A1 PROCESS FOR PRODUCING CONTROLLED VISCOSITY FLUOROSILICONE POLYMERS 审中-公开
公开(公告)号：US20080090985A1
公开(公告)日：2008-04-17
申请号：US11549139
申请日：2006-10-13
申请人： Nancy E. Gosh , John S. Razzano , Anping Wang
发明人： Nancy E. Gosh , John S. Razzano , Anping Wang
IPC分类号： C08G77/06
CPC分类号： C08G77/06 , C08G77/24
摘要： A process for making a fluorosilicone M″DaDFbM′ with M″=(OH)R6R7SiO1/2 or (OH)R4R5SiO1/2 and is chosen independently of M′; M′=(OH)R6R7SiO1/2 or (OH)R4R5SiO1/2 and is chosen independently of M″; D=R4R5SiO2/2; and DF=R6R7SiO2/2; where the subscript a is zero or positive, the subscript b is positive and the subscripts a and b satisfy the following relationship: b>0.4(a+b) and R1 is selected from the group of 1 to 20 carbon atom monovalent alkyl, aryl, or alkaryl hydrocarbon radicals and terminally unsaturated alkenyl groups of from 2 to 10 carbon atoms; R2, R3 are each independently any monovalent hydrocarbon radical: alkyl, aryl, or alkaryl of from 1 to 20 carbon atoms or R1 and each R4 and R5 are any monovalent hydrocarbon radical: alkyl, aryl, alkenyl, or alkaryl of from 1 to 20 carbon atoms, and R6 is a fluorine substituted 3 to 20 carbon atom monovalent hydrocarbon radical having no fluorine substitution on the alpha or beta carbon atoms of the radical and R7 is any monovalent hydrocarbon radical: alkyl, aryl, or alkaryl of from 1 to 20 carbon atoms or R6 by reacting 1) b moles of (R6R7SiO)3, with 2) a moles of (R4R5SiO)3, 3) water and 4) an oxygenated promoter. Compositions made by the process and articles of manufacture made from the compositions.

2. 发明授权

US07671161B2 Process for producing controlled viscosity fluorosilicone polymers 有权
标题翻译：生产受控粘度氟硅氧烷聚合物的方法
公开(公告)号：US07671161B2
公开(公告)日：2010-03-02
申请号：US11549137
申请日：2006-10-13
申请人： Nancy E. Gosh , John S. Razzano , Anping Wang
发明人： Nancy E. Gosh , John S. Razzano , Anping Wang
IPC分类号： C08G77/24
CPC分类号： C08G77/24
摘要： A process for making a fluorosilicone MDaDFbM′ where M=R1R2R3SiO1/2; M′=(OH)R6R7SiO1/2 or (OH)R4R5SiO1/2; D=R4R5SiO2/2; and DF=R6R7SiO2/2; where the subscript a is zero or positive, the subscript b is positive and the subscripts a and b satisfy the following relationship: b>0.4(a+b) and R1 is selected from the group of 1 to 20 carbon atom monovalent alkyl, aryl, or alkaryl hydrocarbon radicals and terminally unsaturated alkenyl groups of from 2 to 10 carbon atoms; R2, R3 are each independently any monovalent hydrocarbon radical: alkyl, aryl, or alkaryl of from 1 to 20 carbon atoms or R1 and each R4 and R5 are any monovalent hydrocarbon radical: alkyl, aryl, alkenyl, or alkaryl of from 1 to 20 carbon atoms, and R6 is a fluorine substituted 3 to 20 carbon atom monovalent hydrocarbon radical having no fluorine substitution on the alpha or beta carbon atoms of the radical and R7 is any monovalent hydrocarbon radical: alkyl, aryl, or alkaryl of from 1 to 20 carbon atoms or R6 by reacting 1) b moles of (R6R7SiO)3, with 2) a moles of (R4R5SiO)3, 3) R1R2R3SiOH and 4) an oxygenated promoter. Compositions made by the process and articles of manufacture made from the compositions.
摘要翻译：制备氟硅酮MDaDFbM的方法，其中M = R 1 R 2 R 3 SiO 1/2; M'=（OH）R6R7SiO1 / 2或（OH）R4R5SiO1 / 2; D = R4R5SiO2 / 2; DF = R6R7SiO2 / 2; 其中下标a为零或正，下标b为正，下标a和b满足以下关系：b> 0.4（a + b），R1选自1至20个碳原子的一价烷基，芳基或烷芳基烃基和具有2-10个碳原子的末端不饱和烯基; R 2，R 3各自独立地为任何一价烃基：具有1-20个碳原子的烷基，芳基或烷芳基或R 1，并且每个R 4和R 5是任何一价烃基：1至20的烷基，芳基，链烯基或烷芳基碳原子，R6是氟取代的3〜20个碳原子，在基团的α或β碳原子上不具有氟取代的一价烃基，R 7是任何一价烃基：1至20的烷基，芳基或烷芳基碳原子或R6通过使1）b摩尔的（R6R7SiO）3与2）摩尔的（R 4 R 5 SiO）3,3）R 1 R 2 R 3 SiOH和4）含氧促进剂反应。由组合物制成的方法和制品制成的组合物。

3. 发明申请

US20080090987A1 PROCESS FOR PRODUCING CONTROLLED VISCOSITY FLUOROSILICONE POLYMERS 有权
公开(公告)号：US20080090987A1
公开(公告)日：2008-04-17
申请号：US11549137
申请日：2006-10-13
申请人： Nancy E. Gosh , John S. Razzano , Anping Wang
发明人： Nancy E. Gosh , John S. Razzano , Anping Wang
IPC分类号： C08G77/22
CPC分类号： C08G77/24
摘要： A process for making a fluorosilicone MDaDFbM′ where M=R1R2R3SiO1/2; M′=(OH)R6R7SiO1/2 or (OH)R4R5SiO1/2; D=R4R5SiO2/2; and DF=R6R7SiO2/2; where the subscript a is zero or positive, the subscript b is positive and the subscripts a and b satisfy the following relationship: b>0.4 (a+b) and R1 is selected from the group of 1 to 20 carbon atom monovalent alkyl, aryl, or alkaryl hydrocarbon radicals and terminally unsaturated alkenyl groups of from 2 to 10 carbon atoms; R2, R3 are each independently any monovalent hydrocarbon radical: alkyl, aryl, or alkaryl of from 1 to 20 carbon atoms or R1 and each R4 and R5 are any monovalent hydrocarbon radical: alkyl, aryl, alkenyl, or alkaryl of from 1 to 20 carbon atoms, and R6 is a fluorine substituted 3 to 20 carbon atom monovalent hydrocarbon radical having no fluorine substitution on the alpha or beta carbon atoms of the radical and R7 is any monovalent hydrocarbon radical: alkyl, aryl, or alkaryl of from 1 to 20 carbon atoms or R6 by reacting 1) b moles of (R6R7SiO)3, with 2) a moles of (R4R5SiO)3, 3) R1R2R3SiOH and 4) an oxygenated promoter. Compositions made by the process and articles of manufacture made from the compositions.

4. 发明授权

US06232425B1 Polymerization process for fluorosilicone polymers 有权
标题翻译：氟硅氧烷聚合物的聚合方法
公开(公告)号：US06232425B1
公开(公告)日：2001-05-15
申请号：US09224670
申请日：1998-12-31
申请人： John S. Razzano , Nancy E. Gosh
发明人： John S. Razzano , Nancy E. Gosh
IPC分类号： C08G7708
CPC分类号： C08G77/24 , C08G77/08
摘要： A process for making organosilyl end-stopped diorganopolysiloxane fluid is provided comprising the steps of reacting an organic end-stopping compound with a fluorosilicone trimer in the presence of a catalytic amount of linear phosphonitrilic acid, and inactivating the linear phosphonitrilic acid, thereby forming organosilyl end-stopped diorganopolysiloxane fluid.
摘要翻译：提供了制备有机甲硅烷基末端停止的二有机聚硅氧烷流体的方法，包括以下步骤：在催化量的线性磷腈酸存在下使有机终止化合物与氟硅酮三聚体反应，并使线性磷腈三乙酸失活，从而形成有机甲硅烷基末端抑制二有机聚硅氧烷流体。

5. 发明授权

US06492479B2 Process for producing fluorosilicon polymers 失效
标题翻译：制备氟硅聚合物的方法
公开(公告)号：US06492479B2
公开(公告)日：2002-12-10
申请号：US09935317
申请日：2001-08-22
申请人： John S. Razzano , Nancy E. Gosh
发明人： John S. Razzano , Nancy E. Gosh
IPC分类号： C08G7708
CPC分类号： C08G77/24 , C08G77/08
摘要： The invention comprises a method for producing fluorosilicone oil by reacting a fluorosilicone trimer with a triorganosilanol in the presence of an alkali silanolate. The polymer may be condensed to increase viscosity and decrease the silanol content of the polymer, and volatiles may be removed by stripping. The method provides a high yield of fluorosilicone oil of narrow viscosity ranges in an efficient reaction, and produces small amounts of waste.
摘要翻译：本发明包括在碱性硅铝酸盐存在下使氟硅酮三聚体与三有机硅烷醇反应生产氟硅油的方法。可以将聚合物缩合以增加聚合物的粘度和降低硅烷醇含量，并且挥发物可以通过汽提除去。该方法在有效的反应中提供了具有窄粘度范围的高产率的氟硅油，并且产生少量的废物。

6. 发明授权

US06433204B1 Process for making silanol stopped oligomeric materials 失效
标题翻译：制备硅烷醇停止的低聚物的方法
公开(公告)号：US06433204B1
公开(公告)日：2002-08-13
申请号：US10055199
申请日：2002-01-23
申请人： Nancy E. Gosh , John S. Razzano , Slawomir Rubinsztajn
发明人： Nancy E. Gosh , John S. Razzano , Slawomir Rubinsztajn
IPC分类号： C07F708
CPC分类号： C07F7/0876
摘要： A process for the production of linear silanol stopped siloxanes comprising: a) conducting a ring opening polymerization of a hexaorganocyclotrisiloxane having the formula: D3=(R1R2SiO)3 where R1 and R2 are independently selected from the group of one to forty carbon atom monovalent radicals, in a solvent comprising a mixture of water and a volatile polar aprotic organic solvent in the presence of catalytic amounts of a strong base; b) neutralizing the catalytic amount of the strong base with a partially neutralized salt of a polybasic acid wherein the pH ranges from about 6 to about 8; and c) washing with water.
摘要翻译：一种制备线性硅烷醇封端硅氧烷的方法，包括：a）进行下式的六有机环三硅氧烷的开环聚合：其中R1和R2独立地选自一至四十个碳原子的一价基团，在包含在催化量的强碱存在下，水与挥发性极性非质子有机溶剂的混合物; b）用多碱的部分中和盐中和强碱的催化量，其中pH范围为约6至约8; 和c）用水洗涤。

7. 发明授权

US4780108A Method for increasing bulk density of fillers 失效
标题翻译：增加填料堆积密度的方法
公开(公告)号：US4780108A
公开(公告)日：1988-10-25
申请号：US157095
申请日：1988-02-09
申请人： John S. Razzano
发明人： John S. Razzano
IPC分类号： C04B18/02 , C08K9/06 , C09C1/30 , C09C1/40 , C09C1/56 , C09C3/04 , C05B19/00 , C04B14/00 , C08K3/10
CPC分类号： C09C1/3009 , C04B18/02 , C08K9/06 , C09C1/407 , C09C1/56 , C09C3/046 , C01P2006/10 , Y02W30/94
摘要： There is provided a method for increasing the bulk density of low bulk density materials by intimately admixing a low bulk density material and an organic or organopolysiloxane liquid and thereafter removing substantially all of said organic or organopolysiloxane liquid, for example, by evaporation.
摘要翻译：提供了一种通过紧密混合低体积密度材料和有机或有机聚硅氧烷液体，然后例如通过蒸发除去基本上所有的有机聚硅氧烷液体或有机聚硅氧烷液体来增加低体积密度材料的体积密度的方法。

8. 发明授权

US4222917A Process aids for heat cured silicone rubber compositions 失效
标题翻译：热固化硅橡胶组合物的加工助剂
公开(公告)号：US4222917A
公开(公告)日：1980-09-16
申请号：US970420
申请日：1978-12-18
申请人： John S. Razzano , George P. De Zuba , Ned J. Reo
发明人： John S. Razzano , George P. De Zuba , Ned J. Reo
IPC分类号： C08G77/06 , C08L83/04
CPC分类号： C08G77/06 , C08L83/04 , C08G77/20 , C08G77/70
摘要： There is provided process aids for heat cured silicone rubber compositions which are the reaction product of a cyclictrisiloxane, and water or an aliphatic alcohol found in the presence of a catalyst which may be selected from certain moderate to high strength organic acids, lithium hydroxide, ammonia, ammonium hydroxide and primary amines. The advantage of such a process aid is that it is considerably less expensive to produce in silicone manufacturing facilities than the more traditional process aids that have been used in the past.
摘要翻译：提供了用于热固化的硅橡胶组合物的加工助剂，它们是环状三硅氧烷和在可以选自某种中等至高强度有机酸的氢氧化锂，氨的催化剂存在下发现的水或脂族醇的反应产物，氢氧化铵和伯胺。这种加工助剂的优点在于，与以往已经使用的较传统的加工助剂相比，在硅制造设备中生产成本要低得多。

9. 发明授权

US4177200A Silyl phosphates as neutralizing agents for alkali metal hydroxides 失效
标题翻译：磷酸硅烷酯作为碱金属氢氧化物的中和剂
公开(公告)号：US4177200A
公开(公告)日：1979-12-04
申请号：US854562
申请日：1977-11-25
申请人： John S. Razzano , Louis P. Petersen , Bruce A. Ashby
发明人： John S. Razzano , Louis P. Petersen , Bruce A. Ashby
IPC分类号： C08G77/00 , C07F9/09 , C08G77/04 , C08G77/06 , C08G77/10 , C08G77/32 , C08G77/38 , C07F7/08
CPC分类号： C08G77/045 , C07F9/095
摘要： A silyl phosphate which is an improved neutralizing agent for alkali metal hydroxides in silicone reactions, comprising the reaction product of a linear siloxane, and a phosphorous oxyhalogen or phosphoric acid. The reaction products of the phosphorous oxyhalogen over phosphoric acid are preferred. Such a reaction product is preferred for the continuous neutralization of alkali metal hydroxides in the equilibration of siloxanes.
摘要翻译：甲硅烷基磷酸酯，其是有机硅反应中的碱金属氢氧化物的改进中和剂，其包含直链硅氧烷和磷酸氢氧根或磷酸的反应产物。磷氧基上的卤代磷酸的反应产物是优选的。这种反应产物优选用于在硅氧烷平衡中连续中和碱金属氢氧化物。

10. 发明授权

US3974120A Fluorosilicone copolymers and process for the preparation thereof 失效
标题翻译：氟硅酮共聚物及其制备方法
公开(公告)号：US3974120A
公开(公告)日：1976-08-10
申请号：US574331
申请日：1975-05-05
申请人： John S. Razzano , Verne G. Simpson
发明人： John S. Razzano , Verne G. Simpson
IPC分类号： C08G77/00 , C08G77/04 , C08G77/06 , C08G77/08 , C08G77/22 , C08G77/24 , C08K5/15
CPC分类号： C08G77/08 , C08G77/24
摘要： Diorganopolysiloxane copolymers having a viscosity from 100,000 to 200,000,000 centipoise at 25.degree.C., are produced by (a) forming an admixture of (i) a cyclic alkyl trifluoropropyl trisiloxane, (ii) a second cyclic diorgano trisiloxane, (i) being present in an amount of 40 to 85 mol % of the total of (i) and (ii), (iii) from 5 to 300 parts per million of an alkyl lithium catalyst, the alkyl component containing from 1 to 12 carbon atoms, and (iv) an aprotic solvent, said aprotic solvent being capable of dissolving both the trimers (i) and (ii) and the copolymer product, (b) reacting said admixture at a temperature between 0.degree.C. and 150.degree.C. to form the copolymer, and (c) recovering the copolymer from the reaction mixture.
摘要翻译：通过（a）形成（i）环状烷基三氟丙基三硅氧烷，（ii）第二环状二有机三硅氧烷，（i）存在于（ⅰ）中的第二环状二有机基三硅氧烷的混合物来制备在25℃下具有100,000至200,000,000厘泊粘度的二羟基聚硅氧烷共聚物（i）和（ii），（iii）的总量的40〜85mol％为5〜300ppm的烷基锂催化剂，含有1〜12个碳原子的烷基成分和（iv ）非质子溶剂，所述非质子溶剂能够溶解三聚物（i）和（ii）和共聚物产物，（b）使所述混合物在0℃至150℃之间的温度下反应以形成共聚物，和（c）从反应混合物中回收共聚物。

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