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    • 2. 发明授权
    • Ultrasonically generated paramagnetic polymer particles
    • 超声波生成顺磁聚合物颗粒
    • US06682660B2
    • 2004-01-27
    • US10143903
    • 2002-05-14
    • Irving SucholeikiNak-Ho SungJun Young Lee
    • Irving SucholeikiNak-Ho SungJun Young Lee
    • H01F100
    • C08K3/22Y10T428/2991Y10T428/2998
    • A composite paramagnetic particle and method of making are provided. In one aspect of the invention, a particle comprising a multitude of submicron polymer bead aggregates covalently cross-linked to each other to form larger diameter particles is presented. Distributed throughout the composite paramagnetic particle are vacuous cavities. Each submicron polymer bead has distributed throughout its interior and surface submicron magnetite crystals. In another aspect of the invention, composite particles are made using high energy ultrasound during polymerization of one or more vinyl monomers. In one embodiment, high energy ultrasound is used during an emulsification step and during the early stages of the polymerization process to produce micron sized composite paramagnetic particles. The particles according to the invention exhibit a high percent magnetite incorporation and water and organic solvent stability.
    • 提供复合顺磁性粒子及其制造方法。 在本发明的一个方面,提供了包含彼此共价交联以形成更大直径的颗粒的大量亚微米聚合物珠聚集体的颗粒。 分布在整个复合顺磁颗粒中的是空泡。 每个亚微米聚合物珠分布在其内部和表面亚微米磁铁矿晶体。 在本发明的另一方面,在一种或多种乙烯基单体的聚合过程中,使用高能超声波制备复合颗粒。 在一个实施方案中,在乳化步骤期间和在聚合过程的早期阶段使用高能超声波以产生微米级的复合顺磁性颗粒。 根据本发明的颗粒表现出高百分比的磁铁矿掺入和水和有机溶剂的稳定性。
    • 3. 发明授权
    • Ultrasonically generated paramagnetic polymer particles
    • 超声波生成顺磁聚合物颗粒
    • US06423410B1
    • 2002-07-23
    • US09365506
    • 1999-08-02
    • Irving SucholeikiNak-Ho SungJun Young Lee
    • Irving SucholeikiNak-Ho SungJun Young Lee
    • B32B516
    • C08K3/22Y10T428/2991Y10T428/2998
    • A composite paramagnetic particle and method of making are provided. In one aspect of the invention, a particle comprising a multitude of submicron polymer bead aggregates covalently cross-linked to each other to form larger diameter particles is presented. Distributed throughout the composite paramagnetic particle are vacuous cavities. Each submicron polymer bead has distributed throughout its interior and surface submicron magnetite crystals. In another aspect of the invention, composite particles are made using high energy ultrasound during polymerization of one or more vinyl monomers. In one embodiment, high energy ultrasound is used during an emulsification step and during the early stages of the polymerization process to produce micron sized composite paramagnetic particles. The particles according to the invention exhibit a high percent magnetite incorporation and water and organic solvent stability.
    • 提供复合顺磁性粒子及其制造方法。 在本发明的一个方面,提供了包含彼此共价交联以形成更大直径的颗粒的大量亚微米聚合物珠聚集体的颗粒。 分布在整个复合顺磁颗粒中的是空泡。 每个亚微米聚合物珠分布在其内部和表面亚微米磁铁矿晶体。 在本发明的另一方面,在一种或多种乙烯基单体的聚合过程中,使用高能超声波制备复合颗粒。 在一个实施方案中,在乳化步骤期间和在聚合过程的早期阶段使用高能超声波以产生微米级的复合顺磁性颗粒。 根据本发明的颗粒表现出高百分比的磁铁矿掺入和水和有机溶剂的稳定性。