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1. 发明专利

JP2008214481A Nanomatrix-dispersed natural rubber and method for producing the same 有权
标题翻译：纳米级分散的天然橡胶及其制造方法
公开(公告)号：JP2008214481A
公开(公告)日：2008-09-18
申请号：JP2007053342
申请日：2007-03-02
申请人： Nagaoka Univ Of Technology , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人長岡技術科学大学
发明人： TASHIRO HIROSHI , KAWAHARA NARIMOTO , ISONO YOSHINOBU
IPC分类号： C08F253/00 , C08C1/04
摘要： PROBLEM TO BE SOLVED: To provide a natural rubber exerting various functions of a graft polymer while retaining excellent properties inherent in a natural rubber (e.g. properties as a damping material).
SOLUTION: The nanomatrix-dispersed natural rubber comprises a grafted natural rubber wherein vinyl monomers are grafted onto the surface of deproteinized natural rubber particles. The nanomatrix-dispersed natural rubber is produced by deproteinizing a natural rubber latex, introducing radical active points onto the surface of rubber particles with a water-soluble radical initiator, adding a monomer to carry out graft copolymerization on the surface of the natural rubber particles, making the obtained latex into a film or a bulk form and subjecting it to a heat-treatment at a temperature ranging from (Tg)-20°C to (Tg)+30°C, provided that (Tg) is the glass transition temperature of a polymer forming a graft chain. In the nanomatrix-dispersed natural rubber, the natural rubber particles are connected to each other and dispersed layeredly in a matrix 1-100 nm thick formed by the graft chain.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种在保持天然橡胶（例如阻尼材料的性能）中固有的优异性能的同时承载接枝聚合物的各种功能的天然橡胶。解决方案：纳米片分散的天然橡胶包括接枝天然橡胶，其中乙烯基单体接枝到脱蛋白天然橡胶颗粒的表面上。纳米片分散的天然橡胶通过对天然橡胶胶乳进行去蛋白化，通过水溶性自由基引发剂将自由基活性点引入橡胶颗粒表面，加入单体以在天然橡胶颗粒表面进行接枝共聚，将所得胶乳制成膜或块状，并在（Tg）-20℃至（Tg）+ 30℃的温度范围内进行热处理，条件是（Tg）为玻璃化转变温度形成接枝链的聚合物。在纳米级分散的天然橡胶中，将天然橡胶颗粒彼此连接并分层分散在由接枝链形成的1-100nm厚的基质中。版权所有（C）2008，JPO＆INPIT

2. 发明专利

JP2005015614A Allergen-removed natural rubber latex and method of producing the same 有权
标题翻译：过敏脱除天然橡胶胶乳及其制造方法
公开(公告)号：JP2005015614A
公开(公告)日：2005-01-20
申请号：JP2003181836
申请日：2003-06-25
申请人： Nagaoka Univ Of Technology , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人長岡技術科学大学
发明人： KAWAHARA NARIMOTO , ISONO YOSHINOBU , TASHIRO HIROSHI , SUZUKI YASUYUKI , SUZUKI NORIYUKI
IPC分类号： C08C1/04
摘要： PROBLEM TO BE SOLVED: To provide a highly allergen-removed natural rubber latex which has an extremely low possibility to induce allergy, and to provide a method of producing the same.
SOLUTION: The allergen-removed natural rubber latex characterised in that the content of protein in crude rubber of natural rubber latex is a level of 0.01% or less in terms of nitrogen content, and the allergen concentration in the natural rubber latex as measured by the LEAP (latex enzyme-linked immunosorbent assay for antigenic protein) method is 1.5μg/ml or less, is obtained by adding a protein denaturant composed of a urea compound into a fresh natural rubber latex, denaturing the protein in the latex and then removing the denatured protein.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种具有非常低的诱导过敏可能性的高度变应原去除的天然橡胶胶乳，并提供其制备方法。解决方案：去除过敏原的天然橡胶胶乳的特征在于，天然橡胶胶乳的粗制橡胶中的蛋白质含量以氮含量计为0.01％以下，天然橡胶胶乳中的变应原浓度为通过LEAP（抗原蛋白的胶乳酶联免疫吸附测定法）测定的方法为1.5μg/ ml以下，通过将由尿素化合物组成的蛋白质变性剂添加到新鲜天然橡胶胶乳中，使胶乳中的蛋白质变性和然后除去变性蛋白质。版权所有（C）2005，JPO＆NCIPI

3. 发明专利

JP2005281681A Process for producing deproteinized natural rubber latex 有权
标题翻译：生产天然橡胶橡胶的方法
公开(公告)号：JP2005281681A
公开(公告)日：2005-10-13
申请号：JP2005036446
申请日：2005-02-14
申请人： Nagaoka Univ Of Technology , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人長岡技術科学大学
发明人： TASHIRO HIROSHI , SUZUKI YASUYUKI , KAWAHARA NARIMOTO , ISONO YOSHINOBU
IPC分类号： C08C1/04
CPC分类号： C08C1/04
摘要： PROBLEM TO BE SOLVED: To provide a process for producing a deproteinized natural rubber latex substantially not containing any allergy inducing proteins and peptide in an industrial massive scale at a low cost.
SOLUTION: The process for producing the deproteinized natural rubber latex is characterized by including a step of adding a urea-base protein modifier and a surfactant to a raw natural rubber latex, a step of modifying any protein contained in the raw natural rubber latex as mixing them with transferring them through a flow channel, and a step of performing separation and removal of the result modified protein.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种以低成本生产工业上大规模生产基本上不含过敏诱导蛋白质和肽的脱蛋白天然橡胶胶乳的方法。解决方案：生产脱蛋白天然橡胶胶乳的方法的特征在于包括向原始天然橡胶胶乳中加入尿素基蛋白改性剂和表面活性剂的步骤，改变原料天然橡胶中所含的任何蛋白质的步骤将其混合并通过流动通道转移它们的胶乳，以及进行分离和去除结果改性蛋白质的步骤。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2013111940A Vulcanizate and method for producing the same 审中-公开
标题翻译： VULCANATEATE及其生产方法
公开(公告)号：JP2013111940A
公开(公告)日：2013-06-10
申请号：JP2011262559
申请日：2011-11-30
申请人： Nagaoka Univ Of Technology , 国立大学法人長岡技術科学大学 , Denki Kagaku Kogyo Kk , 電気化学工業株式会社
发明人： ISONO YOSHINOBU , KOBAYASHI NAOKI , ABE YASUSHI
IPC分类号： B29C35/02 , C08J3/24 , C08K3/36 , C08K5/54 , C08L7/00 , C08L9/00
摘要： PROBLEM TO BE SOLVED: To provide a vulcanizate which can be converted into a low temperature generation material by a simpler method without depending on a specific rubber composition, a vulcanization system, and a compounding component and a method for producing the vulcanizate.SOLUTION: First, an unvulcanized rubber composition at least containing natural rubber and/or synthetic rubber and a filler is vulcanized/molded to obtain a semi-vulcanized molding having a vulcanization characteristic value obtained by a method regulated by JIS K6300-2:2001 of t-t. Next, the semi-vulcanized molding obtained by a semi-vulcanization molding process is vulcanized again while being deformed as a whole. After that, the deformation is released to obtain the vulcanizate in a purposed shape.
摘要翻译：待解决的问题：提供一种可以通过简单的方法转变成低温发生材料的硫化橡胶，而不依赖于特定的橡胶组合物，硫化体系和配混组分以及硫化橡胶的制备方法。解决方案：首先，将至少含有天然橡胶和/或合成橡胶和填料的未硫化橡胶组合物硫化/模塑以获得具有由JIS K6300-2规定的方法获得的硫化特性值的半硫化成型：00 -t 80 。接下来，通过半硫化成型法得到的半硫化成型体在整体变形的同时再次硫化。之后，释放变形以获得目的形状的硫化橡胶。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2005015516A Thermosetting water-based coating composition and method for forming multi-layered coating film 有权
标题翻译：基于水性涂料的热浸涂料组合物和形成多层涂膜的方法
公开(公告)号：JP2005015516A
公开(公告)日：2005-01-20
申请号：JP2003177950
申请日：2003-06-23
申请人： Kansai Paint Co Ltd , Nagaoka Univ Of Technology , 国立大学法人長岡技術科学大学 , 関西ペイント株式会社
发明人： OGAWA TETSUO , KAWAHARA NARIMOTO , ISONO YOSHINOBU
IPC分类号： B05D5/00 , B05D7/24 , C09D7/12 , C09D107/02 , C09D151/04 , C09D201/00
摘要： PROBLEM TO BE SOLVED: To provide a thermosetting water-based coating composition capable of forming a coating film excellent in chipping resistance, adhesiveness to various coated objects or an adjacent coating film, and the like; and a method for forming a multi-layered coating film using the composition.
SOLUTION: The thermosetting water-based coating composition comprises (A) an aqueous resin having cross-linking functional groups, (B) a cross-linking agent, and (C) a natural rubber latex. The method for forming a multi-layered coating film uses the composition.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种能够形成耐切削性，对各种涂覆物或相邻涂膜的粘附性等的涂膜的热固性水性涂料组合物; 以及使用该组合物形成多层涂膜的方法。解决方案：热固性水性涂料组合物包含（A）具有交联官能团的水性树脂，（B）交联剂和（C）天然橡胶胶乳。形成多层涂膜的方法使用该组合物。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2013216029A Vulcanizate and method for production thereof 有权
标题翻译： VULCANATEATE及其生产方法
公开(公告)号：JP2013216029A
公开(公告)日：2013-10-24
申请号：JP2012089829
申请日：2012-04-11
申请人： Nagaoka Univ Of Technology , 国立大学法人長岡技術科学大学 , Denki Kagaku Kogyo Kk , 電気化学工業株式会社
发明人： ISONO YOSHINOBU , KOBAYASHI NAOKI , ABE YASUSHI
IPC分类号： B29C35/02 , B29K21/00 , B29K105/24
CPC分类号： C08K3/04 , B29C35/02 , B29K2011/00 , C08L11/00
摘要： PROBLEM TO BE SOLVED: To provide a vulcanizate comprising a carbon black-containing chloroprene rubber composition and capable of exhibiting a low heat buildup, and to provide a method for production thereof.SOLUTION: A method for production of a vulcanizate includes subjecting an unvulcanized rubber composition comprising at least a chloroprene polymer and carbon black to vulcanization molding to form a semivulcanized molded body having a vulcanization characteristic value in a range of tto tobtained by a method stipulated in JIS K6300-2:2001; vulcanizing the semivulcanized molded body again in a wholly deformed state; and then releasing the deformation to obtain a vulcanizate having an objective shape.
摘要翻译：要解决的问题：提供一种含有含炭黑的氯丁二烯橡胶组合物并且能够发挥低发热性的硫化橡胶，并提供其制造方法。解决方案：一种生产硫化橡胶的方法包括将未硫化橡胶组合物，其至少包含氯丁二烯聚合物和炭黑进行硫化成型，以形成硫化特性值在tto范围内的半硫化成型体，其通过JIS K6300-2：2001中规定的方法来实现; 再次以完全变形的状态硫化半硫化成型体; 然后释放变形，得到具有目标形状的硫化橡胶。

7. 发明专利

JP2004155884A Nanomatrix-dispersed natural rubber and method for producing the same 有权
标题翻译：纳米级分散的天然橡胶及其制造方法
公开(公告)号：JP2004155884A
公开(公告)日：2004-06-03
申请号：JP2002322130
申请日：2002-11-06
申请人： Nagaoka Univ Of Technology , 長岡技術科学大学長
发明人： KAWAHARA NARIMOTO , ISONO YOSHINOBU
IPC分类号： C08F253/00 , C08C1/04
摘要： PROBLEM TO BE SOLVED: To provide a nanomatrix-dispersed natural rubber having such peculiar phase-separated structure that natural rubber particles as the main component dispersed in fine matrix formed by graft chains as the minor component, having graft polymer properties as well as excellent properties inherent in natural rubber and widely usable in the medical field including condoms, gloves for operation and catheters and as domestic articles or the like.
SOLUTION: The nanomatrix-dispersed natural rubber consists of a grafted natural rubber where vinyl monomers are grafted onto the surface of deproteinized natural rubber particles, produced by deproteinizing a natural rubber latex, introducing radical active points on the surface of rubber particles with a water-soluble radical initiator followed by addition of the vinyl monomer to carry out a graft copolymerization on the surface of the natural rubber particles, and subjecting the resultant latex to film formation. In this nanomatrix-dispersed natural rubber, the natural rubber particles are dispersed in a matrix 1-100 nm thick formed by the graft chains.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供具有这样特殊的相分离结构的纳米片分散的天然橡胶，其中天然橡胶颗粒作为主要组分分散在由接枝链形成的细小基质中作为次要组分，具有接枝聚合物性质作为天然橡胶固有的优异性质，广泛用于医疗领域，包括避孕套，操作手套和导管以及家用制品等。解决方案：纳米片分散的天然橡胶由接枝的天然橡胶组成，其中乙烯基单体接枝到脱蛋白天然橡胶颗粒的表面上，通过对天然橡胶胶乳进行去蛋白化，将橡胶颗粒表面上的自由基活性点引入水溶性自由基引发剂，然后加入乙烯基单体以在天然橡胶颗粒的表面上进行接枝共聚，并对所得胶乳进行成膜。在该纳米线分散的天然橡胶中，将天然橡胶颗粒分散在由接枝链形成的1-100nm厚的基质中。版权所有（C）2004，JPO

8. 发明专利

JP2004099696A Method for producing protein-removed natural rubber latex 有权
公开(公告)号：JP2004099696A
公开(公告)日：2004-04-02
申请号：JP2002261693
申请日：2002-09-06
申请人： Nagaoka Univ Of Technology , 長岡技術科学大学長
发明人： KAWAHARA NARIMOTO , WARUNEE KLINKLAI , ISONO YOSHINOBU
IPC分类号： C08J3/02 , C08C1/04 , C08C2/02
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a protein-removed natural rubber latex, by which the natural rubber latex having an extremely small protein content and not causing a side reaction, when used as an industrial raw material, can be produced in a large amount at a low cost.
SOLUTION: This method for producing the protein-removed natural rubber latex is characterized by adding a protein-denaturing agent selected from the group consisting of urea compounds and NaClO to a natural rubber latex to denature proteins in the latex, and then removing the denatured proteins. A desired urea compound includes urea, a lower alkyl urea, or a urea double salt.
COPYRIGHT: (C)2004,JPO

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