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1. 发明申请

US20100031976A1 Detergent 审中-公开
标题翻译：洗涤剂
公开(公告)号：US20100031976A1
公开(公告)日：2010-02-11
申请号：US12536885
申请日：2009-08-06
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： B08B9/20 , C11D3/37
CPC分类号： C11D3/33 , C11D3/2086 , C11D3/3757 , C11D3/378 , C11D3/3942
摘要： Phosphate-free automatic dishwashing agents containing a) citrate, b) sodium percarbonate, c) nonionic surfactant, d) copolymer encompassing i) monomers from the group of the mono- or polyunsaturated carboxylic acids, ii) monomers of the general formula R1(R2)C═C(R3)—X—R4, in which R1 to R3, mutually independently, denote —H, —CH3, or —C2H5, X denotes an optionally present spacer group that is selected from —CH2—, —C(O)O—, and —C(O)—NH—, and R4 denotes a straight-chain or branched saturated alkyl residue having 2 to 22 carbon atoms or an unsaturated, preferably aromatic residue having 6 to 22 carbon atoms, e) 0.05 to 1 wt % methylglycinediacetic acid, are notable for washing and rinsing results that are comparable or even superior to those of phosphate-containing automatic dishwashing agents.
摘要翻译：含有a）柠檬酸盐，b）过碳酸钠的无磷酸盐自动洗碗剂，c）非离子表面活性剂，d）共聚物，包括i）单或多不饱和羧酸基团的单体，ii）通式R 1（R 2 ）CC（R3）-X-R4，其中R1至R3相互独立地表示-H，-CH3或-C2H5，X表示任选存在的间隔基，其选自-CH 2 - ， - C（O） O-和-C（O）-NH-，R 4表示具有2至22个碳原子的直链或支链饱和烷基或不饱和的，优选具有6至22个碳原子的芳族残基，e）0.05至1 重量％甲基甘氨酸二乙酸，对于与含磷酸盐的自动洗碗剂相当甚至更优异的洗涤和漂洗结果是显着的。

2. 发明申请

US20100029536A1 Detergents 有权
标题翻译：洗涤剂
公开(公告)号：US20100029536A1
公开(公告)日：2010-02-04
申请号：US12535956
申请日：2009-08-05
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： C11D3/36
CPC分类号： C11D3/378 , C11D3/2086 , C11D3/361
摘要： Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomer, and b) phosphonate. The detergents have good scale-inhibiting, cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译：含有助洗剂，漂白剂，非离子表面活性剂，以及a）包含i）含磺酸基单体的共聚物，ii）其它离子和/或非离子单体和b）膦酸酯的无磷酸盐洗碗机洗涤剂。洗涤剂具有良好的阻垢，清洁和漂洗结果，与含磷酸盐的洗碗机洗涤剂相当，甚至超过它们。

3. 发明授权

US07879154B2 Phosphate-free dishwashing detergents comprising builder, bleaching agent, nonionic surfactant, copolymer and a phosphonate 有权
标题翻译：不含磷酸盐的餐具洗涤剂包括助洗剂，漂白剂，非离子表面活性剂，共聚物和膦酸盐
公开(公告)号：US07879154B2
公开(公告)日：2011-02-01
申请号：US12535956
申请日：2009-08-05
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： B08B3/04 , C11D1/66 , C11D3/37 , C11D3/395
CPC分类号： C11D3/378 , C11D3/2086 , C11D3/361
摘要： Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomer, and b) phosphonate. The detergents have good scale-inhibiting, cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译：含有助洗剂，漂白剂，非离子表面活性剂，以及a）包含i）含磺酸基单体的共聚物，ii）其它离子和/或非离子单体和b）膦酸酯的无磷酸盐洗碗机洗涤剂。洗涤剂具有良好的阻垢，清洁和漂洗结果，与含磷酸盐的洗碗机洗涤剂相当，甚至超过它们。

4. 发明授权

US08303721B2 Detergent comprising a builder, a bleaching agent, and a copolymer 有权
标题翻译：洗涤剂，其包含助洗剂，漂白剂和共聚物
公开(公告)号：US08303721B2
公开(公告)日：2012-11-06
申请号：US12535927
申请日：2009-08-05
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： B08B3/04 , C11D1/72 , C11D3/37 , C11D3/395
CPC分类号： C11D3/37 , C11D1/721
摘要： A phosphate-free dishwasher detergent which contains a builder, bleaching agents, and also a) a copolymer comprising i) monomers from the group of mono- or polyunsaturated carboxylic acids; ii) monomers of general formula R1(R2)C═C(R3)—X—R4; and iii) optionally further monomers, and b) a nonionic surfactant of general formula R1—CH(OH)CH2O-(AO)w-(A′O)x-(A″O)y-(A′″O)z—R2. The detergent has good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译：一种含磷酸盐的洗碗机洗涤剂，其含有助洗剂，漂白剂，以及a）包含i）单体或多不饱和羧酸的单体的共聚物; ii）通式R 1（R 2）C = C（R 3）-X-R 4的单体; 和（b）通式为R 1 -CH（OH）CH 2 O-（AO）w - （A'O）x - （A“O）y - （A'”O）z的非离子表面活性剂 -R2。洗涤剂具有良好的清洗和漂洗结果，与含磷酸盐的洗碗机洗涤剂相当，甚至超过它们。

5. 发明申请

US20100041575A1 Detergents 有权
标题翻译：洗涤剂
公开(公告)号：US20100041575A1
公开(公告)日：2010-02-18
申请号：US12535991
申请日：2009-08-05
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： C11D3/395
CPC分类号： C11D3/33 , C11D1/72 , C11D1/722 , C11D3/042 , C11D3/075 , C11D3/361 , C11D3/3757 , C11D3/378 , C11D3/3902 , C11D3/3942
摘要： Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomers, b) methyl glycine diacetic acid. The detergents according to the invention have good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译：含有助洗剂，漂白剂，非离子表面活性剂的a）含有i）含磺酸基单体的共聚物，ii）其它离子和/或非离子单体，b）甲基甘氨酸二乙酸。根据本发明的洗涤剂具有良好的清洁和漂洗结果，其与含磷酸盐洗碗机洗涤剂的洗涤剂相当，甚至超过它们。

6. 发明授权

US09752100B2 Detergents 有权
公开(公告)号：US09752100B2
公开(公告)日：2017-09-05
申请号：US12535991
申请日：2009-08-05
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： C11D1/72 , C11D1/722 , C11D3/395 , C11D3/37 , C11D3/33 , C11D3/075 , C11D3/39 , C11D3/04 , C11D3/36
CPC分类号： C11D3/33 , C11D1/72 , C11D1/722 , C11D3/042 , C11D3/075 , C11D3/361 , C11D3/3757 , C11D3/378 , C11D3/3902 , C11D3/3942
摘要： Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomers, b) methyl glycine diacetic acid. The detergents according to the invention have good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.

7. 发明申请

US20100093588A1 Detergent 有权
标题翻译：洗涤剂
公开(公告)号：US20100093588A1
公开(公告)日：2010-04-15
申请号：US12535927
申请日：2009-08-05
申请人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人： Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号： C11D1/72 , C11D3/395 , C11D3/37
CPC分类号： C11D3/37 , C11D1/721
摘要： A phosphate-free dishwasher detergent which contains a builder, bleaching agents, and also a) a copolymer comprising i) monomers from the group of mono- or polyunsaturated carboxylic acids; ii) monomers of general formula R1(R2)C═C(R3)—X—R4; and iii) optionally further monomers, and b) a nonionic surfactant of general formula R1—CH(OH)CH2O-(AO)w-(A′O)x-(A″O)y-(A′″O)z—R2. The detergent has good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译：一种含磷酸盐的洗碗机洗涤剂，其含有助洗剂，漂白剂，以及a）包含i）单体或多不饱和羧酸的单体的共聚物; ii）通式R 1（R 2）C = C（R 3）-X-R 4的单体; 和（b）通式为R 1 -CH（OH）CH 2 O-（AO）w-（A'O）x-（A“O）y - （A'O）z的非离子表面活性剂 -R2。洗涤剂具有良好的清洗和漂洗结果，与含磷酸盐的洗碗机洗涤剂相当，甚至超过它们。

8. 发明申请

US20100024846A1 Detergents 审中-公开
标题翻译：洗涤剂
公开(公告)号：US20100024846A1
公开(公告)日：2010-02-04
申请号：US12536879
申请日：2009-08-06
申请人： Nadine Warkotsch , Johannes Zipfel , Christian Nitsch , Arnd Kessler , Thomas Holderbaum , Cornelius Bessler , Susanne Tondra , Thomas Mueller-Kirschbaum , Sven Mueller , Arno Dueffels
发明人： Nadine Warkotsch , Johannes Zipfel , Christian Nitsch , Arnd Kessler , Thomas Holderbaum , Cornelius Bessler , Susanne Tondra , Thomas Mueller-Kirschbaum , Sven Mueller , Arno Dueffels
IPC分类号： A47L15/44 , C11D3/37
CPC分类号： C11D3/2086 , C11D1/66 , C11D3/3757 , C11D3/378 , C11D3/38672 , C11D3/3932
摘要： Phosphate-free, bleaching agent-containing dishwasher detergents which contain a) citrate, b) bleaching catalyst selected from the group consisting of the bleach-boosting transition metal salts and transition metal complexes, c) copolymer(s) which comprise i) one or more acid group-containing monomer, ii) one or more additional hydrophobic monomer. The detergents have an improved bleaching action.
摘要翻译：含有不含漂白剂的洗碗机洗涤剂，其含有a）柠檬酸盐，b）漂白催化剂，其选自漂白助剂过渡金属盐和过渡金属配合物，c）共聚物，其包含i）一种或多种更多含酸基团的单体，ii）一种或多种另外的疏水性单体。洗涤剂具有改善的漂白作用。

9. 发明申请

US20110232692A1 AUTOMATIC DISHWASHING AGENT 有权
标题翻译：自动洗衣机
公开(公告)号：US20110232692A1
公开(公告)日：2011-09-29
申请号：US13151487
申请日：2011-06-02
申请人： Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
发明人： Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
IPC分类号： A47L15/42 , C11D3/60
CPC分类号： C11D1/825 , C11D1/721 , C11D3/3757 , C11D3/378 , C11D3/386
摘要： An automatic dishwashing agent includes builder(s), enzyme(s) and a) a nonionic surfactant A of the general formula R1O(AlkO)xM(OAlk)yOR2, in which R1 and R2 mutually independently denote a branched or unbranched, saturated or unsaturated, optionally hydroxylated alkyl residue with 4 to 22 carbon atoms; Alk denotes a branched or unbranched alkyl residue with 2 to 4 carbon atoms; x and y mutually independently denote values between 1 and 70; and M denotes an alkyl residue from the group CH2, CHR3, CR3R4, CH2CHR3 and CHR3CHR4, with R3 and R4 mutually independently denoting a branched or unbranched, saturated or unsaturated alkyl residue with 1 to 18 carbon atoms; b) a nonionic surfactant B which differs from the nonionic surfactant A; and c) an anionic copolymer C. The agent imparts an improved drying and rinsing result.
摘要翻译：自动洗碗剂包括助洗剂，酶和a）通式R 1 O（AlkO）x M（OAlk）yOR 2的非离子表面活性剂A，其中R 1和R 2相互独立地表示支链或非支链饱和或不饱和的，任选羟基化的具有4至22个碳原子的烷基; Alk表示具有2至4个碳原子的支链或非支链烷基; x和y相互独立地表示1和70之间的值; 并且M表示CH 2，CHR 3，CR 3 R 4，CH 2 CHR 3和CHR 3 CHR 4基团的烷基，R3和R4相互独立地表示具有1至18个碳原子的支链或非支链，饱和或不饱和的烷基; b）与非离子表面活性剂A不同的非离子表面活性剂B; 和c）阴离子共聚物C.该试剂赋予改进的干燥和漂洗结果。

10. 发明申请

US20100160204A1 Detergents 审中-公开
标题翻译：洗涤剂
公开(公告)号：US20100160204A1
公开(公告)日：2010-06-24
申请号：US12720781
申请日：2010-03-10
申请人： Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch
发明人： Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch
IPC分类号： C11D3/37
CPC分类号： C11D1/721 , C11D1/22 , C11D1/722 , C11D3/378
摘要： Dishwasher detergents containing: a) 10 to 60 percent by weight of a builder; and b) non-ionic surfactant of the general formula R1O[CH2CH(CH3)O]x[CH2CH2O]y[CH2CH(CH3)O]zCH2CH(OH)R2 wherein R1 is a linear or branched aliphatic hydrocarbon radical having 4 to 22 carbon atoms or mixtures thereof, R2 is a linear or branched hydrocarbon radical having 2 to 26 carbon atoms or mixtures thereof, x and z represent values between 0 and 40, and y represents a value of at least 15; c) anionic copolymer comprising: i) unsaturated carboxylic acids, ii) sulfonic acid group-containing monomers, wherein the weight ratio of components c) to b) is less than 3:1. In addition to exhibiting good cleaning and rinsing efficiency, dishwasher detergents according to the invention enhance the drying process of the cleaned dishes.
摘要翻译：洗碗机洗涤剂，其含有：a）10至60重量％的助洗剂; 和b）具有通式R 1 O [CH 2 CH（CH 3）O] x [CH 2 CH 2 O] y [CH 2 CH（CH 3）O] z CH 2 CH（OH）R 2的非离子表面活性剂，其中R 1是具有4至22的直链或支链脂族烃基碳原子或其混合物，R2是具有2至26个碳原子的直链或支链烃基或其混合物，x和z表示0至40之间的值，y表示至少15的值; c）阴离子共聚物，其包含：i）不饱和羧酸，ii）含磺酸基团的单体，其中组分c）至b）的重量比小于3:1。除了表现出良好的清洁和漂洗效率之外，根据本发明的洗碗机洗涤剂增强了清洁的餐具的干燥过程。

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