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1. 发明申请

WO2009018924A4 REGENERATION OF CATALYSTS FOR DEHYDRATING ALKANES 审中-公开
标题翻译：烷烃脱水催化剂的再生
公开(公告)号：WO2009018924A4
公开(公告)日：2009-04-02
申请号：PCT/EP2008006059
申请日：2008-07-24
申请人： UHDE GMBH , GEHRKE HELMUT , HEINRITZ-ADRIAN MAX , MIAN MUHAMMAD IQBAL , NOLL OLIVER , SCHWASS ROLF , WENZEL SASCHA
发明人： GEHRKE HELMUT , HEINRITZ-ADRIAN MAX , MIAN MUHAMMAD IQBAL , NOLL OLIVER , SCHWASS ROLF , WENZEL SASCHA
IPC分类号： C07C5/333 , B01J38/12 , B01J38/16
CPC分类号： C07C5/3335 , B01J23/24 , B01J23/40 , B01J38/06 , B01J38/16 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/06 , C07C2523/14 , C07C2523/24 , C07C2523/74 , Y02P20/584
摘要： The invention relates to a method for dehydrating alkanes, wherein the alkane is guided in a reactor for the dehydration of alkanes via a catalyst, and the process may be carried out adiabatically or non-adiabatically, and the catalyst for dehydration can be regenerated after the reaction phase by means of transferring a gas, wherein said gas is guided via the catalyst after a short rinsing phase using water vapor, and said regeneration gas consists of a gas containing oxygen and of steam, and after regeneration the catalyst is freed of the gas containing oxygen by transferring steam, wherein the duration of the transfer of a gas containing oxygen is significantly reduced as compared to common methods and represents 70% or less of the total regeneration time, and the catalyst has an increased selectivity for forming alkene by means of carrying out the regeneration at a constant activity, and the catalyst is comprised of a metal of the group of platinum metals or of the group VIB of the periodic table of the elements, which is applied to a carrier in the form of a compound or in elementary form, which substantially consists of oxides of the elements of tin, zinc, or aluminum.
摘要翻译：本发明涉及一种方法，用于烷烃的脱氢，其中所述烷烃进料至用于与催化剂和过程的烷烃的脱氢反应器可以绝热的或不绝热进行，并脱氢的催化剂是通过使气体，其中一个反应阶段之后再生这种气体与水蒸气在催化剂和由含氧气体和蒸汽以及通过从含氧气体蒸气的流通的再生后的催化剂的该再生气体短暂漂洗阶段之后被传递被释放，其特征在于，含氧气体在转移的持续时间与常规方法相比是显著缩短，并且在相对于所述再生的总持续时间为70％或以下，并且以恒定的活性进行再生后的催化剂，增加的选择性烯烃的形成是坐在和所述催化剂包含选自铂的金属或元素，其以化合物的形式或以单质形式施加的周期表第VIB族的金属，基本上由元素锡，锌或铝的氧化物的载体上，

2. 发明专利

EG26205A Regeneration of catalysts for dehydrating alkanes 未知
公开(公告)号：EG26205A
公开(公告)日：2013-04-28
申请号：EG2010020174
申请日：2010-02-02
申请人： NOLL OLIVER , SCHWASS ROLF , WENZEL SASCHA
发明人： GEHRKE HELMUT , HEINRITZ-ADRIAN MAX , MIAN MUHAMMAD IQBAL
IPC分类号： C07C5/333 , B01J38/12 , B01J38/16
摘要： The invention relates to a method for dehydrating alkanes, wherein the alkane is guided in a reactor for the dehydrogenation of alkanes via a catalyst, and the process may be carried out adiabatically or non-adiabatically, and the catalyst for dehydration can be regenerated after the reaction phase by means of transferring a gas, wherein said gas is guided via the catalyst after a short rinsing phase using water vapor, and said regeneration gas consists of a gas containing oxygen and of steam, and after regeneration the catalyst is freed of the gas containing oxygen by transferring steam, wherein the duration of the transfer of a gas containing oxygen is significantly reduced as compared to common methods and represents 70% or less of the total regeneration time, and the catalyst has an increased selectivity for forming alkene by means of carrying out the regeneration at a constant activity, and the catalyst is comprised of a metal of the group of platinum metals or group VIB of the periodic table of the elements, which is applied to a carrier in form of a compound or in elementary form, which substantially consists of oxides of the elements of tin, zinc, or aluminum.

3. 发明申请

WO2010069548A4 VARIATION OF THE TIN IMPREGNATION OF A CATALYST FOR THE DEHYDROGENATION OF ALKANES 审中-公开
标题翻译： ZINNIMPRÄGNIERUNG变异性的脱水的烷催化合成
公开(公告)号：WO2010069548A4
公开(公告)日：2010-08-19
申请号：PCT/EP2009008976
申请日：2009-12-15
申请人： UHDE GMBH , MIAN MUHAMMAD IQBAL , HEINRITZ-ADRIAN MAX , WENZEL SASCHA , NOLL OLIVER , SCHWEFER MEINHARD , GEHRKE HELMUT
发明人： MIAN MUHAMMAD IQBAL , HEINRITZ-ADRIAN MAX , WENZEL SASCHA , NOLL OLIVER , SCHWEFER MEINHARD , GEHRKE HELMUT
IPC分类号： B01J23/62 , B01J35/00 , C07C5/333 , C07C11/06
CPC分类号： B01J23/626 , B01J23/005 , B01J35/002 , B01J37/0207 , C07C5/3337 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/42 , Y02P20/52 , C07C11/08 , C07C11/06 , C07C15/46 , C07C11/09 , C07C11/167
摘要： The invention relates to a catalyst for the dehydrogenation of alkanes or alkyl substituents of hydrocarbons, comprising a shaped body having at least one or more oxides from the elements of the main or secondary group II to IV of the periodic table or of an oxidic mixed compound based thereon, wherein the constituents serve as base material of the shape body. The catalyst further comprises an additional constituent having an oxide of an element of the main group IV of the periodic table that is added during the shaping process. A platinum compound and a compound made of an element of the main group IV of the periodic table is chosen as a surface constituent of the catalyst. The invention further relates to the production of the catalyst from the claimed materials by means of different process steps and to a method for the dehydrogenation of alkanes using the catalyst according to the invention.
摘要翻译：本发明涉及一种用于烷烃或烃类的烷基取代基，其包括一个成形体，其由II的元素中的至少一种或多种氧化物的脱氢催化剂。为了IV。Main或周期系的亚组或由其混合氧化物化合物构成，所述服务成分作为成型体的基体材料中，辅助组分包括IV的元素的氧化物。元素周期表，这是在模制工艺过程中加入的，并且其中所选择的铂化合物和Ⅳ的元素的化合物的主要组。元素周期表的主族作为催化剂的表面组分是。本发明还包括与所要求保护的材料的催化剂的由不同的方法步骤的装置的制备，和一种用于烷烃的本发明的催化剂的脱氢。

4. 发明申请

WO2009024259A2 EXTRACTION OF BENZOL AND BENZOL DERIVATIVES FROM GASOLINE FRACTIONS AND REFINERY FLOWS 审中-公开
标题翻译：从PETROL和RAFFINERIESTRÖMEN中提取苯和苯的收集
公开(公告)号：WO2009024259A2
公开(公告)日：2009-02-26
申请号：PCT/EP2008006415
申请日：2008-08-05
申请人： UHDE GMBH , NOLL OLIVER , GEHRKE HELMUT , LUEBBECKE CHRISTIAN , KOLBE BAERBEL
发明人： NOLL OLIVER , GEHRKE HELMUT , LUEBBECKE CHRISTIAN , KOLBE BAERBEL
IPC分类号： B01D3/40 , C07C7/08 , C07C15/04 , C07C15/06 , C07C15/08 , C10G7/08
CPC分类号： C07C7/10 , B01D3/40 , C07C7/08 , C07C15/04 , C07C15/06 , C07C15/08 , C10G2400/06
摘要： The invention relates to a method for separating the aromatic compounds benzol, toluene, and XyIoI from a reformate and pyrolysis gasoline containing aromatic compounds, or a coke benzol, or a refinery flow containing aromatic compounds, wherein extractive distillation is utilized for separating the aromatic compounds, using a novel solvent combination made up of the compounds N,N'-diformyl piperazine or 2,2'-bis-(cyan ethyl)ether in combination with N formyl morpholine as the second solvent for the extractive distillation such that the solvent combination obtained has an increased selectivity with regard to the aromatic compounds to be extracted, such that a reduced solvent charge may be utilized, wherein the mixture containing aromatic compounds utilized is initially subjected to a pre-distillation such that the faction obtained has a very limited boiling point, and that this fraction is then subjected to an extractive distillation in a first column, wherein a head product depleted of aromatic compounds, predominantly having paraffinic hydrocarbons and a sump product enriched with aromatic compounds are obtained, which are transferred into a second column, in which a raffinate rich in aromatic compounds is obtained by means of reduction of the pressure, or increase of the temperature such that the extracted solvent combination obtained as the sump product can be returned to the process.
摘要翻译：本发明涉及一种用于芳族化合物：苯，甲苯和二甲苯的从重整和裂解汽油或焦炉或含芳香族的炼油厂流，其包括采用萃取蒸馏芳烃分离含芳族化合物中，N的新型溶剂组合从化合物中分离 N'二甲酰基哌嗪或2,2'-双（氰基乙基）醚组合使用与N-甲酰基吗啉作为萃取蒸馏的第二溶剂，使得到的溶剂组合具有相对于芳烃的选择性增加要被提取，因此它管理与低级溶剂加载，其中所述含芳族进料混合物首先进行初步精馏，以便所获得的级分具有窄的沸点，并且该级分，然后在第一列中进行萃取蒸馏，其中，e 在芳族化合物的主要含有链烷烃塔顶产物耗尽获得并在得到的芳族化合物富集的塔底产物被送入第二个塔，通过降低压力或增加富含芳烃的提余液的温度，使得所得到的作为底部产物提取在这个过程中溶剂的组合可以归因于。

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