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    • 3. 发明申请
    • EPOXY/ACID ANHYDRIDE COMPOSITION
    • 环氧/酸酐类组合物
    • WO1997000277A1
    • 1997-01-03
    • PCT/JP1996001612
    • 1996-06-13
    • NISSAN CHEMICAL INDUSTRIES, LTD.MIYAKE, SatoruOSAWA, KenichiKODA, ToshinariHIDAKA, Motohiko
    • NISSAN CHEMICAL INDUSTRIES, LTD.
    • C08G59/58
    • C08G59/686C08G59/42C08G59/58
    • An epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure represented by general formula (I) is employed as a curing accelerator to thereby impart a log pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin; and an epoxy/acid anhydride resin composition obtained by thermally curing the above-mentioned composition, wherein X represents amino, C1-18 monoalkylamino, C1-18 dialkylamino, morpholino, piperidino, methyl or phenyl; R and R independently represent each C1-12 alkyl, C1-12 hydroxyalkyl, C4-8 cycloalkyl, C5-9 cycloalkylmethyl or C5-9 methylcycloalkyl.
    • 包含环氧化合物和用作固化剂的酸酐的环氧/酸酐组合物,其中采用通式(I)表示的特定结构的取代三嗪作为固化促进剂,从而赋予适用期限高 储存稳定性和对组合物的良好加工特性,并且在固化树脂中不引起诸如起泡或开裂的缺陷; 和通过热固化上述组合物得到的环氧/酸酐树脂组合物,其中X表示氨基,C 1-18单烷基氨基,C 1-18二烷基氨基,吗啉代,哌啶子基,甲基或苯基; R 1和R 2独立地表示各个C 1-12烷基,C 1-12羟基烷基,C 4-8环烷基,C 5-9环烷基甲基或C 5-9甲基环烷基。
    • 4. 发明申请
    • HEAT-RESISTANT EPOXY RESIN COMPOSITION
    • 耐热环氧树脂组合物
    • WO1996028490A1
    • 1996-09-19
    • PCT/JP1996000621
    • 1996-03-13
    • NISSAN CHEMICAL INDUSTRIES, LTD.MIYAKE, SatoruOSAWA, KenichiKODA, ToshinariHIDAKA, MotohikoTANAKA, NorioTAKAHASHI, Kiyohisa
    • NISSAN CHEMICAL INDUSTRIES, LTD.
    • C08G59/50
    • C08G59/5086C08G59/32
    • A thermosetting epoxy composition comprising one or more trifunctional epoxy compounds having a molecular structure wherein the three epoxy groups are disposed symmetrically, and one or more N-substituted melamines of general formula (I), (wherein X is (a) and R to R are each independently H, C1-C18 alkyl, C1-C18 hydroxyalkyl, C4-C8 cycloalkyl, C5-C9 cycloalkylmethyl or C5-C9 methylcycloalkyl, with the proviso that three to five members of R to R must be hydrogen, or alternatively R and R may be united to form -(CH2)4-7- or -CH2CH2-O-CH2-CH2-), characterized in that the amount of the active hydrogen atom present in the primary and/or secondary amino groups of the N-substituted melamine(s) is 0.1 to 0.7 equivalent per equivalent of the epoxy group of the trifunctional epoxy compound(s); and a heat-resistant epoxy resin composition obtained by thermosetting the above epoxy composition. The above epoxy composition is easy to handle and the above epoxy resin composition exhibits extremely high heat and chemical resistances.
    • 一种热固性环氧组合物,其包含一种或多种具有分子结构的三官能环氧化合物,其中三个环氧基对称设置,以及一种或多种通式(I)的N-取代三聚氰胺(其中X为(a)和R 1 R 6至R 6各自独立地为H,C 1 -C 18烷基,C 1 -C 18羟基烷基,C 4 -C 8环烷基,C 5 -C 9环烷基甲基或C 5 -C 9甲基环烷基,条件是R 1〜 R 6必须是氢,或者R 5和R 6可以一起形成 - (CH 2)4-7 - 或-CH 2 CH 2 -O-CH 2 -CH 2 - ),其特征在于, 存在于N-取代的三聚氰胺的伯和/或仲氨基中的活性氢原子相对于三官能环氧化合物的环氧基当量为0.1〜0.7当量; 和通过将上述环氧组合物热固化得到的耐热性环氧树脂组合物。 上述环氧组合物易于处理,上述环氧树脂组合物表现出极高的耐热和耐化学性。
    • 6. 发明申请
    • HALOGEN-CONTAINING RESIN STABILIZED AGAINST HEAT AND LIGHT
    • 含卤素的树脂耐热和稳定
    • WO1996026979A1
    • 1996-09-06
    • PCT/JP1996000475
    • 1996-02-29
    • NISSAN CHEMICAL INDUSTRIES, LTD.MIYAKE, SatoruOSAWA, KenichiTANAKA, NorioMIMIURA, NaotakaSATO, Yoshinori
    • NISSAN CHEMICAL INDUSTRIES, LTD.
    • C08L27/00
    • C08K5/34922
    • A halogen-containing resin composition stabilized against heat and light, comprising: (a) 100 parts by weight of a halogen-containing resin; (b) 0.1 to 10 parts by weight of an organic acid (an aliphatic or aromatic carboxylic acid or a phenol) salt of a metal selected among group I-IV metals of the periodic table; (c) 0.01 to 1.0 part by weight of one or two triazine compounds having substituted amino groups and represented by general formula (I), wherein R represents a group selected among C1-18 staight-chain and branched monoalkylamino and dialkylamino groups, C4-8 monocycloalkylamino and dicycloalkylamino groups, a pyrrolidino group, and a piperidino group; and R and R represents a group selected among those exemplified by R and an -NH2 group, provided that R and R may be the same or different; (d) 0.01 to 1.0 part by weight of a phenolic antioxidant; and/or (e) 0.01 to 1.0 part by weight of a hindered amine stabilizer.
    • 一种耐热和耐光稳定的含卤树脂组合物,包括:(a)100重量份的含卤树脂; (b)0.1-10重量份选自元素周期表Ⅰ-Ⅳ族金属的金属的有机酸(脂族或芳族羧酸或苯酚)盐; (c)0.01至1.0重量份具有取代氨基并由通式(I)表示的一种或两种三嗪化合物,其中R 1表示选自C1-18直链和支链单烷基氨基和二烷基氨基的基团 C4-8单环烷基氨基和二环烷基氨基,吡咯烷子基和哌啶子基; R 2和R 3表示选自由R 1和-NH 2基团例示的基团中的基团,条件是R 2和R 3可以相同或不同; (d)0.01〜1.0重量份的酚类抗氧化剂; 和/或(e)0.01〜1.0重量份的受阻胺稳定剂。
    • 7. 发明申请
    • MELAMINE POLYMETAPHOSPHATE AND PROCESS FOR ITS PRODUCTION
    • 聚甲基丙烯酸甲酯及其生产工艺
    • WO1997044377A1
    • 1997-11-27
    • PCT/JP1997001712
    • 1997-05-21
    • NISSAN CHEMICAL INDUSTRIES, LTD.SUZUKI, KeitaroSHISHIDO, KoujiSHINDO, Masuo
    • NISSAN CHEMICAL INDUSTRIES, LTD.
    • C08G79/02
    • C08K5/34928C08G79/02C08K5/529
    • A melamine polymetaphosphate having a solubility of from 0.01 to 0.10 g/100 ml in water at 25 DEG C, a pH of from 2.5 to 4.5 in the form of a 10 wt.% aqueous slurry at 25 DEG C and a melamine content of from 1.0 to 1.1 mol per mol of phosphorus atom. A process for producing such a melamine polymetaphosphate, which comprises the following steps (a) and (b): (a) a step of mixing melamine, urea and an aqueous orthophosphoric acid solution containing at least 40 wt.% of orthophosphoric acid, in such a ratio that melamine is from 1.0 to 1.5 mol per mol of orthophosphoric acid and urea is from 0.1 to 1.5 mol per mol of orthophosphoric acid, at a temperature of from 0 to 140 DEG C, to form a reaction mixture, and stirring the reaction mixture at a temperature of from 0 to 140 DEG C, while removing water, to obtain a powdery product of a double salt of orthophosphoric acid with melamine and urea; and (b) a step of calcining the powdery product obtained in step (a) at a temperature of from 240 to 340 DEG C for from 0.1 to 30 hours, while preventing agglomeration, to obtain a melamine polymetaphosphate.
    • 在25℃下在水中溶解度为0.01至0.10g / 100ml,pH为2.5至4.5,在25℃下为10重量%含水浆料形式的三聚氰胺聚偏磷酸钠,三聚氰胺含量为 每摩尔磷原子为1.0-1.1摩尔。 一种制备这种三聚氰胺聚偏磷酸盐的方法,其包括以下步骤(a)和(b):(a)将含有至少40重量%正磷酸的三聚氰胺,尿素和正磷酸水溶液混合在 三聚氰胺的摩尔比为每摩尔正磷酸为1.0〜1.5摩尔,尿素为0.1〜1.5摩尔/升正磷酸,温度为0〜140℃,形成反应混合物,搅拌 反应混合物在0-140℃的温度下,同时除去水,得到正磷酸的双重盐与三聚氰胺和尿素的粉末状产物; 和(b)在240〜340℃的温度下煅烧步骤(a)中得到的粉末状产物0.1〜30小时,同时防止团聚,得到三聚氰胺聚偏磷酸酯的工序。