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    • 10. 发明专利
    • PREPARATION OF ELECTROLYTIC CHROMIC ACID TREATED STEEL SHEET HAVING HIGH ADHESIVE STRENGTH
    • JPS5616696A
    • 1981-02-17
    • JP8980379
    • 1979-07-17
    • NIPPON STEEL CORP
    • MIYAKE NORITSUGUICHIKAWA TAKASHI
    • C25D11/38
    • PURPOSE:To inexpensively obtain the electrolytic chromic acid treated steel sheet having a superior adhesive property, by electrolytically treating the steel sheet in aqueous solution of chromic anhydride etc. making the steel sheet as cathode and next, electrolytically treating it again after carrying out nonelectrolytic dippling treatment in the same aqueous solution at a fixed time and then, washing by water and drying. CONSTITUTION:>=0.5sec nonelectrolytic treatment is carried out in the following component aqueous solution and the upper chromate layer having a high hydration degree, is eluted and exfoliated after electrolytically treating the steel sheet in aqueous solution of chromic anhydride, chromate, etc. making the steel sheet as cathode, at the time of manufacturing the above-mentioned steel sheet having the coating composed of metallic Cr inner layer and chromate outer layer. Next, chromate layer having a low hydration degree is forme by electrollytically treating the steel sheet with a suitable current density in the same bath again and 0.5-15sec treatment is carried out by 65-100 deg.C, >=4pH high temperature water and then, the above-mentioned steel sheet having a low deteriorating property on standing, is inexpensively obtaned. 2.5coulomb/dm cathode electrolytic treatment is allowed to carry out in aqueous solution of alkali metal etc. controlled >1.5pH,