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    • 6. 发明公开
    • PRECOATED METAL PLATE AND PROCESS FOR PRODUCING PRECOATED METAL PLATE
    • VORBESCHICHTETE METALLPLATTE UND VERFAHREN ZUR HERSTELLUNG EINER VORBESCHICHTETEN METALLPLATTE
    • EP1820639A4
    • 2011-04-06
    • EP05814403
    • 2005-12-05
    • NIPPON STEEL CORP
    • FURUKAWA HIROYASUKANAI HIROSHIINADA KENJITOBISAWA KATSUNORITANAKA SHIGENORIUEDA KOUHEIYOSHIDA KENGOSUEMUNE YOSHIHIRO
    • B32B15/18B05D7/14
    • B05D7/14B05D7/50B05D7/5323B05D2202/15B05D2701/00Y10T428/12472Y10T428/12993
    • This invention provides a precoated metal plate that is improved in color shading prevention and adhesion and is produced by simultaneous multilayer coating. In the precoated metal plate, the center line average roughness Ra in the coating film interface is not less than 0.3 µm, and the maximum height from the waviness center line in the interface is not more than 50% of the layer thickness. There are also provided a top clear coated metal plate, which comprises a clear layer as an upper layer, has an interfacial center line average roughness Ra of 0.3 to 0.7 µm and has excellent weathering resistance, a precoated metal plate having excellent processability and corrosion resistance, which contains not less than 30% by mass on average of a rust preventive pigment so that the average rust preventive content of the upper layer is lower than that in the average rust preventive pigment of the lower layer, the concentration gradient is lowered so that the position from around the interface of the upper layer and the lower layer is increased, and the roughness Ra in the interface of the lower layer and the upper layer is 0.3 to 0.7 µm, and a process for producing the same.
    • 本发明提供一种预涂金属板,其改进了防止着色和粘附,并通过同时多层涂布制造。 在预涂金属板中,涂膜界面的中心线平均粗糙度Ra不小于0.3μm,并且界面处的波纹中心线的最大高度不大于层厚度的50%。 还提供了顶部透明涂层金属板,其包括作为上层的透明层,其界面中心线平均粗糙度Ra为0.3〜0.7μm,具有优异的耐候性,具有优异的加工性和耐腐蚀性的预涂金属板 ,防锈颜料的平均防锈成分的平均防锈成分比平均防锈颜料低30质量%,浓度梯度降低, 上层和下层的界面附近的位置增加,下层和上层的界面的粗糙度Ra为0.3〜0.7μm,其制造方法。
    • 8. 发明公开
    • RESIN-CHROMATE COMPOSITION AND SURFACE-TREATED METAL SHEET
    • HARZ-CHROMATZUSAMMENSETZUNG UNDOBERFLÄCHENBEHANDELTESSTAHLBLECH
    • EP0787831A4
    • 1998-11-11
    • EP96926621
    • 1996-08-09
    • NIPPON STEEL CORPTOYO BOSEKI
    • NAKAZAWA MAKOTOIZAKI TERUAKIHAYASHI KIMITAKASUZUKI SHINICHIMIYAUCHI YUJIROYOSHIDA KENGOODASHIMA HISAOTAKAHASHI TOMOMISHIBABUKI SYUJIFUJIOKA YUJIYAMAZAKI MAKOTOTADOKORO KENICHIRO
    • B05D7/14C09D5/08C23C22/28C23C22/33C08L57/00
    • C09D5/08B05D7/14C23C22/28C23C22/33
    • A resin-chromate composition mainly comprising an emulsion of (a) an organic polymer composed of ethylenically unsaturated compounds in an aqueous medium, (b) a water-soluble chromium compound, and (c) a mineral acid, characterized in that the content of (a1) ethylenically unsaturated carboxylic acid components constituting the organic polymer (a) is more than 10 wt.% but below 30 wt.% based on the weight (in terms of solid matter) of the organic polymer (a), that of (a2) ethylenically unsaturated hydroxylated compound components constituting the polymer (a) is 0 wt.% or above but below 3 wt.% based thereon, and the balance is composed of (a3) ethylenically unsaturated compound components bearing neither carboxyl nor hydroxyl groups and that the content of components forming C3-C7 monocarboxylic acids in an aqueous solution of chromic acid and/or a chromate coat is 20 wt.% or below based on the weight (in terms of solid matter) of the organic polymer; and a metal sheet surface-treated with this composition.The above chromate composition is excellent in bath stability and smelling characteristics and the metal sheet surface-treated with the composition does not produce any putrid smell and is excellent in corrosion resistance, prevention of leaching of chromium, resistance to alkali, adhesion of paint, and appearance and quality.
    • 一种树脂铬酸盐组合物,主要包含(a)在水性介质中由烯键式不饱和化合物构成的有机聚合物的乳液,(b)水溶性铬化合物和(c)无机酸,其特征在于, (a1)构成有机聚合物(a)的烯键式不饱和羧酸成分,相对于有机聚合物(a)的重量(以固体成分计)为基准,为(10)重量%以下, a2)构成聚合物(a)的烯键式不饱和羟基化合物组分相对于其为0重量%以上但低于3重量%,余量由(a3)不具有羧基和羟基的烯键式不饱和化合物组分组成, 基于有机聚合物的重量(以固体物质计),在铬酸和/或铬酸盐涂层的水溶液中形成C 3 -C 7单羧酸的组分的含量为20重量%以下。 和用该组合物表面处理的金属片。 上述铬酸盐组合物的浴稳定性和气味特性优异,用组合物表面处理的金属片不产生腐臭,耐腐蚀性优异,防止铬浸出,耐碱性,涂料粘附性和 外观和质量。