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1. 发明公开

EP0520811A3 Catalyst components for polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：EP0520811A3
公开(公告)日：1993-02-03
申请号：EP92305894.5
申请日：1992-06-26
申请人： NIPPON OIL CO. LTD.
发明人： Tajima, Yoshio , Kataoka, Naoki , Numao, Yosuke , Seki, Takashi , Matsuura, Kazuo
IPC分类号： C08F10/00 , C08F4/651 , C08F4/656
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/903 , C08F4/6428 , C08F4/651 , C08F4/656 , C08F2500/12 , C08F210/08
摘要： A catalyst component is disclosed for use in the homo- or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula M¹ (OR¹) p R² q X¹ 4-p-q and a second compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing high molecular weight, wide distribution thereof and other desirable qualities in the polymer product.
摘要翻译：公开了用于烯烃的均聚或共聚的催化剂组分。催化剂组分由式M 1（OR 1）pR 2 q X 14-p-q的第一种化合物和为具有两个或多个共轭双键的有机环化合物的第二种化合物组成。还公开了生产烃聚合物的方法，其中将上述催化剂组分与改性的有机铝化合物结合以形成能够在聚合物产物中提供高分子量，宽分布和其他所需质量的催化剂组合物。

2. 发明公开

EP0237294A2 Process for preparing ethylene polymers 失效
标题翻译：一种用于乙烯聚合物的制备方法。
公开(公告)号：EP0237294A2
公开(公告)日：1987-09-16
申请号：EP87301961.6
申请日：1987-03-06
申请人： NIPPON OIL CO. LTD.
发明人： Tajima, Yoshio , Nomiyama, Kazutosi , Nishikitani, Yoshinori , Kuroda, Nobuyuki , Matsuura, Kazuo
IPC分类号： C08F10/02 , C08F4/62 , C08F2/00
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F210/16 , Y10S526/905 , C08F2/34 , C08F4/6228 , C08F2500/12 , C08F2500/14 , C08F2500/13 , C08F2500/07 , C08F2500/11 , C08F2500/18 , C08F210/08 , C08F4/6543 , C08F4/69 , C08F4/025
摘要： A process for preparing an ethylene polymer by a two-stage polymerization of ethylene or ethylene and an a-olefin in an inert hydrocarbon at 50-100°C using a coordination polymerization catalyst containing a solid component and an organoaluminum compound, said solid component containing a transition metal compound, which process comprises:

(a) in a first stage, producing 10-90% by weight based on the total polymer quantity of a polymer having a melt index in the range of 0.0001 to 0.5 g/10 min as measured according to ASTM D 1238-73, Condition E, using as said solid component a solid product obtained by supporting chromium trioxide or a compound which on calcining forms chromium oxide at least partially, on an inorganic oxide carrier followed by calcining, and using as said organoaluminum compound a compound of the general formula
wherein R is a hydrocarbon radical having 1 to 18 carbon atoms and n is 2 5 n ≦ 100; and
(b) in a second stage, producing 90-10% by weight based on the total polymer quantity of a polymer having a melt index in the range of 0.01 to 50 g/10 min as measured according to ASTM D 1238-73, Condition E, using as said solid component a solid material containing at least magnesium and titanium, and using as said organoaluminum compound a compound of the general formula AIR'pX 3 - P wherein R' is a hydrocarbon radical having 1 to 20 carbon atoms, X is halogen and/or alkoxy and p is 0

Alternatively the solid component of (a) also contains magnesium and titanium and step (b) is effected simply by adding the compound of the formula AIR'pX 3 -p after completion of the first stage polymerisation.

3. 发明授权

EP0669346B1 Solid catalyst components for olefin polymerization and use thereof 失效
标题翻译：用于烯烃聚合及其应用的固体催化剂组分
公开(公告)号：EP0669346B1
公开(公告)日：1998-06-03
申请号：EP94301377.1
申请日：1994-02-25
申请人： NIPPON OIL CO. LTD.
发明人： Sano, Akira , Matsuura, Kazuo , Kubo, Kunimichi , Tajima, Yoshio
IPC分类号： C08F10/00 , C08F4/02
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F110/06 , C08F210/16 , C08F4/6567 , C08F4/6555 , C08F4/025 , C08F2500/08 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F210/08

4. 发明授权

EP0520811B1 Catalyst components for polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：EP0520811B1
公开(公告)日：1996-05-08
申请号：EP92305894.5
申请日：1992-06-26
申请人： NIPPON OIL CO. LTD.
发明人： Tajima, Yoshio , Kataoka, Naoki , Numao, Yosuke , Seki, Takashi , Matsuura, Kazuo
IPC分类号： C08F10/00 , C08F4/651 , C08F4/656
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/903 , C08F4/6428 , C08F4/651 , C08F4/656 , C08F2500/12 , C08F210/08

5. 发明授权

EP0474391B1 Polyolefins 失效
标题翻译：聚烯烃。
公开(公告)号：EP0474391B1
公开(公告)日：1995-10-25
申请号：EP91307633.7
申请日：1991-08-19
申请人： NIPPON OIL CO. LTD.
发明人： Tajima, Yoshio , Nomiyama, Kazutoshi , Kataoka, Naoki , Matsuura, Kazuo
IPC分类号： C08F10/00 , C08F4/642
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/14 , C08F2500/18

6. 发明公开

EP0669346A1 Solid catalyst components for olefin polymerization and use thereof 失效
标题翻译： Fester KatalysatorbestandteilfürOlefinpolymerisation und Anwendung derselben。
公开(公告)号：EP0669346A1
公开(公告)日：1995-08-30
申请号：EP94301377.1
申请日：1994-02-25
申请人： NIPPON OIL CO. LTD.
发明人： Sano, Akira , Matsuura, Kazuo , Kubo, Kunimichi , Tajima, Yoshio
IPC分类号： C08F10/00 , C08F4/02
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F110/06 , C08F210/16 , C08F4/6567 , C08F4/6555 , C08F4/025 , C08F2500/08 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F210/08
摘要： An effective catalyst carrier for use in the polymerization of olefins is provided.
Said carrier comprises particles of silicon oxide or aluminum oxide satisfying the following characteristics (A) to (E):

(A) An average particle diameter as measured by the sieving method is in the range of 20 to 150 µm.
(B) A specific surface area as measured by the BET method is in the range of 150 to 600 m 2 /g.
(C) The volume of pores ranging in pore radius from 18 to 1,000 Angstroms as measured by the mercury penetration method is in the range of 0.3 to 2.0 cm 3 /g.
(D) An apparent specific gravity as measured according to JIS K6220-6.8 is not lower than 0.32.
(E) After the particles classified in the range of between 53 µm and 75 µm by the sieving method have been subjected to an ultrasonic disintegration treatment at 40 KHz, 35W, for 20 minutes, the proportion of 50 µm or smaller particles, i.e., degree of ultrasonic disintegration, is not more than 30%.
摘要翻译：提供了一种用于烯烃聚合的有效催化剂载体。所述载体包含满足以下特征（A）至（E）的氧化硅或氧化铝颗粒：（A）通过筛分方法测量的平均粒径在20至150μm的范围内。（B）通过BET法测定的比表面积在150〜600m 2 / g的范围内。（C）通过水银渗透法测定的孔径在18〜1000埃范围内的孔的体积在0.3〜2.0cm 3 / g的范围内。（D）根据JIS K6220-6.8测定的表观比重不低于0.32。（E）通过筛分方法将分级在53μm〜75μm范围内的粒子在40KHz，35W，20分钟以上进行超声波分解处理，将50μm以下的粒子即超声崩解度不超过30％。

7. 发明公开

EP0546690A1 Catalyst components for polymerization of olefins 失效
标题翻译：碳酸酯混合物。
公开(公告)号：EP0546690A1
公开(公告)日：1993-06-16
申请号：EP92310315.4
申请日：1992-11-12
申请人： NIPPON OIL CO. LTD.
发明人： Kataoka, Naoki , Numao, Yosuke , Seki, Takashi , Tajima, Yoshio , Matsuura, Kazuo
IPC分类号： C08F4/642 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F210/16 , Y10S526/901 , Y10S526/943 , C08F4/657 , C08F4/655 , C08F4/651 , C08F4/654 , C08F210/08 , C08F2500/18 , C08F2500/12
摘要： A process for the polymerization of olefinic hydrocarbons is carried out in the presence of a catalyst comprising a catalyst component derived from reacting a compound of the formula Me 1 R 1 n X 1 4-n , a compound of the formula Me 2 R 2 mX 2 z-m , an organocyclic compound having two or more conjugated double bonds and a carrier of inorganic or polymeric material, and a modified organoaluminum compound having Al-O-Al bonds, the resulting polyolefins having a relatively wide molecular weight distribution, a relatively narrow composition distribution and increased bulk density.
摘要翻译：烯烃聚合的方法是在催化剂存在下进行的，所述催化剂包含催化剂组分，该催化剂组分衍生自使式Me 1 R 1 n X 1 4-n的化合物，式具有两个或多个共轭双键的有机环状化合物和无机或聚合物材料的载体和具有Al-O-Al键的改性有机铝化合物，所得聚烯烃具有相对宽的分子量分布，相对较窄的组成分布和增加的体积密度。

8. 发明公开

EP0474391A3 Polyolefins 失效
标题翻译：的聚烯烃
公开(公告)号：EP0474391A3
公开(公告)日：1992-11-19
申请号：EP91307633.7
申请日：1991-08-19
申请人： NIPPON OIL CO. LTD.
发明人： Tajima, Yoshio , Nomiyama, Kazutoshi , Kataoka, Naoki , Matsuura, Kazuo
IPC分类号： C08F10/00 , C08F4/642
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/14 , C08F2500/18
摘要： Olefins are polymerized with use of a catalyst composed of a specified catalyst component and a specified modified organoaluminum compound. The catalyst component is derived from mutual contact of an inorganic porous oxide, an aluminum-based of Al(OR¹) n X 3-n and a transition metal compound of R 2 p MX r . The organoaluminum compound has Al-O-Al bonds in the molecule. Bulk density and particle shape qualities are greatly improved among important physical properties.

9. 发明授权

EP0273284B1 Polyethylene composition 失效
标题翻译：聚乙烯组合物
公开(公告)号：EP0273284B1
公开(公告)日：1991-10-09
申请号：EP87118488.3
申请日：1987-12-14
申请人： Nippon Oil Co., Ltd.
发明人： Tajima, Yoshio , Nomiyama, Kazutoshi , Shimo, Yoshiyuki , Kuroda, Nobuyuki , Matsuura, Kazuo
IPC分类号： C08F10/02 , C08L23/04
CPC分类号： C08F10/02 , C08L23/06 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/02 , C08F2/001 , C08L2666/06

10. 发明公开

EP0273284A2 Polyethylene composition 失效
标题翻译： Polyäthylen-Zusammensetzung。
公开(公告)号：EP0273284A2
公开(公告)日：1988-07-06
申请号：EP87118488.3
申请日：1987-12-14
申请人： Nippon Oil Co., Ltd.
发明人： Tajima, Yoshio , Nomiyama, Kazutoshi , Shimo, Yoshiyuki , Kuroda, Nobuyuki , Matsuura, Kazuo
IPC分类号： C08F10/02 , C08L23/04
CPC分类号： C08F10/02 , C08L23/06 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/02 , C08F2/001 , C08L2666/06
摘要： Disclosed is polyethylene composition having excellent environmental stress cracking resistance (ESCR) and giving molded articles with good surface properties.
This composition comprises a blend of two specific types of polyethylene selected with due consideration for their molecular weight distribution in addition to their molecular weights, so that it has excellent melt tension, ESCR and moldability. Accordingly, it can suitably be used in blow molding and extrusion molding to produce molded articles with no shark skin, as well as vessels of very large size.
This composition is formed by blending (A) polyethylene obtained according to a two-step polymerization process using a Ziegler catalyst containing magnesium and titanium, and (B) high-molecular-weight polyethylene obtained with the aid of a chromium-containing catalyst, in a specified proportion.
摘要翻译：公开了具有优异的耐环境应力开裂性（ESCR）的聚乙烯组合物和具有良好表面性能的模塑制品。除了它们的分子量之外，该组合物还包括两种特定类型的聚乙烯的共混物，其中考虑到它们的分子量分布，从而具有优异的熔体张力，ESCR和成型性。因此，它可以适用于吹塑和挤出成型，以生产没有鲨鱼皮的模制品，以及非常大尺寸的容器。该组合物通过使用含有镁和钛的齐格勒催化剂和（B）借助于含铬催化剂获得的高分子量聚乙烯，通过使用两步聚合方法得到的聚乙烯（A）一个比例。

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