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    • 4. 发明专利
    • BLOCK TYPE SHIFTING MOLD
    • JPH02108442A
    • 1990-04-20
    • JP26146388
    • 1988-10-19
    • NIPPON KOKAN KKISHIKAWAJIMA HARIMA HEAVY IND
    • NAKADA MASAYUKIKOMATSU MASAMITAKASUGI HIDETOKAWAI YOSHIHIKOOZEKI AKIYAOSADA SHIRO
    • B22D11/06
    • PURPOSE:To prevent the development of crossing crack and longitudinal crack and to improve the yield of a cast slab by forming grid-like grooves on a part of casting wall in each block mold member and arranging these grid grooves in casting direction and the crossing direction at the right angle to this. CONSTITUTION:Molten metal 12 is poured into a cavity 27 in the block caster 20 through a nozzle 14. Carrying velocities (a), (b) of the mold members 23 for upper and lower units 22 and cast slab drawing velocity (c) are suitably controlled with a computer in accordance with variations of molten metal pouring rate and molten metal surface in the cavity. The block mold member 23 has L-shape of the cross section as crossing at the right angle to the casting direction, and the grid-like grooves 25 are formed on the long side surface 24 in the inner wall thereof. The groove 25 has V-shape of the shallow groove depth to the groove width. When the solidified shell grows, shortage of cooling to the molten metal at joint part of the mutual block mold members is developed and solidified delay is formed and shrinkage stress is concentrated and the crossing crack on the cast slab is apt to develop. The longitudinal crack is apt to develop as the same as the above. As the grid-like grooves are formed, shrinkage stress is dispersed to the whole casting wall. By this method, the development of the crack is prevented and the yield of the cast slab can be improved.
    • 5. 发明专利
    • NOZZLE FOR SHIFTING TYPE MOLD
    • JPH02108441A
    • 1990-04-20
    • JP26146288
    • 1988-10-19
    • NIPPON KOKAN KKISHIKAWAJIMA HARIMA HEAVY IND
    • NAKADA MASAYUKITAKASUGI HIDETOKAWAI YOSHIHIKOOZEKI AKIYATSUCHIDA HIROSHI
    • B22D11/06
    • PURPOSE:To prevent sticking of solidified metal to a nozzle tip by providing molten metal flowing passage formed with a refractory, gas passage formed as opening so as to surround this discharging hole and means for supplying oxidizing gas into the gas passage. CONSTITUTION:The molten metal 12 is poured into a cavity 27 and caterpillar driving for each mold unit 22 and cast slab drawing velocity are optimumly controlled while adjusting the molten metal pouring rate with a sensor and control unit in tundish side. At the time of continuously pouring the molten metal through the nozzle 14, temp. gradient between the molten metal discharging hole 30 side and the nozzle outer circumferential side, is developed and the molten metal is solidified and stuck to the nozzle tip 15. This is grown as the solidified metal 40 and apt to bridge between the nozzle and casting wall, but oxygen gas is injected toward the tip part 15 from an injection hole 18. As the oxygen gas is directly injected to the solidified metal 40, Fe component is oxidized and melted with exothermic reaction. Therefore, it does not happen that the solidified metal 40 is taken in the solidified shell 26 caused by falling-down from the nozzle tip. By this method, the sticking of solidified metal is prevented and the cast slab having sound surface characteristic can be obtd.
    • 7. 发明专利
    • METHOD, APPARATUS, AND PROBE FOR MEASURING THE ACTIVITY OF A SOLUTE ELEMENT IN MOLTEN METAL
    • CA1303133C
    • 1992-06-09
    • CA610341
    • 1989-09-05
    • SASABE MINORUNIPPON KOKAN KKOSAKA OXYGEN IND
    • SASABE MINORUHASEGAWA TERUYUKIISHIKAWA HIROAKIKAWAI YOSHIHIKOFURUTA CHIKAYOSHINAGATSUKA TOSHIOMATSUSHIGE HARUHIKO
    • G01N27/411G01N33/20G01N27/409
    • \\ A method for measuring an activity of a solute element M in molten metal comprises steps of measuring an electromotive force El corresponding oxygen content of the molten metal by means of a solid electrolyte having oxygen ion conductivity and measuring temperature T of the molten metal, also measuring the electromotive force E2 corresponding to manganese content of the molten metal by means of a solid electrolyte having oxygen ion conductivity and coated with MnO, and obtaining the manganese activity aMn on the basis of the measured electromotive forces El, E2 and the measured temperature T. Another activity measuring method comprises steps of measuring the temperature T and solidifying temperature Ts of molten metal, obtaining the carbon concentration ¢C! of the molten metal on the basis of the solidifying temperature Ts, also measuring the manganese electromotive force E2 in the molten metal by means of a solid electrolyte having oxygen ion conductivity and coated with MnO, and obtaining the manganese activity aMn on the basis of the measured electromotive force E2, the carbon concentration ¢C!, and the measured temperature T. An Mn sensor electrode comprises a solid electrolyte surrounding a reference and having oxygen ion conductivity, and a coating layer composed of MnO or a composite oxide thereof and covering the outer periphery of the solid electrolyte. The MnO or the composite oxide for the coating layer has a composition such that two or more balance portions A, B, C, D are provided for an electromotive force E1, E2 measured by an electromotive force measuring circuit, the electromotive force E1, E2 being defined by the manganese activity aMn in the first one A, C of the balance portions, and by the oxygen activity aO in the molten metal in the last balance portion B, D.